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A novel study on the adsorption of low concentration Cd(II) and Ni(II) using porous boron nitride: effectiveness, coexisting anion interference, and regeneration

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Abstract

The difficulty of removing low-concentration heavy metals from wastewater and the impact of coexisting anions on adsorption and regeneration performance has been widely recognized. To address this challenge, we synthesized a new adsorbent called porous boron nitride (PBN) and characterized it with X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and nitrogen isothermal adsorption–desorption isotherms. Then, the adsorption kinetics and equilibrium models of PBN for Cd(II) and Ni(II) with a concentration as low as 10 mg/L, along with the impact of anions on adsorption performance and the regeneration of PBN, were investigated. The findings indicated that PBN achieved adsorption equilibrium for Cd(II) and Ni(II) in just 5 min. Furthermore, the adsorption processes fit better with the pseudo-second order kinetic model and the Freundlich isothermal model. Especially, we found that the presence of SO42− inhibited the adsorption of Cd(II) and Ni(II), whereas SiO32−, CO32−, and PO43− promoted adsorption by forming a PBN-anion-metal ternary complex. We determined that the adsorption mechanism involved electrostatic attraction and chemisorption. After regeneration, PBN retained its crystal structure and typical pore distribution, demonstrating excellent adsorption performance for heavy metals.

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References

  • Bai XS, Lin JW, Zhang ZB, Zhan YH (2022) Immobilization of lead, copper, cadmium, nickel, and zinc in sediment by red mud: adsorption characteristics, mechanism, and effect of dosage on immobilization efficiency. Environ Sci Pollut Res 29:51793–51814

    Article  CAS  Google Scholar 

  • Buema G, Lupu N, Chiriac H, Ciobanu G, Bucur RD, Bucur D, Favier L et al (2021a) Performance assessment of five adsorbents based on fly ash for removal of cadmium ions. J Mol Liq 333:15–15

    Article  Google Scholar 

  • Buema G, Borhan AI, Herea DD, Stoian G, Chiriac H, Lupu N, Roman T et al (2021b) Magnetic solid-phase extraction of cadmium ions by hybrid self-assembled multicore type nanobeads. Polymers 13:15–15

    Article  Google Scholar 

  • Calderón OAR, Abdeldayem OM, Pugazhendhi A, Rene ER (2020) Current updates and perspectives of biosorption technology: an alternative for the removal of heavy metals from wastewater. Curr Pollut Rep 6:8–27

    Article  Google Scholar 

  • Celebi H, Gok G, Gok O (2020) Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions. Sci Rep 10:17570

    Article  ADS  CAS  PubMed  PubMed Central  Google Scholar 

  • Chen G, Shah KJ, Shi L, Chiang PC (2017) Removal of Cd(II) and Pb(II) ions from aqueous solutions by synthetic mineral adsorbent: Performance and mechanisms. Appl Surf Sci 409:296–305

    Article  ADS  CAS  Google Scholar 

  • Egbosiuba TC, Egwunyenga MC, Tijani JO, Mustapha S, Abdulkareem AS, Kovo AS, Krikstolaityte V et al (2022) Activated multi-walled carbon nanotubes decorated with zero valent nickel nanoparticles for arsenic, cadmium and lead adsorption from wastewater in a batch and continuous flow modes. J Hazard Mater 423:126993

    Article  CAS  PubMed  Google Scholar 

  • Feng XF, Long RX, Wang LL, Liu CC, Bai ZX, Liu XB (2022) A review on heavy metal ions adsorption from water by layered double hydroxide and its composites. Sep Purif Technol 284:120099

    Article  CAS  Google Scholar 

  • Freundlich H (1907) Uber die adsorption in losungen. J Phys Chem 57:385

    CAS  Google Scholar 

  • He J, Li Y, Wang C, Zhang K, Liu J (2017) Rapid adsorption of Pb, Cu and Cd from aqueous solutions by β-cyclodextrin polymers. Appl Surf Sci 426:29–39

  • Hwang SY, Lee GB, Kim JH, Hong BU, Park JE (2020) Pre-treatment methods for regeneration of spent activated carbon. Molecules 25:4561

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Khanam R, Kumar A, Nayak AK, Shahid M, Tripathi R, Vijayakumar S, Bhaduri D et al (2020) Metal(loid)s (As, Hg, Se, Pb and Cd) in paddy soil: bioavailability and potential risk to human health. Sci Total Environ 699:134330

    Article  ADS  CAS  PubMed  Google Scholar 

  • Kong J, Gu R, Yuan J, Liu W, Wu J, Fei Z (2018) Adsorption behavior of Ni(II) onto activated carbons from hide waste and high-pressure steaming hide waste. Ecotox Environ Safe 156:294–300

