Abstract
Despite its widespread use in many industrial applications, phenol is a hazardous pollutant that needs proper treatment before its discharge into the environment. Herein, a new activated carbon (AC) from Atlas oak wood was reported as adsorbent for phenol removal from aqueous solutions. The charcoal was activated with different acidic and basic solutions and characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption/desorption measurements to determine the structural and textural properties of the solids. The iodine number test and the pH at zero charge point were also determined and discussed. Its iodine number test and pH at zero charge point were also determined and discussed. Then, the phenol adsorption capacity of prepared activated carbons was evaluated under several operating conditions. The H3PO4-activated carbon had the highest adsorption capacity, which outperformed that of a commercially activated carbon. Optimum results were achieved at 2 h equilibrium time, a mass of adsorbent of 100 mg, and an initial concentration of 10−2 mol/L at a pH = 4. The phenol elimination using acid-treated carbons gave extraction yields up to 98.77%, higher than that of the commercially activated carbon (91.48%) and base-treated carbons that showed unfavorable adsorption. An adsorbed quantity of the phenol of the order with a yield of 99% for the carbon was activated by H3PO4. The adsorption of phenol on activated carbon followed the second-order rate equation and Langmuir adsorption isotherm model. However, it should be noted that the adsorbed amount by activated carbon using H3PO4 (Qm = 250 mg/g) exceeds that adsorbed by commercial carbon (Qm = 200 mg/g). Outcomes of this work can open a gate for the development of efficient natural-based adsorbents for the removal of pollutants from wastewater.
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The data that support the findings of this study are available from the corresponding author (H.L.) upon reasonable request.
References
Salgot M, Folch M (2018) Wastewater treatment and water reuse. Curr Opin Environ Sci Health 2:64–74
Azhagapillai P, Al Shoaibi A, Chandrasekar S (2021) Surface functionalization methodologies on activated carbons and their benzene adsorption. Carbon Lett 31:419–426
Hu R, Liu Y, Zhu G et al (2022) COD removal of wastewater from hydrothermal carbonization of food waste: using coagulation combined activated carbon adsorption. J Water Process Eng 45:102462. https://doi.org/10.1016/j.jwpe.2021.102462
de Leite L, S, Hoffmann MT, de Vicente FS, et al (2021) Adsorption of algal organic matter on activated carbons from alternative sources: influence of physico-chemical parameters. J Water Process Eng 44:102435. https://doi.org/10.1016/j.jwpe.2021.102435
Zhang S, Zhang Z, Zhao R et al (2017) A review of challenges and recent progress in supercritical water oxidation of wastewater. Chem Eng Commun 204:265–282
Dehmani Y, Abouarnadasse S (2020) Study of the adsorbent properties of nickel oxide for phenol depollution. Arab J Chem 13:5312–5325
Akani NP, Nwankwo CEI (2018) Monitoring the microbial load at chosen critical control points in the production of Kunun-zaki. IOSR J Environ Sci 12(9):41–46. https://doi.org/10.9790/2402-1209034146
El Nemr A, Aboughaly RM, El Sikaily A et al (2020) Microporous nano-activated carbon type I derived from orange peel and its application for Cr(VI) removal from aquatic environment. Biomass Conv Bioref. https://doi.org/10.1007/s13399-020-00995-5
Biftu WK, Suneetha M, Ravindhranath K (2021) Zirconium-alginate beads doped with H2SO4-activated carbon derived from leaves of Magnoliaceae plant as an effective adsorbent for the removal of chromate. Biomass Conv Bioref. https://doi.org/10.1007/s13399-021-01568-w
Zeng X, Yu T, Wang P et al (2010) Preparation and characterization of polar polymeric adsorbents with high surface area for the removal of phenol from water. J Hazard Mater 177:773–780. https://doi.org/10.1016/j.jhazmat.2009.12.100
Saleh S, Younis A, Ali R, Elkady E (2019) Phenol removal from aqueous solution using amino modified silica nanoparticles. Korean J Chem Eng 36:529–539. https://doi.org/10.1007/s11814-018-0217-3
Yapar S, Yilmaz M (2005) Removal of phenol by using montmorillonite, clinoptilolite and hydrotalcite. Adsorption 10:287–298. https://doi.org/10.1007/s10450-005-4814-1
Mondal NK, Roy S (2016) Optimization study of adsorption parameters for removal of phenol on gastropod shell dust using response surface methodology. Clean Techn Environ Policy 18:429–447. https://doi.org/10.1007/s10098-015-1026-6
Hasan MK, Shahriar A, Jim KU (2019) Water pollution in Bangladesh and its impact on public health. Heliyon 5:e02145
