Abstract
The results of numerical calculations of the variability of number concentrations of aerosol particles of different sizes and the rates of ion-induced nucleation and binary nucleation of sulfuric acid and water vapors are presented. The calculations were performed using a new three-dimensional model of regional transport and transformation of gaseous species and aerosols in the atmosphere, incorporating photochemistry, nucleation with the participation of neutral molecules and ions, condensation/evaporation, and coagulation processes. The numerical results indicate that ion-induced nucleation in wintertime plays a significant role in aerosol formation, especially in the lower troposphere and lower stratosphere over the Northern Hemisphere. Along with the level of air ionization, temperature and relative humidity are among the key factors controlling the dynamics of ionic processes in the atmosphere and their impact on the spatiotemporal distribution of aerosol particles.
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REFERENCES
J. H. Seinfeld and S. N. Pandis, Atmospheric Chemistry and Physics. From Air Pollution to Climate Change (Wiley-Interscience, New York, 1997).
H. Akimoto, Atmospheric Reaction Chemistry (Springer, 2016).
D. Lowe and R. MacKenzie, “Review of polar stratospheric cloud microphysics and chemistry,” J. Atmos. Sol.-Terr. Phys. 70 (1), 13–40 (2008).
A. E. Aloyan, A. N. Yermakov, and V. O. Arutyunyan, “Formation of sulfate aerosols in the troposphere and lower stratosphere,” in Study of the Possibility of Climate Stabilization with New Technologies. Problems of Adaptation to Climate Change (Rosgidromet, Moscow, 2012), pp. 75–98 [in Russian].
A. E. Aloyan, A. N. Yermakov, and V. O. Arutyunyan, “Aerosols in the troposphere and lower stratosphere. Sulfate particles in northern latitudes,” Opt. Atmos. Okeana 31 (2), 136–142 (2018).
A. E. Aloyan, “Mathematical modeling of the interaction of gas species and aerosols in atmospheric dispersive systems,” Russ. J. Numer. Anal. Math. Modell. 15 (1–4), 211–224 (2000).
J. Kirkby, J. Curtius, J. Almeida, et al., “Role of sulphuric acid, ammonia, and galactic cosmic rays in atmospheric aerosol nucleation,” Nature 476, 429–433 (2011).
A. E. Aloyan, A. N. Yermakov, and V. O. Arutyunyan, “Modeling the influence of ions on the dynamics of formation of atmospheric aerosol,” Izv., Atmos. Ocean. Phys. 57 (1), 104–109 (2021).
Y. Kurihara and R. E. Televa, “Structure of tropical cyclone developed in three-dimensional numerical simulation model,” J. Atmos. Sci. 31 (5), 893–919 (1974).
E. E. Ferguson, “Ion–molecule reactions in the atmosphere,” in Kinetics of Ion–Molecule Reactions, Ed. by P. Ausloos (Springer, Boston, 1979), pp. 377–403.
K. D. Froyd and E. R. Lovejoy, “Experimental thermodynamics of cluster ions composed of H2SO4 and H2O. 1. Positive ions,” J. Phys. Chem. A 107 (45), 9800–9811 (2003).
F. Yu, “Ion-mediated nucleation in the atmosphere: Key controlling parameters, implications, and look-up table,” Geol. Soc. Am. Bull. 115, D03206 (2010).
D. J. Hofmann, “Measurement of the concentration nuclei profile to 31 km in the Arctic in January and comparison with Antarctic measurements,” Geophys. Res. Lett. 17 (4), 357–360 (1990).
A. E. Aloyan, Modeling the Dynamics and Kinetics of Gaseous Pollutants and Aerosols in the Atmosphere (Nauka, Moscow, 2008) [in Russian].
Funding
This study was supported by the Russian Foundation for Basic Research (project no. 19-05-50007) (Mikromir) and by state orders to the Marchuk Institute of Numerical Mathematics, Russian Academy of Sciences, and Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences (project no. AAAA-0047-2018-0012).
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Translated by V. Arutyunyan
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Aloyan, A.E., Yermakov, A.N. & Arutyunyan, V.O. Modeling the Regional Influence of Ions on Aerosol Formation in the Atmosphere. Izv. Atmos. Ocean. Phys. 58, 246–253 (2022). https://doi.org/10.1134/S000143382203001X
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DOI: https://doi.org/10.1134/S000143382203001X