Log in

Characterization of heat-treated biosilica from biomass waste fox tail millet husks and banana fiber reinforced epoxy composite

  • Original Article
  • Published:
Biomass Conversion and Biorefinery Aims and scope Submit manuscript

Abstract

This research investigated the effect of adding heat-treated biosilica synthesized from fox tail millet husk on load bearing, thermal and water absorption behavior of banana-epoxy composite. The biosilica reinforcing material was extracted from the tail husks and heat treated in a box furnace. Further, the composites are prepared using hand layup method and tested in accordance to the American Society of Testing and Materials. According to results, the composite containing 2 vol. % of biosilica exhibited exceptional mechanical characteristics, including a tensile strength of 134 MPa, flexural strength of 231.64 MPa, compressive strength of 187.2 MPa, impact energy of 4.81 J, and hardness strength of 93. The enhancements are attributed to the robust connection established between the heat-treated biosilica and the composite matrix, enabling effective transmission of stress. In addition, the study thoroughly assessed the durability and fire safety of the composites. The findings showed that the inclusion of heat-treated biosilica improved the resistance to fire and decreased the flammability. Moreover, the 2 vol. % of biosilica reinforced composite demonstrated a notably low specific wear rate of 0.008 mm3/Nm and a coefficient of friction of 0.28 with a lower flame propagation speed of 7.2 mm/min. In addition, the composite containing 2 vol. % of biosilica exhibited controlled water absorption and a moderate water contact angle of 82°, suggesting a retained hydrophobicity. These findings highlight the considerable potential of eco-friendly composites for various applications, such as in the building, automotive, and aerospace sectors, where lightweight and high strength is required.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Brazil)

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Data availability

All data within manuscript.

References

  1. Alshahrani H, Arun Prakash VR (2024) Characterisation of microcrystalline cellulose from waste green pea pod sheath and its sunn hemp fibre-polyester composite: a step towards greener manufacturing. Physiol Plant 176(1):e14166

    Article  CAS  Google Scholar 

  2. Bharath KN, Basavarajappa S (2016) Applications of biocomposite materials based on natural fibers from renewable resources: a review. Sci Eng Compos Mater 23(2):123–133. https://doi.org/10.1515/secm-2014-0088

    Article  Google Scholar 

  3. Qu J, Zhang J, Li H, Li S, Hou X, Chang R, Zhang Y (2024) Coal gasification slag-derived highly reactive silica for high modulus sodium silicate synthesis: process and mechanism. Chem Eng J 479:147771. https://doi.org/10.1016/j.cej.2023.147771

    Article  CAS  Google Scholar 

  4. Riaz R, Bashir M, Imtiaz K, Rahdar A, Nazar MF, Sumrra SH et al (2024) Silicones and their applications. In: In Advances in Minerals Research. Springer Nature Switzerland, Cham, pp 131–156. https://doi.org/10.1007/978-3-031-49175-7_5

    Chapter  Google Scholar 

  5. Tabish M, Zaheer MM, Baqi A (2023) Effect of nano-silica on mechanical, microstructural and durability properties of cement-based materials: a review. J Build Eng 65:105676. https://doi.org/10.1016/j.jobe.2022.105676

    Article  Google Scholar 

  6. Sathish Kumar S, Manimaran R, Anbukarasi K (2022) Mechanical, wear and fatigue behavior of silane-treated corncob biosilica toughened epoxy resin composite reinforced with prickly pear short fibers. Polym Compos 43(10):6998–7006. https://doi.org/10.1002/pc.26761

    Article  CAS  Google Scholar 

  7. Sivakumar A, Vinith KK, Savadamuthu L, Sathiamurthi P (2023) Development of pineapple fibre and biosilica toughened polyester sustainable biocomposite of few mechanical properties for automobile application. Silicon 15(8):3507–3514. https://doi.org/10.1007/s12633-022-02284-4

    Article  CAS  Google Scholar 

  8. Raj TM, Robert TP (2023) Effect of adding silanized cassava periderm biosilica on mechanical, V-notch rail shear, wear, and UL-94 flammability behavior of spinach stem fiber epoxy composite. Biomass Convers Biorefin:1–9. https://doi.org/10.1007/s13399-023-04619-6

  9. Bhatt D, Rasane P, Singh J, Kaur S, Fairos M, Kaur J et al (2023) Nutritional advantages of barnyard millet and opportunities for its processing as value-added foods. J Food Sci Technol 60(11):2748–2760. https://doi.org/10.1007/s13197-022-05602-1

    Article  PubMed  Google Scholar 

  10. Lacelle T, Sampson KL, Yazdani Sarvestani H, Rahimizadeh A, Barroeta Robles J, Mirkhalaf M et al (2023) Additive manufacturing of polymer derived ceramics: materials, methods, and applications. APL Mater 11(7). https://doi.org/10.1063/5.0151661

  11. Sarraf F, Churakov SV, Clemens F (2023) Preceramic polymers for additive manufacturing of silicate ceramics. Polymers 15(22):4360. https://doi.org/10.3390/polym15224360

