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An adenine-based palladium complex: a capable heterogeneous magnetic nano-catalyst for the green synthesis of the ureas in aqueous media

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Abstract

A novel adenine-based palladium nano-complex was synthesized via preparation of the Fe3O4 magnetic nano-particles (Fe3O4 MNPs), coating with tetraethyl orthosilicate, functionalization with both 3-chloropropyltrimethoxysilane (CPTMS) and adenine (AD) ligands and finally formation of the corresponding complex by PdCl2 (Fe3O4@SiO2@CPTMS@AD@ Pd). Then, it was characterized with different methods such as FT-IR, EDX, ICP, XRD, SEM, TEM, VSM and TGA-DTA techniques, and capability of the adenine-based Pd complex evaluated by its application as an efficient heterogeneous nano-catalyst for the synthesis of various N-mono-substituted ureas in water by hydrolysis of cyanamides in the presence of 98% HCOOH with good to high yields in relatively short reaction times at room temperature.

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Acknowledgements

We thank Bu-Ali Sina University, Hamedan Iran, for the fiscal support of this work.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Vahideh Khorram Abadi, Davood Habibi & Maryam Mahmoudiani Gilan

  2. Saveh Medical University, Saveh, Iran

    Somayyeh Heydari

Authors
  1. Vahideh Khorram Abadi
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  2. Davood Habibi
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  3. Somayyeh Heydari
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  4. Maryam Mahmoudiani Gilan
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Correspondence to Davood Habibi.

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Khorram Abadi, V., Habibi, D., Heydari, S. et al. An adenine-based palladium complex: a capable heterogeneous magnetic nano-catalyst for the green synthesis of the ureas in aqueous media. J IRAN CHEM SOC 20, 1985–1996 (2023). https://doi.org/10.1007/s13738-023-02813-x

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  • DOI: https://doi.org/10.1007/s13738-023-02813-x

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