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Influence of microcrystalline structure on compressive failure of carbon fiber

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Abstract

Carbon fibers (CFs) with different tensile moduli of 280–384 GPa were applied to investigate the relationship between crystalline structure and compressive failure. The carbon chemical structure and crystalline structure were studied by Raman, high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The correlation between compressive strength and crystalline structure was investigated. The results showed that the transition point between medium and high tensile modulus was around 310 GPa, and within the range of medium modulus, the compressive strength of CFs improved with the increase of tensile modulus, and the compressive strength also improved with the increase of crystal thickness Lc, crystal width La, and crystal plane orientation; In the high modulus range, the correlation law was opposite, which was mainly influenced by the grain boundary structure. CFs with tensile modulus lower than 310 GPa exhibited bucking and kinking fracture under compressive loading, while shear fracture was observed for CFs with tensile modulus higher than 310 GPa.

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Data and additional information is available upon request.

References

  1. Soutis C (2005) Fiber reinforced composites in aircraft construction. Prog Aerosp Sci 41(2):143–151. https://doi.org/10.1016/j.paerosci.2005.02.004

    Article  Google Scholar 

  2. Wang YF, Wang YW, Xu LH, Wang Y (2021) Regulating the radial structure of polyacrylonitrile fibers during pre-oxidation and its effect on the mechanical properties of the resulting carbon fibers. New Carbon Mater 36:1. https://doi.org/10.1016/s1872-5805(20)60516-9

    Article  CAS  Google Scholar 

  3. Ruan RY, Ye LW, Feng H, Xu LH, Wang Y (2020) High temperature evolution of the microstructure in the radial direction of PAN-based carbon fibers and its relationship to mechanical properties. New Carbon Mater 35:295. https://doi.org/10.1016/S1872-5805(20)60491-7

    Article  CAS  Google Scholar 

  4. Hayes GJ, Edie DD, Kennedy JM (1993) The recoil compressive strength of pitch-based carbon fibers. J Mater Sci 28(12):3247–3257. https://doi.org/10.1007/bf00354243

    Article  CAS  Google Scholar 

  5. Oya N, Johnson DJ (1999) Direct measurement of longitudinal compressive strength in carbon fibers. Carbon 37(10):1539–1544. https://doi.org/10.1002/pc.26493

    Article  CAS  Google Scholar 

  6. Hahn HT, Sohi M (1986) Buckling of a fiber bundle embedded in epoxy. Compos Sci Technol 27(1):25–41. https://doi.org/10.1016/0266-3538(86)90061-8

    Article  CAS  Google Scholar 

  7. Naoyuki O, David JJ (2001) Longitudinal compressive behavior and microstructure of PAN-based carbon fibers. Carbon. https://doi.org/10.1016/s0008-6223(00)00147-0

    Article  Google Scholar 

  8. Xu YL, Reifsnider KL (1993) Micromechanical modeling of composite compressive strength. J Compos Mater 27(6):572–588. https://doi.org/10.1177/002199839302700602

    Article  CAS  Google Scholar 

  9. Sugimoto Y, Kato T, Shioya M, Kobayashi T, Sumiya K, Fujie M (2013) Structure change of carbon fibers during axial compression. Carbon 57:416–424. https://doi.org/10.1016/j.carbon.2013.02.014

    Article  CAS  Google Scholar 

  10. Bledzki AK, Seidlitz H, Goracy K, Urbaniak M, Rosch JJ (2021) Recycling of carbon fiber reinforced composite polymers-review-part 1: volume of production, recycling technologies, legislative aspects. Polymers (Basel) 13(2):300. https://doi.org/10.3390/polym13020300

    Article  CAS  PubMed  Google Scholar 

  11. Sayam A, Rahman A, Rahman MS et al (2022) A review on carbon fiber-reinforced hierarchical composites: mechanical performance, manufacturing process, structural applications and allied challenges. Carbon Lett 32(5):1173–1205. https://doi.org/10.1007/s42823-022-00358-2

    Article  Google Scholar 

  12. Tanaka F, Okabe T, Okuda H, Kinloch IA, Young RJ (2013) The effect of nanostructure upon the compressive strength of carbon fibers. J Mater Sci 48(5):2104–2110. https://doi.org/10.1007/s10853-012-6984-z

    Article  CAS  Google Scholar 

  13. Chen J, Li G, Liu Z, Zhong X, Zhao Y, Bao J (2023) Influence of the electrochemical treatment level of carbon fibers on the compression after impact property of carbon fiber/epoxy composites. Polym Compos 44(2):1213–1227. https://doi.org/10.1002/pc.27165

    Article  CAS  Google Scholar 

  14. Ji X, Wang C, Francis PAB et al (2015) Mechanical and interfacial properties characterization of single carbon fibers for composite applications. Exp Mech. https://doi.org/10.1007/s11340-015-0007-3

    Article  Google Scholar 

  15. Qian BZ (2018) Japan Toray develops new carbon fiber. Synth Fiber 47(12):41. https://doi.org/10.16090/j.cnki.hcxw.2018.12.007. (in Chinese)

    Article  Google Scholar 

  16. Nakatani M, Shioya M, Yamashita J (1999) Axial compressive fracture of carbon fibers. Carbon 37(4):601–608. https://doi.org/10.1016/s0008-6223(98)00230-9

    Article  CAS  Google Scholar 

  17. Li ML, Zhu SP, Ou YQ et al (2018) Study on the relationship between the structure and axial compressive strength of domestic high strength medium model carbon fibers with different diameters. High Tech Fiber Appl 4(3(6)):33–39 (in Chinese)

    Google Scholar 

  18. Zou W, Tong Y, Wang Y, Qi Y, Wang X, Xu L (2023) Characteristics of compressive failure behavior of polyacrylonitrile-based carbon fiber multifilament. Polym Compos. https://doi.org/10.1002/pc.2782

    Article  Google Scholar 

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Acknowledgements

The author of this article greatly appreciates the support provided by the National Carbon Fiber Engineering Technology Research Center during the experimental process.

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No funding was received for conducting this study.

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Authors

Contributions

Yang Zhang: writing original draft preparation; writing—review and editing investigation; validation; formal analysis; data curation; Ruo-yan Wang: investigation; validation; Heng Zhang: investigation; validation; Yuan-jian Tong: writing—review and editing; investigation; supervision; Yu Wang: methodology; writing—review and editing; project administration; funding acquisition; conceptualization.

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Correspondence to Yu Wang.

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Zhang, Y., Wang, R., Zhang, H. et al. Influence of microcrystalline structure on compressive failure of carbon fiber. Carbon Lett. (2024). https://doi.org/10.1007/s42823-024-00768-4

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