Log in

Groundwater contamination apportionment in Beida-Bordj rural territory, northeast Algeria, using the nitrate pollution index (NPI) and groundwater pollution index (GPI)

  • Original Article
  • Published:
Sustainable Water Resources Management Aims and scope Submit manuscript

A Correction to this article was published on 15 September 2023

This article has been updated

Abstract

Most of the time, too much use of artificial fertilizers in rural areas, especially nitrogen fertilizers used to make crops grow faster, causes nitrate levels in groundwater to rise. In the Beida-Bordj area in northeast Algeria, groundwater is the main source of water for agriculture and drinking. Because of this, the quality of groundwater is very important. Therefore, nitrogen pollution in groundwater, which is one of the most important environmental problems, needs to be looked into. Therefore, evaluating groundwater contamination to protect human health was the primary focus of this investigation. As a result, 111 samples were taken in May 2022 from wells in different parts of the study area for physical and chemical research. Therefore, the nitrogen pollution index (NPI) and the groundwater pollution index (GPI) have been used to measure how clean groundwater is. The results show that the groundwater in the area that was tested is alkaline. Based on their average values, the abundance of cations and anions is as follows: Ca2+ > Na+ > Mg2+ > K+; and SO42− > Cl > HCO3 > NO3, in that order. The estimated NPIs ranged from – 1 to 4.5, with 0.92 being the average. Overall, the NPI data showed that only 25% of groundwater samples were clean, and the other 75% were dirty. The GPI readings ranged from 6.3 to 0.4, with an average of 1.2. This means that only 54% of the samples of groundwater from the study area were safe to drink. According to analyses of water quality parameters like SAR, SSP, RSC, PI, MH, and KR, the majority of groundwater samples from the research region are suitable for irrigation, because they fall into the "good" or "suitable" quality classes. This study's findings offer some intriguing suggestions for lowering pollution levels and bolstering groundwater management strategies for the future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data availability

All relevant data are included in this article.

Change history

References

  • Adimalla N (2020) Spatial distribution, exposure, and potential health risk assessment from nitrate in drinking water from semi-arid region of South India. Hum Ecol Risk Assess Int J 26(2):310–334

    Article  Google Scholar 

  • Aghazadeh N, Chitsazan M, Golestan Y (2017) Hydrochemistry and quality assessment of groundwater in the Ardabil area, Iran. Appl Water Sci 7:3599–3616

    Article  Google Scholar 

  • Akakuru OC, Adakwa CB, Ikoro DO, Eyankware MO, Opara AI, Njoku AO, Usman A (2023) Application of artificial neural network and multi-linear regression techniques in groundwater quality and health risk assessment around Egbema, Southeastern Nigeria. Environ Earth Sci 82(3):77

    Article  Google Scholar 

  • Akpan AE, Ugbaja AN, Okoyeh EI, George NJ (2018) Assessment of spatial distribution of contaminants and their levels in soil and water resources of Calabar, Nigeria using geophysical and geological data. Environ Earth Sci 77:1–19

    Article  Google Scholar 

  • Al-Hamdany NA, Al-Shaker Y, Al-Saffawi AY (2020) Application of nitrate pollution index (NPI) to evaluate the health safety of wells water for some quarters of the leftside of Mosul city, Iraq. Biochem Cell Arch 20(2):6063–6068

    Google Scholar 

  • Al Obaidy AHMJ, Kadhem AJ, Hamiza NH, Al Mashhady AA (2014) Assessment of ground water quality for drinking and agricultural uses in Mouqdadiya District, Diyala, Iraq. Eng Technol J 32(12):2921–2936

    Article  Google Scholar 

  • Ameur M, Hamzaoui-Azaza F, Gueddari M (2016) Nitrate contamination of Sminja aquifer groundwater in Zaghouan, northeast Tunisia: WQI and GIS assessments. Desalin Water Treat 57(50):23698–23708

    Article  Google Scholar 

  • Amiri V, Kamrani S, Ahmad A, Bhattacharya P, Mansoori J (2021) Groundwater quality evaluation using Shannon information theory and human health risk assessment in Yazd province, central plateau of Iran. Environ Sci Pollut Res 28(1):1108–1130

    Article  Google Scholar 

  • Arauzo M (2017) Vulnerability of groundwater resources to nitrate pollution: a simple and effective procedure for delimiting nitrate vulnerable zones. Sci Total Environ 575:799–812

    Article  Google Scholar 

  • Ayers RS, Westcot DW (1985) Water quality for agriculture, vol 29. Food and Agriculture Organization of the United Nations, Rome, p 174

