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Modeling and optimizing Cd(II) ions adsorption onto Corn Silk/Zeolite-Y composite from industrial effluents applying response surface methodology: isotherm, kinetic, and reusability studies

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Abstract

This study aimed to eliminate Cd(II) ions from aqueous solutions by Corn Silk/Zeolite-Y (CS/ZY) adsorbent. The prepared composite was characterized by FTIR, SEM, XRD, TEM, and BET analysis. The adsorption process was optimized by central composite design (CCD). Four factors including the solution pH (2.0–6.0), Cd(II) concentration (2.5–12.5 mg L−1), contact time (5.5–11.5 min), and adsorbent dose (0.005–0.01 g) were considered, and the optimal condition of parameters for maximum cadmium adsorption was as follows: pH 5.0, adsorbent dosage: 0.009 g, cadmium concentration: 10.0 mg L−1, and contact time: 7.0 min. The kinetic and equilibrium data were well-fitted by pseudo-second-order and Langmuir models (qm = 315.27 mg g−1). The obtained results related to the reusability of the CS/ZY composite after five sorption desorption cycles offered promising potential in industrial activities.

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Acknowledgements

The authors wish to express their thanks to the Research Council of the Shahrood University of Technology for the financial support of this research work.

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Authors and Affiliations

  1. Faculty of Chemistry, Shahrood University of Technology, Shahrood, 36199-95161, Iran

    Zahra Kalantar

  2. Department of Chemistry, Faculty of Sciences, University of Shahrekord, P. O. Box 115, Shahrekord, Iran

    Shima Ghanavati Nasab

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  1. Zahra Kalantar
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Correspondence to Zahra Kalantar or Shima Ghanavati Nasab.

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Kalantar, Z., Ghanavati Nasab, S. Modeling and optimizing Cd(II) ions adsorption onto Corn Silk/Zeolite-Y composite from industrial effluents applying response surface methodology: isotherm, kinetic, and reusability studies. J IRAN CHEM SOC 19, 4209–4221 (2022). https://doi.org/10.1007/s13738-022-02594-9

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