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Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands

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Abstract

Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum-chemical calculations. Probable sites of localization of electronic changes in the molecules of these complexes under electrochemical oxidation and reduction were determined.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    T. V. Magdesieva, D. N. Kravchuk, K. P. Butin & V. I. Sokolov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. V. Bashilov & F. M. Dolgushin

Authors
  1. T. V. Magdesieva
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  2. V. V. Bashilov
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  3. D. N. Kravchuk
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  4. F. M. Dolgushin
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  5. K. P. Butin
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  6. V. I. Sokolov
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Magdesieva, T.V., Bashilov, V.V., Kravchuk, D.N. et al. Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands. Russian Chemical Bulletin 53, 795–799 (2004). https://doi.org/10.1023/B:RUCB.0000037844.93864.3c

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  • DOI: https://doi.org/10.1023/B:RUCB.0000037844.93864.3c

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