    Google Scholar 

  • Baghapour MA, Fadaei Nobandegani A, Talebbeydokhti N, Bagherzadeh S, Nadiri AA, Gharekhani M, Chitsazan N (2016) Optimization of DRASTIC method by artificial neural network, nitrate vulnerability index, and composite DRASTIC models to assess groundwater vulnerability for unconfined aquifer of Shiraz Plain, Iran. J Environ Health Sci Eng 14:1–16

    Article  Google Scholar 

  • Bahrami M, Zarei AR, Rostami F (2020) Temporal and spatial assessment of groundwater contamination with nitrate by nitrate pollution index (NPI) and GIS (case study: Fasarud Plain, southern Iran). Environ Geochem Health 42:3119–3130

    Article  Google Scholar 

  • Birkinshaw SJ, Ewen J (2000) Modelling nitrate transport in the Slapton Wood catchment using SHETRAN. J Hydrol 230(1–2):18–33

    Article  Google Scholar 

  • Delgado JA (2002) Quantifying the loss mechanisms of nitrogen. J Soil Water Conserv 57(6):389–398

    Google Scholar 

  • Domzig (2007) deformation active et récente, et structuration tectono-sédimentaire de la marge sous-marine algérienne. Thèse de doctorat. Université Bretagne occidentale. p 332

  • Doneen LD (1962) The influence of crop and soil on percolating water. In: Proc. 1961 Biennial conference on Groundwater recharge, pp. 156–163

  • Ducci D (2018) An easy-to-use method for assessing nitrate contamination susceptibility in groundwater. Geofluids. https://doi.org/10.1155/2018/1371825

    Article  Google Scholar 

  • Ducci D, Dell Morte R, Mottola A, Onorati G, Pugliano G (2019) Nitrate trends in groundwater of the Campania region (southern Italy). Environ Sci Pollut Res 26:2120–2131

    Article  Google Scholar 

  • Eaton FM (1950) Significance of carbonates in irrigation waters. Soil Sci 69(2):123–134

    Article  Google Scholar 

  • Egbi CD, Anornu GK, Ganyaglo SY, Appiah-Adjei EK, Li SL, Dampare SB (2020) Nitrate contamination of groundwater in the lower Volta River Basin of Ghana: sources and related human health risks. Ecotoxicol Environ Saf 191:110227

    Article  Google Scholar 

  • El Mountassir O, Bahir M, Ouazar D, Chehbouni A, Carreira PM (2022) Temporal and spatial assessment of groundwater contamination with nitrate using nitrate pollution index (NPI), groundwater pollution index (GPI), and GIS (case study: Essaouira basin, Morocco). Environ Sci Pollut Res 29:17132–17149

    Article  Google Scholar 

  • Elton NW, EltonW J, Nazareno JP (1963) Pathology of acute salt poisoning in infants. Am J Clin Pathol 39:252–264

    Article  Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall, Englewood Cliffs, NJ

    Google Scholar 

  • Gardner SG, Levison J, Parker BL, Martin RC (2020) Groundwater nitrate in three distinct hydrogeologic and land-use settings in southwestern Ontario, Canada. Hydrogeol J 28(5):1891–1908

    Article  Google Scholar 

  • Gejl RN, Rygaard M, Henriksen HJ, Rasmussen J, Bjerg PL (2019) Understanding the impacts of groundwater abstraction through long-term trends in water quality. Water Res 156:241–251

    Article  Google Scholar 

  • Gibbs AJ, McIntyre GA (1970) The diagram, a method for comparing sequences: Its use with amino acid and nucleotide sequences. Eur J Biochem 16(1):1–11

    Article  Google Scholar 

  • Green CT, Liao L, Nolan BT, Juckem PF, Shope CL, Tesoriero AJ, Jurgens BC (2018) Regional variability of nitrate fluxes in the unsaturated zone and groundwater, Wisconsin, USA. Water Resour Res 54(1):301–322

    Article  Google Scholar 

  • Gu B, Ge Y, Chang SX, Luo W, Chang J (2013) Nitrate in groundwater of China: sources and driving forces. Glob Environ Chang 23(5):1112–1121

    Article  Google Scholar 

  • Han L, Huang M, Ma M, Wei J, Hu W, Chouhan S (2018) Evaluating sources and processing of nonpoint source nitrate in a small suburban watershed in China. J Hydrol 559:661–668