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  12. Butto M, Maspoch ML, Bernal C (2023) Effect of post-drawing thermal treatment on the mechanical behavior of solid-state drawn poly (lactic acid) (PLA) filaments. Textiles 3(3):339–352. https://doi.org/10.3390/textiles3030023

    Article  Google Scholar 

  13. Villota-Enríquez MD, Rodríguez-Páez JE (2023) Bio-silica production from rice husk for environmental remediation: removal of methylene blue from aqueous solutions. Mater Chem Phys 301:127671. https://doi.org/10.1016/j.jma.2023.08.001

    Article  CAS  Google Scholar 

  14. Pokhriyal M, Rakesh PK, Rangappa SM, Siengchin S (2023) Effect of alkali treatment on novel natural fiber extracted from Himalayacalamusfalconeri culms for polymer composite applications. Biomass Convers Biorefin:1–17. https://doi.org/10.1007/s13399-023-03843-4

  15. Vinod B, Sudev LJ, Ganesha BB, Arunkumar KN, Thammegowda CS (2023) Study on effect of pista shell as filler material on mechanical performance of banana fiber reinforced polymer composite. In: In International Conference on Inventive Material Science Applications. Springer Nature Singapore, Singapore, pp 145–154. https://doi.org/10.1007/978-981-99-4189-6_13

    Chapter  Google Scholar 

  16. Balaji A, Purushothaman R, Udhayasankar R, Vijayaraj S, Karthikeyan B (2020) Study on mechanical, thermal and morphological properties of banana fiber-reinforced epoxy composites. J Bio-Tribo-Corros 6:1–10. https://doi.org/10.1007/s40735-020-00357-8

    Article  Google Scholar 

  17. Karthikeyan B, Babu K (2023) Experimental investigation on machining characteristics of minimum quantity lubrication grinding of AISI-4320 steel using finger millet husk biosilica nanofluid. Biomass Convers Biorefinery:1–11. https://doi.org/10.1007/s13399-023-04804-7

  18. Chiu WT, Sratong-on P, Tahara M, Chernenko V, Hosoda H (2023) Aging behavior of Ni-Mn-Ga/silicone particulate composites exhibiting large recoverable magnetostrain. Scr Mater 227:115277. https://doi.org/10.1016/j.scriptamat.2023.115277

    Article  CAS  Google Scholar 

  19. Verma R, Sharma B, Singh MK, Rathore SS, Kaur H (2023) Experimental assessment of nanoclay effect on hardness, tensile and flexural properties of glass fiber/epoxy laminates. Mater Today: Proc 79:395–397. https://doi.org/10.1016/j.matpr.2022.12.163

    Article  CAS  Google Scholar 

  20. Saravanan K, Kaliappan S, Natrayan L et al (2023) Effect of cassava tuber nanocellulose and satin weaved bamboo fiber addition on mechanical, wear, hydrophobic, and thermal behavior of unsaturated polyester resin composites. Biomass Convers Biorefinery:1–13. https://doi.org/10.1007/s13399-023-04495-0

  21. Kaliappan S, Natrayan L, Kumar PVA et al (2023) Mechanical, fatigue, and hydrophobic properties of silane-treated green pea fiber and egg fruit seed powder epoxy composite. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-023-04534-w

  22. Arun Prakash VR, Jayaseelan V, Mothilal T, Kumar M, Depoures MV, Jayabalakrishnan D, Ramesh G (2020) Effect of silicon coupling grafted ferric oxide and E-glass fibre in thermal stability, wear and tensile fatigue behaviour of epoxy hybrid composite. Silicon 12:2533–2544

    Article  Google Scholar 

  23. Prakash VA, Viswanthan R (2019) Fabrication and characterization of echinoidea spike particles and kenaf natural fibre-reinforced Azadirachta-Indica blended epoxy multi-hybrid bio composite. Compos A: Appl Sci Manuf 118:317–326

    Article  Google Scholar 

  24. Balaji N, Gurupranes SV, Balaguru S et al (2023) Mechanical, wear, and drop load impact behavior of Cissus quadrangularis fiber–reinforced moringa gum powder–toughened polyester composite. Biomass Convers Biorefinery:1–10. https://doi.org/10.1007/s13399-023-04491-4

  25. Prabhushankar N, Balaji N, Kaliappan S (2023) Effect of sisal/kevlar inter-ply stacking and silane-treatment on mechanical, wear, fracture toughness, drop load impact, and hydrophobicity behavior of cellulose toughened polyester composite. Biomass Convers Biorefinery:1–9. https://doi.org/10.1007/s13399-023-04416-1

  26. Alshahrani H, Prakash VA (2022) Mechanical, fatigue and DMA behaviour of high content cellulosic corn husk fibre and orange peel biochar epoxy biocomposite: a greener material for cleaner production. J Clean Prod 374:133931

