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Preparation and Characterization of Mechanically Strong Nanocomposite Latex Materials Based on Polyurethane/Graphene Oxide

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Abstract

Nanocomposites based on aqueous polyurethane latex and graphene oxide have been synthesized and characterized. The structure and composition of the nanocomposites were studied using elemental analysis, optical microscopy, IR spectroscopy, DSC, and thermogravimetry. The nanocomposites showed higher thermal stability and increased mechanical strength compared to those of the original polymer. It has been established that the Young’s modulus of latex films after the introduction of 2 wt % graphene oxide increased by a factor of almost 6. In this case, the fracture stress decreased only slightly by 10–15%. The influence of the particle size of graphene oxide on the mechanical properties of the composites was found, namely: composites with larger particles of graphene oxide had a higher Young’s modulus, and their relative elongation at break decreased.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of state contracts (state registration nos. АААА-А19-119032690060-9 and 122040500074-1). S.A.B. acknowledges the support of the Russian Science Foundation (project no. 22-13-00410).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    S. A. Baskakov, Yu. V. Baskakova, E. V. Dvoretskaya, S. S. Krasnikova, V. A. Lesnichaya & Yu. M. Shulga

  2. Chernogolovka Branch of Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. N. Vasilets

Authors
  1. S. A. Baskakov
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  2. Yu. V. Baskakova
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  3. E. V. Dvoretskaya
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  4. S. S. Krasnikova
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  5. V. A. Lesnichaya
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  6. Yu. M. Shulga
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  7. V. N. Vasilets
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Correspondence to V. N. Vasilets.

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Translated by V. Makhlyarchuk

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Baskakov, S.A., Baskakova, Y.V., Dvoretskaya, E.V. et al. Preparation and Characterization of Mechanically Strong Nanocomposite Latex Materials Based on Polyurethane/Graphene Oxide. High Energy Chem 57, 217–223 (2023). https://doi.org/10.1134/S0018143923020042

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  • DOI: https://doi.org/10.1134/S0018143923020042

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