    Article  Google Scholar 

  • Hansen B, Thorling L, Kim H, Blicher-Mathiesen G (2019) Long-term nitrate response in shallow groundwater to agricultural N regulations in Denmark. J Environ Manag 240:66–74

    Article  Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural water (USGS water-supply paper 2254). US Geological Survey, pp. 117–120

  • Hooda PS, Edwards AC, Anderson HA, Miller A (2000) A review of water quality concerns in livestock farming areas. Sci Total Environ 250(1–3):143–167

    Article  Google Scholar 

  • Hutchins MG, Abesser C, Prudhomme C, Elliott JA, Bloomfield JP, Mansour MM, Hitt OE (2018) Combined impacts of future land-use and climate stressors on water resources and quality in groundwater and surface waterbodies of the upper Thames river basin, UK. Sci Total Environ 631:962–986

    Article  Google Scholar 

  • Jahangeer Gupta PK, Yadav BK (2018) Spatial and temporal nitrate transport in deep heterogeneous vadose zone of India’s Alluvial Plain. In: Groundwater: select Proceedings of ICWEES-2016. Springer, Singapore. pp. 171–178

  • Jia H, Qian H, Zheng L, Feng W, Wang H, Gao Y (2020) Alterations to groundwater chemistry due to modern water transfer for irrigation over decades. Sci Total Environ 717:137170

    Article  Google Scholar 

  • ** Z, Wang J, Chen J, Zhang R, Li Y, Yaoting L, He K (2020) Identifying the sources of nitrate in a small watershed using δ15N-δ18O isotopes of nitrate in the Kelan Reservoir, Guangxi, China. Agr Ecosyst Environ 297:106936

    Article  Google Scholar 

  • Kada H (2022) Apport de la géologie, l’hydrogéologie et des outils hydrogéochimiques à la connaissance des aquifères du barrémien et hauterivien de la région sud-sétifienne nord-est algérien (doctoral dissertation).

  • Kada H, Demdoum A (2020) Assessment of the Hauterivian groundwater quality in zinc mining area for drinking and irrigation uses: case of Chaabet el Hamra, Algeria. J Water Land Dev 46:131–139

    Google Scholar 

  • Kada H, Demdoum A, Baali F, Aouati H, Eddine HD (2022) Heavy metal contamination and exposure risk assessment via drinking groundwater in Ain Azel territory, north-eastern Algeria. Sustain Water Resour Manag 8(5):163

    Article  Google Scholar 

  • Kamaraj J, Sekar S, Roy PD, Senapathi V, Chung SY, Perumal M, Nath AV (2021) Groundwater pollution index (GPI) and GIS-based appraisal of groundwater quality for drinking and irrigation in coastal aquifers of Tiruchendur, South India. Environ Sci Pollut Res 28:29056–29074

    Article  Google Scholar 

  • Kelley WP (1940) Permissible composition and concentration of irrigation water. In: Proceedings of the American society of civil engineers, Vol. 66, pp. 607–613

  • Khosravi K, Sartaj M, Tsai FTC, Singh VP, Kazakis N, Melesse AM, Pham BT (2018) A comparison study of DRASTIC methods with various objective methods for groundwater vulnerability assessment. Sci Total Environ 642:1032–1049

    Article  Google Scholar 

  • Koh EH, Lee E, Lee KK (2020) Application of geographically weighted regression models to predict spatial characteristics of nitrate contamination: implications for an effective groundwater management strategy. J Environ Manag 268:110646

    Article  Google Scholar 

  • Loizidou M, Kapetanios EG (1993) Effect of leachate from landfills on underground water quality. Sci Total Environ 128(1):69–81

    Article  Google Scholar 

  • Muhib MI, Uddin MK, Rahman MM, Malafaia G (2023) Occurrence of microplastics in tap and bottled water, and food packaging: a narrative review on current knowledge. Sci Total Environ 865:161274

    Article  Google Scholar 

  • Nezhad AB, Emamjomeh MM, Farzadkia M, Jafari AJ, Sayadi M, Talab AHD (2017) Nitrite and nitrate concentrations in the drinking groundwater of Shiraz City, South-central Iran by statistical models, Iran. J Public Health 46(9):1275

    Google Scholar 

  • Obeida MM, Awawdeh M, Al-Rub FA, Al-Ajlouni A (2012) An innovative nitrate pollution index and multivariate statistical investigations of groundwater chemical quality of Umm Rijam Aquifer (B4), North Yarmouk River Basin, Jordan. In: Vouddouris K, Voutsa D (eds) Water quality monitoring and assessment. InTech, Croatia, pp 169–188

