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Inhibition of Photodegradation Processes by Additive of Fluorinated Carbon Nanotubes into the Active Layer of Organic Photovoltaic Cells

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Abstract

The composites based on a semiconducting polymer and a modified fullerene were deposited as active layers of organic photovoltaic cells (OPCs). Fluorinated carbon nanotubes were added into the composite according to the procedure described previously [Kobeleva, E.S. et al., Fuller. Nanotub. 31, 464 (2023)]. The admixture inhibited photodegradation processes within OPC samples. This phenomenon is due to several reasons, in particular, the fixation of the optimal nanostructure of the bulk polymer : fullerene heterojunction and inhibition of the processes of morphological degradation of the active layer.

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ACKNOWLEDGMENTS

Authors are thankful to Multi-Access Chemical Service Center SB RAS for carrying out spectral and analytical measurements, the Center for Collective Use “Nanostructures” of the Institute of Semiconductor Physics SB RAS, and the Core Facilities “VTAN” Novosibirsk State University for providing the equipment for deposition of functional OPC layers.

Funding

The study was supported by the Russian Science Foundation, project no. 23-73-00072. https://rscf.ru/project/23-73-00072/.

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Authors and Affiliations

  1. V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    N. V. Kravets, E. S. Kobeleva, L. V. Kulik & M. N. Uvarov

  2. Novosibirsk National Research State University, 630090, Novosibirsk, Russia

    N. V. Kravets, D. A. Nevostruev & D. E. Utkin

  3. A.V. Rzhanov Institute of Semiconductor Physics, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    D. E. Utkin

  4. Siberian Physico-Technical Institute, Tomsk State University, 634050, Tomsk, Russia

    K. M. Degtyarenko

Authors
  1. N. V. Kravets
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  2. D. A. Nevostruev
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  3. E. S. Kobeleva
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  4. D. E. Utkin
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  5. K. M. Degtyarenko
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  6. L. V. Kulik
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  7. M. N. Uvarov
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Correspondence to M. N. Uvarov.

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Kravets, N.V., Nevostruev, D.A., Kobeleva, E.S. et al. Inhibition of Photodegradation Processes by Additive of Fluorinated Carbon Nanotubes into the Active Layer of Organic Photovoltaic Cells. High Energy Chem 57 (Suppl 3), S426–S432 (2023). https://doi.org/10.1134/S0018143923090084

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  • DOI: https://doi.org/10.1134/S0018143923090084

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