Abstract
The paper presents a comparative study of the magnetocaloric characteristics of rare-earth magnets. Both hydrogen containing systems Gd–H, (Gd,R)Ni–H (R is a rare-earth metal) and RCo2–H with a Laves phase structure and systems without hydrogen, such as layered magnets with the general formula RTX (T = Mn, Fe, Co; X = Si), are studied, as well as compounds of the type R2(Fe,T)17 (T = Al), which have a magnetic compensation point and exhibit an alternating magnetocaloric effect (MCE). The MCE was measured directly and indirectly from the analysis of the field dependences of magnetization. The main regularities and specific features of the formation of magnetocaloric properties of materials depending on their composition and structure have been revealed.
REFERENCES
A. S. Andreenko, K. P. Belov, S. A. Nikitin, and A. M. Tishin, “Magnetocaloric effects in rare-earth magnetic materials,” Sov. Phys. Usp. 32, 649 (1989). https://doi.org/10.1070/PU1989v032n08ABEH002745
K. P. Belov, Magnetothermal Phenomena in Rare-Earth Magnetics (Nauka, Moscow, 1990).
S. A. Nikitin, Magnetic Properties of Rare-Earth Metals and Their Alloys (Mosk. Gos. Univ., Moscow, 1989).
A. M. Tishin and Y. I. Spichkin, The Magnetocaloric Effect and its Applications (Institute of Physics Publishing Ltd, 2003).
V. V. Sokolovskiy, O. N. Miroshkina, V. D. Buchelnikov, and V. V. Marchenkov, “Magnetocaloric effect in metals and alloys,” Phys. Met. Metallogr. 123, 315–318 (2022). https://doi.org/10.1134/s0031918x2204010x
V. V. Sokolovskiy, O. N. Miroshkina, and V. D. Buchelnikov, “Review of modern theoretical approaches for study of magnetocaloric materials,” Phys. Met. Metallogr. 123, 319–374 (2022). https://doi.org/10.1134/S0031918X22040111
A. A. Inishev, E. G. Gerasimov, P. B. Terent’ev, V. S. Gaviko, and N. V. Mushnikov, “The magnetocaloric effect of nonstoichiometric ErM2Mnx compounds (with M = Ni, Co, and Fe),” Phys. Met. Metallogr. 123, 869–873 (2022). https://doi.org/10.1134/s0031918x22090046
G. S. Burkhanov, N. B. Kolchugina, E. A. Tereshina, I. S. Tereshina, G. A. Politova, V. B. Chzhan, D. Badurski, O. D. Chistyakov, M. Paukov, H. Drulis, and L. Havela, “Magnetocaloric properties of distilled gadolinium: Effects of structural inhomogeneity and hydrogen impurity,” Appl. Phys. Lett. 104, 242402–242407 (2014). https://doi.org/10.1063/1.4883744
V. B. Chzhan, A. A. Kurganskaya, I. S. Tereshina, A. Yu. Karpenkov, I. A. Ovchenkova, E. A. Tereshina-Chitrova, A. V. Andreev, D. I. Gorbunov, S. A. Lushnikov, and V. N. Verbetsky, “Influence of interstitial and substitutional atoms on magnetocaloric effects in RNi compounds,” Mater. Chem. Phys. 264, 124455 (2021). https://doi.org/10.1016/j.matchemphys.2021.124455
I. S. Tereshina, I. A. Ovchenkova, G. A. Politova, and N. Yu. Pankratov, “Materials based on RCo2 and RMnSi for solid-state magnetic cooling,” Bull. Russ. Acad. Sci.: Phys. 87, 304–309 (2023). https://doi.org/10.3103/s1062873822701131
S. A. Nikitin, T. I. Ivanova, and I. A. Tskhadadze, “Magnetic properties of GdMnxFe1–xSi intermetallic compounds,” Acta Phys. Pol. A 91, 463–466 (1997). https://doi.org/10.12693/aphyspola.91.463
N. Yu. Pankratov, T. P. Kaminskaya, I. S. Tereshina, A. A. Makurenkova, A. Yu. Karpenkov, M. A. Paukov, and S. A. Nikitin, “Magnetic properties and surface morphology of the intermetallic compound Dy2Fe10Al7 and its hydride,” Phys. Solid State 62, 808–814 (2020). https://doi.org/10.1134/s1063783420050224
K. A. Gschneidnerjr, V. K. Pecharsky, and A. O. Tsokol, “Recent developments in magnetocaloric materials,” Rep. Prog. Phys. 68, 1479–1539 (2005). https://doi.org/10.1088/0034-4885/68/6/r04