    Google Scholar 

  • Ogrinc N, Tamše S, Zavadlav S, Vrzel J, ** L (2019) Evaluation of geochemical processes and nitrate pollution sources at the Ljubljansko polje aquifer (Slovenia): a stable isotope perspective. Sci Total Environ 646:1588–1600

    Article  Google Scholar 

  • Ostad-Ali-Askari K (2022a) Develo** an optimal design model of furrow irrigation based on the minimum cost and maximum irrigation efficiency. Appl Water Sci 12(7):144

    Article  Google Scholar 

  • Ostad-Ali-Askari K (2022b) Review of the effects of the anthropogenic on the wetland environment. Appl Water Sci 12(12):260

    Article  Google Scholar 

  • Paliwal KV, Gandhi AP (1976) Effect of salinity, SAR, Ca: Mg ratio in irrigation water, and soil texture on the predictability of exchangeable sodium percentage. Soil Sci 122(2):85–90

    Article  Google Scholar 

  • Panagopoulos Y, Makropoulos C, Baltas E, Mimikou M (2011) SWAT parameterization for the identification of critical diffuse pollution source areas under data limitations. Ecol Model 222(19):3500–3512

    Article  Google Scholar 

  • Pande CB, Moharir K (2018) Spatial analysis of groundwater quality map** in hard rock area in the Akola and Buldhana districts of Maharashtra, India. Appl Water Sci 8:1–17

    Article  Google Scholar 

  • Pandey D, Katpatal YB, Kundal PP, Chandrayan VR (2016) Nitrate contamination indexing of subsurface water of upper Wainganga drainage basin of India. Int J Innov Res Sci, Eng Technol 5(1):161–170

    Google Scholar 

  • Panneerselvam B, Karuppannan S, Muniraj K (2020) Evaluation of drinking and irrigation suitability of groundwater with special emphasizing the health risk posed by nitrate contamination using nitrate pollution index (NPI) and human health risk assessment (HHRA). Hum Ecol Risk Assess Int J 27(5):1324–1348

    Article  Google Scholar 

  • Panneerselvam B, Pande CB, Muniraj K, Balasubramanian A, Ravichandran N (eds) (2022) Climate change impact on groundwater resources: human health risk assessment in arid and semi-arid regions. Springer, Cham. https://doi.org/10.1007/978-3-031-04707-7

    Book  Google Scholar 

  • Panneerselvam B, Ravichandran N, Kaliyappan SP, Karuppannan S, Bidorn B (2023) Quality and health risk assessment of groundwater for drinking and irrigation purpose in semi-arid region of India using entropy water quality and statistical techniques. Water 15(3):601

    Article  Google Scholar 

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. EOS Trans Am Geophys Union 25(6):914–928

    Article  Google Scholar 

  • Qian H, Chen J, Howard KW (2020) Assessing groundwater pollution and potential remediation processes in a multi-layer aquifer system. Environ Pollut 263:114669

    Article  Google Scholar 

  • Rahmati O, Choubin B, Fathabadi A, Coulon F, Soltani E, Shahabi H, Bui DT (2019) Predicting uncertainty of machine learning models for modelling nitrate pollution of groundwater using quantile regression and UNEEC methods. Sci Total Environ 688:855–866

    Article  Google Scholar 

  • Rawat KS, Jeyakumar L, Singh SK, Tripathi VK (2019) Appraisal of groundwater with special reference to nitrate using statistical index approach. Groundw Sustain Dev 8:49–58

    Article  Google Scholar 

  • Richards LA (1954) Diagnosis and improvement of saline and alkali soils (No. 60). US Government Printing Office

    Google Scholar 

  • Sahoo PK, Kim K, Powell MA (2016) Managing groundwater nitrate contamination from livestock farms: implication for nitrate management guidelines. Curr Pollut Rep 2:178–187

    Article  Google Scholar 

  • Schwartz PDF (1990) Physical and chemical hydrogeology. Wiley, New York

    Google Scholar 

  • Shrestha RK, Ladah JK (2002) Nitrate pollution in groundwater and strategies to reduce pollution. Water Sci Technol 45(9):29–35

    Article  Google Scholar 

  • Singh S, Raju NJ, Ramakrishna C (2015) Evaluation of groundwater quality and its suitability for domestic and irrigation use in parts of the Chandauli-Varanasi region, Uttar Pradesh, India. J Water Resour Prot 7(07):572

