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X-ray diffraction study of zirconia pillared clays

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Abstract

X-ray powder diffraction (XRPD) and X-ray radial electronic distribution density (RED) of initial and zirconia-pillared interlayered clays (Zr-PILC) were studied. After pillaring, the basal (001) spacing was found to increase from 11 Å in the initial clay kept under air to 17.7 Å in Zr-PILC. The structure of zirconium nanopillars was characterized. The interatomic distances with corresponding coordination numbers obtained from the RED curves were close to those in zirconium tetramers.

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Zyuzin, D., Moroz, E., Kuznetsova, T. et al. X-ray diffraction study of zirconia pillared clays. Reaction Kinetics and Catalysis Letters 81, 137–142 (2004). https://doi.org/10.1023/B:REAC.0000016527.92435.63

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  • DOI: https://doi.org/10.1023/B:REAC.0000016527.92435.63

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