Abstract
The activity of Co/ZnO and Rh/Al2O3 catalysts in ethanol steam reforming was studied in a traditional tubular reactor with a fixed catalyst bed and in a microchannel reactor. At temperatures of 600 and 700°C, the Rh/Al2O3 catalyst was much more active and stable than Co/ZnO. A comparison between the reactors of two types showed that the ethanol steam reforming occurred more efficiently in the microchannel reactor because of intense heat and mass exchange. The specific hydrogen production per unit weight of catalyst in the microchannel reactor was almost twice as high as that in the traditional reactor.
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Fuel Cell Handbook, Morgantown, W.Va.: US Department of Energy, Office of Fossil Energy, National Energy Technology Laboratory, 2000.
Makarshin, L.L. and Parmon, V.N., Catal. Ind., 2012, vol. 4, no. 5, p. 27.
Meng, Ni., Leung, D.Y.C., and Leung, M.K.H., Int. J. Hydrogen Energy, 2007, vol. 32, p. 3238.
Liguras, D.K., Kondarides, D.I., and Verykios, X.E., Appl. Catal., B, 2003, vol. 43, p. 345.
Men, Y., Kolb, G., Zapf, R., Hessel, V., and Loewe, H., Trans. Inst. Chem. Eng., Part B, 2007, vol. 85, no. 5, p. 413.
Diagne, C., Idriss, H., and Kiennemann, A., Catal. Commun., 2002, vol. 3, p. 565.
Virginie, M., Araque, M., Roger, A.-C., Vargas, J.C., and Kiennemann, A., Catal. Today, 2008, vol. 138, p. 21.
Akande, A.J., Idem, R.O., and Dalai, A.K., Appl. Catal., A, 2005, vol. 287, p. 159.
Sun, J., Qiu, X.P., Wu, F., and Zhu, W.T., Int. J. Hydrogen Energy, 2005, vol. 30, p. 437.
Torres, J.A., Llorca, J., Casanovas, A., Domínguez, M., Salvado, J., and Montane, D., J. Power Sources, 2007, vol. 169, p. 158.
Vargas, J.C., Vanhaecke, E., Roger, A.C., and Kiennemann, A., Stud. Surf. Sci. Catal., 2004, vol. 147, p. 115.
Makarshin, L.L., Andreev, D.V., Gribovskii, A.G., Dutov, P.M., Khantakov, R.M., and Parmon, V.N., Kinet. Catal., 2007, vol. 48, no. 5, p. 765.
Gribovskii, A.G., Makarshin, L.L., Andreev, D.V., Korotaev, S.V., Zaikovskii, V.I., and Parmon, V.N., Kinet. Catal., 2009, vol. 50, no. 3, p. 444.
Delsman, E.R., Microstructured Reactors for a Portable Hydrogen Production Unit, Eindhoven: Tech. Univ., 2005.
Ratnasamy, C. and Wagner, J.P., Catal. Rev. Sci. Eng., 2009, vol. 51, p. 325.
Karim, A.M., Yu Su, Junming Sun, Cheng Yang, Strohm, J.J., King, D.L., and Yong Wang, Appl. Catal., B, 2010, vol. 96, p. 441.
Moura, J.S., Souza, M.O.G., and Rangel, M.C., Fuel, 2008, vol. 87, p. 3627.
Araujo, G.C., Lima, S., Rangel, M.C., La Parola, V., Pena, M.A., and Fierro, J.L.G., Catal. Today, 2005, vols. 107–108, p. 906.
Chesnokov, V.V. and Buyanov, R.A., Russ. Chem. Rev., 2000, vol. 69, no. 7, p. 623.
Tsybulya, S.V., Cherepanova, S.V., Khasin, A.A., Zaikovskii, V.I., and Parmon, V.N., Dokl. Phys. Chem., 1999, vol. 366, p. 143.
Bartholomew, C.H., Appl. Catal., A, 2001, vol. 212, p. 17.
Purnama, H., Ressler, T., Jentoft, R.E., Soerijanto, H., Schloegl, R., and Schomacker, R., Appl. Catal., A, 2004, vol. 259, p. 83.
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Original Russian Text © D.V. Andreev, V.V. Radaev, L.L. Makarshin, A.G. Gribovskii, V.I. Zaikovskii, V.N. Parmon, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 6, pp. 799–809.
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Andreev, D.V., Radaev, V.V., Makarshin, L.L. et al. Ethanol steam reforming over Co/ZnO and Rh/Al2O3 catalysts in a microchannel catalytic reactor. Kinet Catal 55, 798–808 (2014). https://doi.org/10.1134/S0023158414060019
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DOI: https://doi.org/10.1134/S0023158414060019