SpringerLink
Log in

Preparation and characterization of a novel washcoat material and supported Pd catalysts

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

A nanosized Ce0.5Mn0.5O1.5 powder was successfully synthesized by macromolecule surfactant modified method and then it was used as the cordierite honeycomb washcoat of VOCs combustion catalysts. The effect of Ce-Mn-O powder with different Ce/Mn molar ratio on the catalytic activity and the cohesive ability of washcoat on the cordierite honeycomb substrate was also investigated. The structure and catalytic properties of Ce0.5Mn0.5O1.5 washcoat were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), atomic force microscopy (AFM), differential thermal analysis and thermo-gravimetric analysis (TG/DTA), and N2 adsorption and desorption techniques. The results indicated that the Ce0.5Mn0.5O1.5 powder belongs to a novel washcoat with the advantages of strong cohesiveness, high surface area and without agglomeration even after 1000°C calcination. The total oxidation temperature for toluene, acetone and ethyl acetate over the 0.1 wt % Pd/Ce0.5Mn0.5O1.5/cordierite honeycomb catalysts was at 200, 220 and 220°C, respectively. Compaired with the catalysts without Ce0.5Mn0.5O1.5 washcoat, the catalyst with Ce0.5Mn0.5O1.5 as washcoat on the cordierite honeycomb could improve the dispersion of PdO and shows a good catalytic activity for toluene, acetone and ethyl acetate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Minicò S., Scirè, S., Crisafulli, C., Maggiore, R., and Galvagno, S., Appl. Catal., B, 2000, vol. 28, p. 245.

    Article  Google Scholar 

  2. Scirè S., Minicò, S., Crisafulli, C., Satriano, C., and Pistone, A., Appl. Catal., B, 2003, vol. 40, p. 43.

    Article  Google Scholar 

  3. Pijolat, M., Prin, M., Soustelle, M., Touret, O., and Nortier, P., J. Chem. Soc., Faraday Trans., 1995, vol. 91, p. 3941.

    Article  CAS  Google Scholar 

  4. Kozlov, A.I., Kim, D.H., Yezerets, A., Anderson, P., Kung, H.H., and Kung, M.C., J. Catal., 2002, vol. 209, p. 417.

    Article  CAS  Google Scholar 

  5. Hori, C.E., Permana, H., Simon Ng, K.Y., Brenner, A., More, K., Rahmoeller, K.M., and Belton, D., Appl. Catal., B, 1998, vol. 16, p. 105.

    Article  CAS  Google Scholar 

  6. Lemaux, S., Bensaddik, A., van der Eerden, A.M.J., Bitter, J.H., and Koningsberger, D.C., J. Phys. Chem. B, 2001, vol. 105, p. 4810.

    Article  CAS  Google Scholar 

  7. Han, X.X., Chen, Q., and Zhou, R.X., J. Mol. Catal. A: Chem., 2007, vol. 277, p. 210.

    Article  CAS  Google Scholar 

  8. Li, J., Han, Y.X., Zhu, Y.H., and Zhou, R.X., Appl. Catal., B, 2011, vols. 108–109, p. 72.

    Google Scholar 

  9. **, Y., Reed, C., Lee, Y.K., and Oyama, S.T., J. Phys. Chem. B, 2005, vol. 109, p. 17587.

    Article  CAS  Google Scholar 

  10. Chen, M., Zheng, H., Shi, C.M., Zhou, R.X., and Zheng, X.M., J. Mol. Catal. A: Chem., 2008, vol. 237, p. 132.

    Article  Google Scholar 

  11. Biz, S. and Occelli, M.L., Catal. Rev. Sci. Eng., 1998, vol. 40, p. 329.

    Article  CAS  Google Scholar 

  12. Corma, A., Chem. Rev., 1997, vol. 97, p. 2373.

    Article  CAS  Google Scholar 

  13. Shigapov, A.N., Graham, G.W., McCabe, R.W., and Plummer, H.K., Jr., Appl. Catal., A, 2001, vol. 210, p. 287.

    Article  CAS  Google Scholar 

  14. Wu, D.D., Guo, J.X., Li, Y., Gong, M.C., and Chen, Y.Q., Chin. J. Catal., 2010, vol. 31, p. 567.

    CAS  Google Scholar 

  15. Chen, M., Chen, F., and Zheng, X.M., Chin. J. Inorg. Chem., 2004, vol. 20, p. 647.

    CAS  Google Scholar 

  16. Chen, M., Fan, L.P., and Zheng, X.M., J. Rare Earths, 2006, vol. 24, p. 447.

    Article  CAS  Google Scholar 

  17. Persson, K., Jansson, K., and Jaras, S.G., J. Catal., 2007, vol. 245, p. 401.

    Article  CAS  Google Scholar 

  18. Machida, M., Uto, M., Kurogi, D., and Kijima, Ts., J. Mater. Chem., 2000, vol. 12, p. 3158.

    Article  CAS  Google Scholar 

  19. Machida, M., Uto, M., Kurogi, D., and Kijima, Ts., J. Mater. Chem., 2001, vol. 11, p. 900.

    Article  CAS  Google Scholar 

  20. Zayat, M. and Levy, D., J. Sol-Gel Sci. Technol., 2002, vol. 25, p. 201.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Zhejiang University, **xi Campus, 310028, Hangzhou, China

    **ang-**ang Li, Min Chen & **ao-Ming Zheng

Authors
  1. **ang-**ang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Min Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. **ao-Ming Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Kinetika i Kataliz, 2013, Vol. 54, No. 5, pp. 604–610.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, XX., Chen, M. & Zheng, XM. Preparation and characterization of a novel washcoat material and supported Pd catalysts. Kinet Catal 54, 572–577 (2013). https://doi.org/10.1134/S0023158413050108

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158413050108

Keywords

Search

Navigation