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Unconventional Approach to the Synthesis of Nickel and Platinum Complexes of 1,3,6-Azadiphosphacycloheptanes

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Abstract

A new method has been proposed for the synthesis of bis(phosphine sulfides) and nickel and platinum chelate complexes of 1,3,6-azadiphosphacycloheptanes. The method is based on the ability of 14-membered 3,6,10,13-diazadiphosphacyclotetradecanes to undergo a reversible transformation in solutions into a mixture of meso- and rac-isomers of seven-membered bis-phosphines. The reaction of 3,6,10,13-diazadiphosphacyclotetradecanes with elementary sulfur results in 14-membered tetrakis(phosphine sulfides) or seven-membered bis(phosphine sulfides), depending on the reaction conditions. The reaction of 1,3,6-azadiphosphacycloheptanes, resulting from the reversible dissociation of 14-membered tetraphosphines in chloroform, with Ni(CH3CN)6(BF4)2 and Pt(COD)Cl2 gives the corresponding chelate complexes. The structures of the meso-isomer of 1-cyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane-3,6-disulfide, bis-(κ2-1-isopropyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)nickel bis(tetrafluoroborate), bis-(κ2-1-cyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)chloronickel tetrafluoroborate, and cis-dichloro-(κ2-1-cyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)platinum(II), isolated in crystalline form, have been confirmed by single crystal X-ray diffraction.

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ACKNOWLEDGMENTS

The authors are grateful to the Center of Collective Use for Physicochemical Studies of Structure and Properties at Kazan Scientific Center, RAS, for technical support of the research.

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This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    E. I. Musina, I. D. Strelnik, I. A. Litvinov &  A. A. Karasik

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  1. E. I. Musina
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  2. I. D. Strelnik
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  3. I. A. Litvinov
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  4. A. A. Karasik
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Correspondence to E. I. Musina.

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Dedicated to the Anniversary of Academician Irina Petrovna Beletskaya

Translated by G. Kirakosyan

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Musina, E.I., Strelnik, I.D., Litvinov, I.A. et al. Unconventional Approach to the Synthesis of Nickel and Platinum Complexes of 1,3,6-Azadiphosphacycloheptanes. Dokl Chem 513, 342–350 (2023). https://doi.org/10.1134/S0012500823600827

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