    Article  CAS  Google Scholar 

  • Kumar A, Song HW, Mishra S, Zhang W, Zhang YL, Zhang QR, Yu ZG (2023) Application of microbial-induced carbonate precipitation (MICP) techniques to remove heavy metal in the natural environment: a critical review. Chemosphere 318:137894

    Article  CAS  PubMed  Google Scholar 

  • Kumar R, Sharma RK, Singh AP (2019) Sorption of Ni (II), Pb (II) and Cu (II) ions from aqueous solutions by cellulose grafted with poly (HEMA-co-AAc): kinetic, isotherm and thermodynamic study. J Environ Chem Eng 7(3):103088

    Article  Google Scholar 

  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40(9):1361–1403

    Article  CAS  Google Scholar 

  • Lee SY, Choi HJ (2018) Persimmon leaf bio-waste for adsorptive removal of heavy metals from aqueous solution. J Environ Manage 209:382–392

    Article  CAS  PubMed  Google Scholar 

  • Lekgoba T, Ntuli F, Falayi T (2021) Application of coal fly ash for treatment of wastewater containing a binary mixture of copper and nickel. J Water Process Eng 40:12–12

    Article  Google Scholar 

  • Li J, Lin J, Xu X, Zhang X, Xue Y, Mi J (2013a) Porous boron nitride with a high surface area: hydrogen storage and water treatment. Nanotechnology 24(15):155603

    Article  ADS  PubMed  Google Scholar 

  • Li J, **ao X, Xu X, Lin J, Huang Y, Xue Y, ** P, Zou J, Tang C (2013b) Activated boron nitride as an effective adsorbent for metal ions and organic pollutants. Sci Rep 3:3208

    Article  ADS  PubMed  PubMed Central  Google Scholar 

  • Lin J, Su B, Sun M, Chen B, Chen Z (2018) Biosynthesized iron oxide nanoparticles used for optimized removal of cadmium with response surface methodology. Sci Total Environ 627:314–321

    Article  ADS  CAS  PubMed  Google Scholar 

  • Liu T, Li Y, He J, Zhang K, Yi Hu, Chen X (2019a) Few-layered boron nitride nanosheets as superior adsorbents for the rapid removal of lead ions from water. J Mater Sci 54(7):5366–5380

    Article  ADS  CAS  Google Scholar 

  • Liu T, Li Y, He J (2019b) Porous boron nitride nanoribbons with large width as superior adsorbents for the rapid removal of cadmium and copper ions from water. New J Chem 43(8):3280–3290

    Article  ADS  CAS  Google Scholar 

  • Madawala CK, Jahinge THL, Rathnayake KT, Perera BA (2023) Adsorption of cadmium (II) from aqueous solutions by coconut dregs residue: kinetic and thermodynamic studies. Sep Sci Technol 58:1972–1984

    Article  CAS  Google Scholar 

  • Mcbride MB (1994) Environmental chemistry of soils. Oxford University Press, Oxford, pp 4–7

    Google Scholar 

  • Tempkin MI, Pyzhev V (1940) Kinetics of ammonia synthesis on promoted iron catalyst. Acta Physiochim URSS 12:327–356

    Google Scholar 

  • Qasem NAA, Mohammed RH, Lawal DU (2021) Removal of heavy metal ions from wastewater: a comprehensive and critical review. NPJ Clean Water 4:36

    Article  CAS  Google Scholar 

  • Qiu M, He C (2019) Efficient removal of heavy metal ions by forward osmosis membrane with a polydopamine modified zeolitic imidazolate framework incorporated selective layer. J Hazard Mater 367:339–347

    Article  CAS  PubMed  Google Scholar 

  • Reddy TV, Chauhan S, Chakraborty S (2017) Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake. Engviron Eng Res 22(1):95–107

    Article  Google Scholar 

  • Redlich O, Peterson DL (1959) A useful adsorption isotherm. J Phys Chem 63(6):1024–1024

    Article  CAS  Google Scholar 

  • Song Q, Liang J, Fang Y (2020) Nickel(II) modified porous boron nitride: an effective adsorbent for tetracycline removal from aqueous solution. Chem Eng J 394:124985

    Article  CAS  Google Scholar 

  • Sun H, Shi B, Yang F, Wang D (2017) Effects of sulfate on heavy metal release from iron corrosion scales in drinking water distribution system. Water Res 114:69–77

    Article  CAS  PubMed  Google Scholar 

  • Tan Y, Yin X, Wang C, Sun H, Ma A, Zhang G, Wang N (2019) Sorption of cadmium onto Mg-Fe Layered Double Hydroxide (LDH)-Kiwi branch biochar. Env Pollut Bioavail 31:189–197

    Article  CAS  Google Scholar 

  • Thommes M, Kaneko K, Neimark A, Olivier J, Rodriguez-Reinoso F, Rouquerol J, Sing K (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87:1051–1069

