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Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass

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Abstract

New methods are proposed for the gas-chromatographic determination of the molecular masses of unknown components in complex mixtures within one cycle of analysis. The methods are based on the use of complex chromatographic data in the form of linear retention indices of compounds for a column with a nonpolar stationary phase and sensitivity indices of a thermal conductivity detector and a flame ionization detector.

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Authors and Affiliations

  1. Department of Chemistry, Samara State University, ul. Akademika Pavlova 1, Samara, 443011, Russia

    Yu. I. Arutyunov, S. Yu. Kudryashov & L. A. Onuchak

Authors
  1. Yu. I. Arutyunov
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  2. S. Yu. Kudryashov
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  3. L. A. Onuchak
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Arutyunov, Y.I., Kudryashov, S.Y. & Onuchak, L.A. Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass. Journal of Analytical Chemistry 59, 358–365 (2004). https://doi.org/10.1023/B:JANC.0000022789.02629.eb

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  • DOI: https://doi.org/10.1023/B:JANC.0000022789.02629.eb

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