S. V. Vonsovskii, Magnetism (Nauka, Moscow, 1971).
M. P. Annaorazov, S. A. Nikitin, A. L. Tyurin, K. A. Asatryan, and A. Kh. Dovletov, “Anomalously high entropy change in FeRh alloy,” J. Appl. Phys. 79, 1689–1695 (1996). https://doi.org/10.1063/1.360955
A. I. Smarzhevskaya, W. Iwasieczko, V. N. Verbetsky, and S. A. Nikitin, “New magnetocaloric material based on GdNiH3.2 hydride for application in cryogenic devices,” Phys. Status Solidi (c) 11, 1102–1105 (2014). https://doi.org/10.1002/pssc.201300728
E. Gratz and A. S. Markosyan, “Physical properties of RCo2 Laves phases,” J. Phys.: Condens. Matter 13, R385–R413 (2001). https://doi.org/10.1088/0953-8984/13/23/202
S. A. Nikitin, G. A. Tskhadadze, I. A. Ovchenkova, D. A. Zhukova, and T. I. Ivanova, “The magnetic phase transitions and magnetocaloric effect in the Ho(Co1 – xAlx)2 and Tb(Co1–xAlx)2 compounds,” Solid State Phenom. 168, 119–121 (2011). https://doi.org/10.4028/www.scientific.net/SSP.168-169.119
I. A. Ovchenkova, G. A. Tskhadadze, D. A. Zhukova, T. I. Ivanova, and S. A. Nikitin, “Magnetocaloric effect in RCo2 compounds,” Solid State Phenom. 190, 339–342 (2012). https://doi.org/10.4028/www.scientific.net/ssp.190.339
Yi. Zhuang, X. Chen, K. Zhou, K. Li, and C. Ma, “Phase structure and magnetocaloric effect of (Tb1 ‒ xDyx)Co2 alloys,” J. Rare Earths 26, 749–752 (2008). https://doi.org/10.1016/s1002-0721(08)60176-3
M. Halder, S. M. Yusuf, M. D. Mukadam, and K. Shashikala, “Magnetocaloric effect and critical behavior near the paramagnetic to ferrimagnetic phase transition temperature in TbCo2 – xFex,” Phys. Rev. B 81 (2010). https://doi.org/10.1103/physrevb.81.174402
N. V. Mushnikov, V. S. Gaviko, and T. Goto, “Magnetic properties of hydrogen-amorphized RCo2Hx (R = Gd, Tb, Dy, Ho, Er, Tm and Y) alloys,” J. Alloys Compd. 398, 36–41 (2005). https://doi.org/10.1016/j.jallcom.2005.02.032
E. Burzo, P. Vlaic, D. P. Kozlenko, S. E. Kichanov, N. T. Dang, E. V. Lukin, and B. N. Savenko, “Magnetic properties of TbCo2 compound at high pressures,” J. Alloys Compd. 551, 702–710 (2013). https://doi.org/10.1016/j.jallcom.2012.10.178
M. Brouha and K. H. J. Buschow, “The pressure dependence of the Curie temperature of rare earth-cobalt compounds,” J. Phys. F: Met. Phys. 3, 2218–2226 (1973). https://doi.org/10.1088/0305-4608/3/12/021
S. A. Nikitin, I. A. Tskhadadze, A. V. Morozkin, and Yu. D. Seropegin, “The influence of Ti on the itinerant magnetism of RTX compounds,” J. Magn. Magn. Mater. 196–197, 632–633 (1999). https://doi.org/10.1016/s0304-8853(98)00880-4
S. A. Nikitin, I. A. Ovchenkova, M. E. Blinova, and I. S. Tereshina, “Magnetocaloric effect in GdMn1 – xTxSi (T = Ti, Fe, Co) compounds,” Moscow Univ. Phys. Bull. 77 (4), 645–651 (2022). https://doi.org/10.3103/S0027134922040117
I. S. Tereshina, S. V. Veselova, V. N. Verbetsky, M. A. Paukov, D. I. Gorbunov, and E. A. Tereshina-Chitrova, “Influence of substitutions and hydrogenation on the structural and magnetic properties of (R'R'')2Fe17 (R', R'' = Sm, Er, Ho): Compositions with promising fundamental characteristics,” J. Alloys Compd. 897, 163228 (2022). https://doi.org/10.1016/j.jallcom.2021.163228
D. Givord and R. Lemaire, “Magnetic transition and anomalous thermal expansion in R2Fe17 compounds,” IEEE Trans. Magn. 10, 109–113 (1974). https://doi.org/10.1109/tmag.1974.1058311
N. Yu. Pankratov, I. S. Tereshina, A. Yu. Karpenkov, and S. A. Nikitin, “Sign-reversing magnetocaloric effect in R2Fe10Al7 (R = Dy and Ho) compounds,” Crystallogr. Rep. 68, 441–445 (2023). https://doi.org/10.1134/s1063774523700141
K. H. J. Buschow, “Intermetallic compounds of rare-earth and 3d transition metals,” Rep. Prog. Phys. 40, 1179–1256 (1977). https://doi.org/10.1088/0034-4885/40/10/002
V. B. Chzhan, I. S. Tereshina, A. Yu. Karpenkov, and E. A. Tereshina-Chitrova, “Persistent values of magnetocaloric effect in the multicomponent Laves phase compounds with varied composition,” Acta Mater. 154, 303–310 (2018). https://doi.org/10.1016/j.actamat.2018.05.053
N. A. de Oliveira and P. J. von Ranke, “Theoretical aspects of the magnetocaloric effect,” Phys. Rep. 489, 89–159 (2010). https://doi.org/10.1016/j.physrep.2009.12.006
Funding
This work was supported by the Russian Science Foundation (project no. 22-29-00773, https://rscf.ru/project/22-29-00773/), Lomonosov Moscow State University.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Translated by E. Chernokozhin
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Pankratov, N.Y., Tereshina, I.S. & Nikitin, S.A. Magnetocaloric Effect in Rare-Earth Magnets. Phys. Metals Metallogr. 124, 1139–1146 (2023). https://doi.org/10.1134/S0031918X23601841
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0031918X23601841