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Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines

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Abstract

Salen-porphyrin-based conjugated microporous polymers(CMPs) have been demonstrated to be an attractive material platform for predesigned structures and promising applications. Herein, a new salen-porphyrin-based conjugated microporous polymer(SP-CMP-L) was solvothermally prepared by porphyrin-forming condensation reaction of pyrrole and salen-dialdehyde derivative. The SP-CMP-L was characterized by spectroscopy technologies, and also exhibited excellent thermal and chemical stability. The porosity of SP-CMP-L was examined by N2 adsorption/desorption isotherms. The BET specific surface area of the CMP material was calculated to be 290.4 m2/g with the pore volume of 0.19 cm3/g. The microstructure property of the resulting material was further evaculated by scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The SP-CMP-L with salen and porphyrin multidentate coordination sites was proposed to serve as an initiator to promote the cross-coupling between aryl halides with unactivated arenes under base-mediated conditions. The transition-metal-free catalytic protocol provided high catalytic activity for direct C-H arylation reaction of unactivated arenes, and thus offered a convenient and efficient alternative for the construction biaryl scaffolds. In addition, the salen-porphyrin-based CMP material possessed remarkable adsorption capability for the removal of organic amines from water.

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Kexin Luo, Qing Su, Pengyao Ju, **aodong Li, Ziqian Liu, **aoman Sun & Qiaolin Wu

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, P. R. China

    Guanghua Li

Authors
  1. Kexin Luo
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  2. Qing Su
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  3. Pengyao Ju
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  4. **aodong Li
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  5. Ziqian Liu
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  6. **aoman Sun
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  7. Guanghua Li
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  8. Qiaolin Wu
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Corresponding authors

Correspondence to Qing Su or Qiaolin Wu.

Additional information

Supported by the National Natural Science Foundation of China(No.51703076).

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40242_2020_208_MOESM1_ESM.pdf

Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines

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Luo, K., Su, Q., Ju, P. et al. Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines. Chem. Res. Chin. Univ. 36, 1302–1309 (2020). https://doi.org/10.1007/s40242-020-0208-x

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  • DOI: https://doi.org/10.1007/s40242-020-0208-x

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