Abstract
A plausible reaction pathway for maleic anhydride (MA) hydrogenation is firstly proposed, which suggests that the CH4 is produced by the methanation of CO formed during the reaction rather than direct de-carbonization of tetrahydrofuran, and MA cannot be directly decyclized, subsequently de-carbonized to C3 compounds and CO. This work sheds light on the superficial phenomenon for MA liquid hydrogenation reported by other researchers, and may better explain the reaction process both in liquid and vapor phase MA hydrogenation. These results are important to understand the mechanism and reaction pathway of MA hydrogenation, and to facilitate the decrease of production cost in industrial plant.
Similar content being viewed by others
References
N. Harris and M.W. Tuck, Hydrocarbon Process 69 (1990) 79.
N.J. Kerrigan, P.C. Hutchison, T.D. Heightman and D.J. Procter, Chem. Commun.1402(2003).
R. Grigg and V. Savic, Chem. Commun.2381(2000).
J.L., D.-J. Choo and Y.H. Kim, Chem. Commun.55(2000).
Y. Hara, H. Kusaka, H. Inagaki, K. Takahashi and K. Wada, J. Catal. 194 (2000) 188.
A. Kuksal, E. Elemm and G. Emig, Appl. Catal. A: Gen. 228 (2002) 237.
U.R. Pillai and E. Sahle-Demessie, Chem. Commun.422 (2002).
U.R. Pillai, E. Sahle-Demessie and D. Young, Appl. Catal. B: Environ. 43 (2003) 131.
A. Cybulski, J. Chrzaszcz and M.V. Twigg, Catal. Today 69 (2001) 241.
S.M. Jung, E. Godard, S.Y. Jung, K.-C. Park and J.U. Choi, Catal. Today 87 (2003) 171.
Y.-L. Zhu, H.-W. **ang, Y.-W. Li, H. Jiao, G.-S. Wu, B. Zhong and G.-Q. Guo, New J. Chem. 27 (2003) 208.
Y.-L. Zhu, H.-W. **ang, G.-S. Wu, L. Bai and Y.-W. Li, Chem. Commun. 254 (2002).
G.L. Castiglioni and C. Fumagalli, US Patent 6297389, 2001).
M. Bergfeld and G. Wiesgickl, US Patent 5536849, 1996).
M.J. Bergfeld and K. Uihlein, US Patent 6075153, (2000).
R.W. Wegman and D.R. Bryant, US Patent 5142067, 1992).
J. Kanetaka, T. Asano and S. Masamune, Ind. Eng. Chem. 62 (1970) 24.
R.M. Deshpande, V.V. Buwa, C.V. Rode, R.V. Chaudhari and P.L. Mills, Catal. Commun. 3 (2002) 269.
M. Messori and A. Vaccari, J. Catal. 150 (1994) 177.
S. Minoda and M. Makoto, Hydrocarbon Process 69 (1990) 176.
U. Herrmann and G. Eming, Ind. Eng. Chem. Res. 37 (1998) 759.
S.P. Müller, M. Kucher, C. Ohlinger and B. Kraushaar-Czarnetzki, J. Catal. 218 (2003) 419.
G.L. Castiglioni, M. Ferrari, A. Guercio, A. Vaccari, R. Lancia and C. Fumagalli, Catal. Today 27 (1996) 181.
V. Pallassana, M. Neurock and G. Coulston, Catal. Today 50 (1999) 589.
K. klusacek and V. Stuchly, Catal. Today 25 (1995) 169.
H. Habazaki, M. Yamasaki, B.P. Zhang, A. Kawashima, S. Kohno, T. Takai and K. Hashimoto, Appl. Catal. A: Gen. 172 (1998) 131.
S.I. Fujiti and N. takezawa, Chem. Eng. J. 68 (1997) 63.
S. Freni, S. Cavallaro, N. Mondello, L. Spadaro and F. Frusteri, J. Power Sources, 108 (2002) 53.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhu, YL., Zhao, GW., Chang, J. et al. New Insight for Reaction Route of Hydrogenation of Maleic Anhydride to γ-Butyrolactone. Catalysis Letters 96, 123–127 (2004). https://doi.org/10.1023/B:CATL.0000030109.02546.3f
Issue Date:
DOI: https://doi.org/10.1023/B:CATL.0000030109.02546.3f