Log in

Ethane aromatization on galloaluminosilicate modified with platinum and palladium

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

Ethane conversion into aromatic hydrocarbons on galloaluminosilicate of the ZSM-5 structural type modified with platinum and palladium was studied. The acid properties of the catalyst were investigated by ammonia temperature-programmed desorption. The microstructure and composition of the Pt- and Pd-containing zeolites was determined by transmission electron microscopy and energy-dispersive X-ray analysis. It was shown that modifying the galloaluminosilicate enhances its activity and selectivity in the formation of aromatic hydrocarbons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Dorogochinskii, A.Z., Proskurnin, A.L., Ovcharov, S.N., and Krupina, N.N., Aromatizatsiya nizkomolekulyarnykh parafinovykh uglevodorodov na tseolitnykh katalizatorakh: Obzornaya informatsiya (Aromatization of Light Paraffins over Zeolite Catalysts: A Review), Moscow: TsNIITEneftekhim, 1989, issue 4.

    Google Scholar 

  2. Minachev, Kh.M. and Dergachev, A.A., Usp. Khim., 1990, vol. 59, no. 9, p. 1522.

    Article  CAS  Google Scholar 

  3. Erofeev, V.I., Vosmerikov, A.V., Korobitsyna, L.L., and Solov’ev, A.I., Neftekhimiya, 1990, vol. 30, no. 4, p. 496.

    CAS  Google Scholar 

  4. Minachev, Kh.M. and Dergachev, A.A., Izv. Akad. Nauk, Ser. Khim., 1993, no. 6, p. 1018.

  5. Minachev, Kh.M. and Dergachev, A.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1998, no. 6, p. 1071.

  6. Vosmerikov, A.V., Ermakov, A.E., Vosmerikova, L.N., Fedushchak, T.A., and Ivanov, G.V., Kinet. Catal., 2004, vol. 45, no. 2, p. 215.

    Article  CAS  Google Scholar 

  7. Dergachev, A.A. and Lapidus, A.L., Ross. Khim. Zh., 2008, vol. 52, no. 4, p. 15.

    CAS  Google Scholar 

  8. Vosmerikova, L.N., Ryabova, N.V., and Vosmerikov, A.V., Neftepererab. Neftekhim., 2008, no. 2, p. 35.

  9. Vosmerikov, A.V. and Erofeev, V.I., Zh. Fiz. Khim., 1995, vol. 69, no. 5, p. 787.

    CAS  Google Scholar 

  10. Vosmerikova, L.N. and Vosmerikov, A.V., Gazokhimiya, 2011, no. 1 (17), p. 24.

  11. Diaz, Y., Melo, L., Mediavilla, M., Albornoz, A., and Britoa, J.L., J. Mol. Catal. A: Chem., 2005, vol. 227, p. 7.

    Article  CAS  Google Scholar 

  12. Melo, L., Diaz, Y., Mediavilla, M., Llanos, A., Albornoz, A., and Brito, J.L., Catal. Today, 2008, vol. 133–135, p. 99.

    Article  Google Scholar 

  13. Mediavilla, M., Melo, L., Diaz, Y., Albornoz, A., Llanos, A., and Brito, J.L., Microporous Mesoporous Mater., 2008, vol. 116, p. 627.

    Article  CAS  Google Scholar 

  14. Mikhailov, M.N., Mishin, I.V., Kustov, L.M., and Lapidus, A.L., Microporous Mesoporous Mater., 2007, vol. 104, p. 145.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Vosmerikov.

Additional information

Original Russian Text © V.I. Zaikovskii, L.N. Vosmerikova, A.V. Vosmerikov, 2012, published in Kinetika i Kataliz, 2012, Vol. 53, No. 6, pp. 778–784.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaikovskii, V.I., Vosmerikova, L.N. & Vosmerikov, A.V. Ethane aromatization on galloaluminosilicate modified with platinum and palladium. Kinet Catal 53, 731–736 (2012). https://doi.org/10.1134/S0023158412060122

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158412060122

Keywords

Navigation