    Article  CAS  Google Scholar 

  • Tiberg C, Sjöstedt C, Persson I, Gustafsson JP (2013) Phosphate effects on copper(II) and lead(II) sorption to ferrihydrite. Geochim Cosmochim Acta 120:140–157

    Article  ADS  CAS  Google Scholar 

  • Velarde L, Nabavi MS, Escalera E, Antti ML, Akhtar F (2023) Adsorption of heavy metals on natural zeolites: a review. Chemosphere 328:138508

    Article  CAS  PubMed  Google Scholar 

  • Wang H, Wang W, Wang H, Zhang F, Fu Z (2018) Urchin-like boron nitride hierarchical structure assembled by nanotubes-nanosheets for effective removal of heavy metal ions. Ceram Int 44:12216–12224

    Article  CAS  Google Scholar 

  • Wang M, Bai Y, Zhang B, Zhong B, Yu Y, Zhang J, Huang X, Wen G (2019) Large scale fabrication of porous boron nitride microrods with tunable pore size for superior copper (II) ion adsorption. Ceram Int 45:6684–6692

    Article  CAS  Google Scholar 

  • Wang W, Zhou J, Achari G, Yu J, Cai W (2014a) Cr(VI) removal from aqueous solutions by hydrothermal synthetic layered double hydroxides: Adsorption performance, coexisting anions and regeneration studies. Colloid Surf A-Physicochem Eng Asp 457:33–40

    Article  CAS  Google Scholar 

  • Wang Y, Wang S, Sun H, Lei J, Ye T, Lin L, Wang L (2014b) Crayfish carapace powder adsorbing heavy metal ions from aqueous solution: capacity, characterization, mechanism. J Aquat Food Prod Technol 25:122–130

    Article  Google Scholar 

  • **ang J, Lin Q, Cheng S, Guo J, Yao X, Liu Q, Yin G et al (2018) Enhanced adsorption of Cd(II) from aqueous solution by a magnesium oxide-rice husk biochar composite. Environ Sci Pollut Res 25:14032–14042

    Article  CAS  Google Scholar 

  • Xu C, Zeng J, Gu X, Wang Y, Li E, Zhang C, Ge C et al (2022) Porous monolith of few-layered boron nitride for effective water cleanup. J Mater Chem A 10:846–854

    Article  CAS  Google Scholar 

  • Xue L, Lu B, Wu Z, Ge C, Wang P (2014) Synthesis of mesoporous hexagonal boron nitride fibers with high surface area for efficient removal of organic pollutants. Chem Eng J 243:494–499

    Article  CAS  Google Scholar 

  • Yang GX, Jiang H (2014) Amino modification of biochar for enhanced adsorption of copper ions from synthetic wastewater. Water Res 48:396–405

    Article  CAS  PubMed  Google Scholar 

  • Yaqub M, Lee SH (2019) Heavy metals removal from aqueous solution through micellar enhanced ultrafiltration: A review. Environ Eng Res 24:363–375

    Article  Google Scholar 

  • Zamora-Ledezma C, Negrete-Bolagay D, Figueroa F, Zamora-Ledezma E, Ni M, Alexis F, Guerrero VH (2021) Heavy metal water pollution: a fresh look about hazards, novel and conventional remediation methods. Environ Technol Innovation 22:101504

  • Zhou G, Luo J, Liu C, Chu L, Crittenden J (2018) Efficient heavy metal removal from industrial melting effluent using fixed-bed process based on porous hydrogel adsorbents. Water Res 131:246–254

    Article  CAS  PubMed  Google Scholar 

  • Zinicovscaia I, Yushin N, Grozdov D, Vergel K, Popova N, Artemiev G, Safonov A (2020) Metal removal from nickel-containing effluents using mineral-organic hybrid adsorbent. Materials 13:21–21

    Article  Google Scholar 

  • Zou C, Jiang W, Liang J, Guan Y, Sun X (2019) Desorption regeneration performance of magnetic bentonite after Pb(II) adsorbed. ChemistrySelect 4:1306–1315

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the Key Technology Research and Development Program of China (Award Number: 2021YFC3201405), and the National Natural Science Foundation of China (Award Number: 51608165).

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  1. School of Civil and Transportation Engineering, Hebei University of Technology, Tian**, 300401, China

    Fei Han, Mingyao Zhao & Xun Ding

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  1. Fei Han
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Correspondence to Fei Han.

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Han, F., Zhao, M. & Ding, X. A novel study on the adsorption of low concentration Cd(II) and Ni(II) using porous boron nitride: effectiveness, coexisting anion interference, and regeneration. Braz. J. Chem. Eng. (2024). https://doi.org/10.1007/s43153-024-00451-1

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