    Article  Google Scholar 

  • Stelzer RS, Scott JT (2018) Predicting nitrate retention at the groundwater-surface water interface in Sandplain streams. J Geophys Res Biogeosci 123(9):2824–2838

    Article  Google Scholar 

  • Subba Rao N (2012) PIG: a numerical index for dissemination of groundwater contamination zones. Hydrol Process 26(22):3344–3350

    Article  Google Scholar 

  • Subba Rao N, Krishna Rao G (1991) Groundwater quality in Visakhapatnam urban area, Andhra Pradesh. Indian J Environ Health 33(1):25–30

    Google Scholar 

  • Sun J, Li Z, Xue L, Wang T, Wang X, Gao J, Wang W (2018) Summertime C1–C5 alkyl nitrates over Bei**g, northern China: spatial distribution, regional transport, and formation mechanisms. Atmos Res 204:102–109

    Article  Google Scholar 

  • Suthar S, Bishnoi P, Singh S, Mutiyar PK, Nema AK, Patil NS (2009) Nitrate contamination in groundwater of some rural areas of Rajasthan, India. J Hazard Mater 171(1–3):189–199

    Article  Google Scholar 

  • Szabolcs I, Darab K (1964) Radio-Active technique for examining the improving effect of CaCO3 on alkali (Szik) soils. Acta Agron Hung 13:93–101

    Google Scholar 

  • Taufiq A, Effendi AJ, Iskandar I, Hosono T, Hutasoit LM (2019) Controlling factors and driving mechanisms of nitrate contamination in groundwater system of Bandung Basin, Indonesia, deduced by combined use of stable isotope ratios, CFC age dating, and socioeconomic parameters. Water Res 148:292–305

    Article  Google Scholar 

  • Todd DK, Mays LW (2004) Groundwater hydrology. Wiley

    Google Scholar 

  • WHO (2011) Guidelines for drinking-water quality. World Health Organ 216:303–304

    Google Scholar 

  • WHO (2017) Guidelines for drinking water quality, 4th edition incorporating the first addendum. World Health Organization, Geneva

    Google Scholar 

  • Wilcox L (1955) Classification and use of irrigation waters (No. 969). US Department of Agriculture

    Google Scholar 

  • Yang S, Yang Q, Ma H, Liang J, Niu C, Martin JD (2018) Health risk assessment of phreatic water based on triangular fuzzy theory in Yinchuan plain. Ecotoxicol Environ Saf 164:732–738

    Article  Google Scholar 

  • Yin S, **ao Y, Gu X, Hao Q, Liu H, Hao Z, Pei Q (2019) Geostatistical analysis of hydrochemical variations and nitrate pollution causes of groundwater in an alluvial fan plain. Acta Geophys 67(4):1191–1203

    Article  Google Scholar 

  • Zhai Y, Zhao X, Teng Y, Li X, Zhang J, Wu J, Zuo R (2017) Groundwater nitrate pollution and human health risk assessment by using HHRA model in an agricultural area, NE China. Ecotoxicol Environ Saf 137:130–142

    Article  Google Scholar 

  • Zhang F, Huang G, Hou Q, Liu C, Zhang Y, Zhang Q (2019) Groundwater quality in the Pearl River Delta after the rapid expansion of industrialization and urbanization: distributions, main impact indicators, and driving forces. J Hydrol 577:124004

    Article  Google Scholar 

  • Zhang Q, Xu P, Qian H (2020) Groundwater quality assessment using improved water quality index (WQI) and human health risk (HHR) evaluation in a semi-arid region of northwest China. Expo Health 12:487–500

    Article  Google Scholar 

  • Zhang Q, Qian H, Xu P, Li W, Feng W, Liu R (2021) Effect of hydrogeological conditions on groundwater nitrate pollution and human health risk assessment of nitrate in Jiaokou Irrigation District. J Clean Prod 298:126783

    Article  Google Scholar 

Download references

Acknowledgements

The first author wishes to acknowledge the other authors for their contributions to this study.

Funding

The work was not supported by any external financial sources.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Houria Kada.

Ethics declarations

Conflict of interest

The authors have no known conflicts of interest that could appear to influence the content of this article.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

The original online version of this article was revised due to a retrospective Open Access cancellation.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kada, H., Demdoum, A. & Aouati, H. Groundwater contamination apportionment in Beida-Bordj rural territory, northeast Algeria, using the nitrate pollution index (NPI) and groundwater pollution index (GPI). Sustain. Water Resour. Manag. 9, 152 (2023). https://doi.org/10.1007/s40899-023-00931-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40899-023-00931-1

Keywords

Navigation