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HIGH-VALENCE CLUSTER COMPOUNDS OF TRANSITION METALS CONTAINING INTERSTITIAL HETEROATOMS: GEOMETRY, ELECTRONIC STRUCTURE, AND PHYSICOCHEMICAL PROPERTIES

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Abstract

The article reviews the current state of the chemistry of high-valence cluster compounds of group 3-7 transition metals containing interstitial heteroatoms. The synthesis methods, reactivity, main structural types, and electronic structure of resulting compounds are discussed.

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Funding

The reported study was funded by RFBR, project number  19-13-50318.

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Ya. M. Gayfulin, Yu. V. Mironov & N. G. Naumov

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  1. Ya. M. Gayfulin
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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 3, pp. 355-381.https://doi.org/10.26902/JSC_id69875

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Gayfulin, Y.M., Mironov, Y.V. & Naumov, N.G. HIGH-VALENCE CLUSTER COMPOUNDS OF TRANSITION METALS CONTAINING INTERSTITIAL HETEROATOMS: GEOMETRY, ELECTRONIC STRUCTURE, AND PHYSICOCHEMICAL PROPERTIES. J Struct Chem 62, 331–355 (2021). https://doi.org/10.1134/S002247662103001X

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