    Article  CAS  Google Scholar 

  27. Arockiasamy FS, Muthukrishnan M, Iyyadurai J, Kaliappan S, Lakshmaiya N, Djearamane S et al (2023) Tribological characterization of sponge gourd outer skin fiber-reinforced epoxy composite with Tamarindus indica seed filler addition using the Box–Behnken method. e-Polymers 23(1):20230052

    Article  CAS  Google Scholar 

  28. Prabhu P, Jayabalakrishnan D, Balaji V, Bhaskar K, Maridurai T, Prakash VA (2024) Mechanical, tribology, dielectric, thermal conductivity, and water absorption behaviour of Caryota urens woven fibre-reinforced coconut husk biochar toughened wood-plastic composite. Biomass Convers Biorefin 14(1):109–116

    Article  Google Scholar 

  29. Sahayaraj AF, Selvan MT, Jenish I et al (2023) Extraction and characterization of novel cellulosic fiber from Jatropha integerrima plant stem for potential reinforcement in polymer composites. Biomass Convers Biorefin:1–11. https://doi.org/10.1007/s13399-023-04541-x

  30. Ramesh M, Tamil Selvan M, Felix Sahayaraj A, Jenish I, Balakrishnan P, Ravanan A (2023) Investigation of mechanical and viscoelastic properties of Agave cantala fiber-reinforced green composites for structural applications. Proc Inst Mech Eng, Part E: J Proc Mech Eng 0(0). https://doi.org/10.1177/09544089231190225

  31. Selvan MT, Jenish I, Ramesh M et al (2023) Characterization of Plumeria pudica bark fiber for reinforcing lightweight polymer composites and evaluating its physical, chemical, and thermal properties. Biomass Convers Biorefinery:1–14. https://doi.org/10.1007/s13399-023-05172-y

  32. Sundarakannan R, Arumugaprabu V, Manikandan V, Vigneshwaran S (2020) Mechanical property analysis of biochar derived from cashew nut shell waste reinforced polymer matrix. Mater Res Express 6(12):125349

    Article  Google Scholar 

  33. Kaliappan S, Arunadevi B, Sateesh N et al (2023) Effect of amino silane grafted cellulose and kenaf fibers in mechanical, impact toughness and drilling characteristics of epoxy resin composite. Silicon 15:3149–3158. https://doi.org/10.1007/s12633-022-02245-x

    Article  CAS  Google Scholar 

  34. Sivakumar V, Kaliappan S, Natrayan L et al (2023) Effects of silane-treated high-content cellulose okra fibre and tamarind kernel powder on mechanical, thermal stability and water absorption behaviour of epoxy composites. Silicon 15:4439–4447. https://doi.org/10.1007/s12633-023-02370-1

    Article  CAS  Google Scholar 

  35. Muralidaran VM, Natrayan L, Kaliappan S et al (2023) Grape stalk cellulose toughened plain weaved bamboo fiber-reinforced epoxy composite: load bearing and time-dependent behavior. Biomass Convers Biorefin:1–8. https://doi.org/10.1007/s13399-022-03702-8

  36. Jaiganesh V, Manikandan G, Gurusamy P et al (2022) Tensile fatigue, fracture toughness, and thermo-mechanical behavior of silane-modified Morinda citrifolia fiber and chitosan-reinforced epoxy composites. Biomass Convers Biorefin:1–8. https://doi.org/10.1007/s13399-022-03679-4

  37. Kaliappan S, Velumayil R, Natrayan L, Pravin P (2023) Polym Compos 44(4):2115. https://doi.org/10.1002/pc.27228

    Article  CAS  Google Scholar 

  38. Khan MK, Faisal M, Arun Prakash VR Effect of silane coupling grafted polyethylene terephthalate foam and areca fruit fiber reinforced chitin modified vinyl ester prosthetic composite on thermal and water accelerated aging conditions. Polym Compos

  39. Arun Prakash VR, Xavier JF, Ramesh G et al (2022) Mechanical, thermal and fatigue behaviour of surface-treated novel Caryota urens fibre–reinforced epoxy composite. Biomass Convers Biorefin 12:5451–5461. https://doi.org/10.1007/s13399-020-00938-0

    Article  CAS  Google Scholar 

  40. Rajadurai A (2016) Thermo-mechanical characterization of siliconized E-glass fiber/hematite particles reinforced epoxy resin hybrid composite. Appl Surf Sci 384:99–106

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Contributions

N. Nithyanandan and Gokilakrishnan G have undertaken the complete research. Manoj Kumar S and Hanish Anand S have provided supports in testing and manuscript drafting.

Corresponding author

Correspondence to N. Nithyanandan.

Ethics declarations

Ethical statement

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nithyanandan, N., Gokilakrishnan, G., Manoj Kumar, S. et al. Characterization of heat-treated biosilica from biomass waste fox tail millet husks and banana fiber reinforced epoxy composite. Biomass Conv. Bioref. (2024). https://doi.org/10.1007/s13399-024-05411-w

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s13399-024-05411-w

Keywords

Navigation