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An Antipyrine Based Fluorescent Probe and Selective Detection of Hg2+ AND Ag+

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Abstract

The fluorescence-enhanced probe was synthesized based on 4-aminoantipyrine and 2-hydroxy-1-naphthalaldehyde. The structure was characterized by NMR, ESI-MS, IR and X-ray single-crystal diffraction. The fluorescent probe HL1 synthesized in this thesis have recognition performance for Hg2+ and Ag+ in acetonitrile solution, with HL1 allowing visual detection of Hg2+. Their recognition properties and mechanisms were examined and investigated using fluorescence spectroscopy and ESI-MS. The binding ratios between the probe and the response ions were 1:1, while the detection limits for the response ions both reached 10–8 M and below, with the potential to detect actual samples.

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Funding

This work supported by the Hubei Key Laboratory of Pollutant Analysis & Reuse Technology (Grant No. PA150203), the Hubei provincial Department of Education (Grant No. B2019133).

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Authors and Affiliations

  1. Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering of Hubei Normal University, Huangshi, Hubei, People’s Republic of China

    Y. Zhou, J. -W. Cao & D. -H. Zhang

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  1. Y. Zhou
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  2. J. -W. Cao
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  3. D. -H. Zhang
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Correspondence to D. -H. Zhang.

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Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 1, 120025.https://doi.org/10.26902/JSC_id120025

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Zhou, Y., Cao, J.W. & Zhang, D.H. An Antipyrine Based Fluorescent Probe and Selective Detection of Hg2+ AND Ag+. J Struct Chem 65, 28–35 (2024). https://doi.org/10.1134/S0022476624010037

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  • DOI: https://doi.org/10.1134/S0022476624010037

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