Dao MU, Le HS, Hoang HY et al (2021) Natural core-shell structure activated carbon beads derived from Litsea glutinosa seeds for removal of methylene blue: facile preparation, characterization, and adsorption properties. Environ Res 198:110481. https://doi.org/10.1016/j.envres.2020.110481
Zhan M-X, Liu Y-W, Ye W-W et al (2022) Modification of activated carbon using urea to enhance the adsorption of dioxins. Environ Res 204:112035. https://doi.org/10.1016/j.envres.2021.112035
Prabu D, Kumar PS, Rathi BS et al (2022) Feasibility of magnetic nano adsorbent impregnated with activated carbon from animal bone waste: application for the chromium (VI) removal. Environ Res 203:111813. https://doi.org/10.1016/j.envres.2021.111813
Wu Z, Guo X, Lv C et al (2018) Study on the quantification method of water pollution ecological compensation standard based on emergy theory. Ecol Ind 92:189–194
Petersen NB, Madsen T, Glaring MA et al (2019) Ballast water treatment and bacteria: analysis of bacterial activity and diversity after treatment of simulated ballast water by electrochlorination and UV exposure. Sci Total Environ 648:408–421
Shao S, Li B, Fan M, Yang L (2021) How does labor transfer affect environmental pollution in rural China? Evidence from a survey. Energy Econ 102:105515
Saleem M, Bachmann RT (2019) A contemporary review on plant-based coagulants for applications in water treatment. J Ind Eng Chem 72:281–297
Kannaujiya MC, Prajapati AK, Mandal T et al (2021) Extensive analyses of mass transfer, kinetics, and toxicity for hazardous acid yellow 17 dye removal using activated carbon prepared from waste biomass of Solanum melongena. Biomass Conv Bioref. https://doi.org/10.1007/s13399-020-01160-8
Güzel F, Koyuncu F (2021) Adsorptive removal of diclofenac sodium from aqueous solution via industrial processed citrus solid waste–based activated carbon: optimization, kinetics, equilibrium, thermodynamic, and reusability analyses. Biomass Conv Bioref. https://doi.org/10.1007/s13399-021-01969-x
Menya E, Olupot PW, Storz H et al (2020) Synthesis and evaluation of activated carbon from rice husks for removal of humic acid from water. Biomass Conv Bioref. https://doi.org/10.1007/s13399-020-01158-2
Mousavi SA, Kamarehie B, Almasi A et al (2021) Removal of Rhodamine B from aqueous solution by stalk corn activated carbon: adsorption and kinetic study. Biomass Conv Bioref. https://doi.org/10.1007/s13399-021-01628-1
Nassar MM, El-Geundi MS (1991) Comparative cost of colour removal from textile effluents using natural adsorbents. J Chem Technol Biotechnol 50:257–264. https://doi.org/10.1002/jctb.280500210
Choksi PM, Joshi VY (2007) Adsorption kinetic study for the removal of nickel (II) and aluminum (III) from an aqueous solution by natural adsorbents. Desalination 208:216–231. https://doi.org/10.1016/j.desal.2006.04.081
Moharami S, Jalali M (2013) Removal of phosphorus from aqueous solution by Iranian natural adsorbents. Chem Eng J 223:328–339. https://doi.org/10.1016/j.cej.2013.02.114
Figueiredo SA, Boaventura RA, Loureiro JM (2000) Color removal with natural adsorbents: modeling, simulation and experimental. Sep Purif Technol 20:129–141. https://doi.org/10.1016/S1383-5866(00)00068-X
Poots VJP, McKay G, Healy JJ (1976) The removal of acid dye from effluent using natural adsorbents—I peat. Water Res 10:1061–1066. https://doi.org/10.1016/0043-1354(76)90036-1
Almuntashiri A, Hosseinzadeh A, Badeti U et al (2022) Removal of pharmaceutical compounds from synthetic hydrolysed urine using granular activated carbon: column study and predictive modelling. J Water Process Eng 45:102480. https://doi.org/10.1016/j.jwpe.2021.102480
Taoufik N, Elmchaouri A, Anouar F et al (2019) Improvement of the adsorption properties of an activated carbon coated by titanium dioxide for the removal of emerging contaminants. J Water Process Eng 31:100876. https://doi.org/10.1016/j.jwpe.2019.100876
Mariana M, H.p.s AK, Mistar EM et al (2021) Recent advances in activated carbon modification techniques for enhanced heavy metal adsorption. J Water Process Eng 43:102221. https://doi.org/10.1016/j.jwpe.2021.102221
Dehmani Y, El Khalki O, Mezougane H, Abouarnadasse S (2021) Comparative study on adsorption of cationic dyes and phenol by natural clays. Chem Data Collections 33:100674
Shaw JLA, Monis P, Fabris R et al (2014) Assessing the impact of water treatment on bacterial biofilms in drinking water distribution systems using high-throughput DNA sequencing. Chemosphere 117:185–192. https://doi.org/10.1016/j.chemosphere.2014.06.077
Chandrasekaran A, Patra C, Narayanasamy S, Subbiah S (2020) Adsorptive removal of ciprofloxacin and amoxicillin from single and binary aqueous systems using acid-activated carbon from Prosopis juliflora. Environ Res 188:109825. https://doi.org/10.1016/j.envres.2020.109825
Sahu N, Singh J, Koduru JR (2021) Removal of arsenic from aqueous solution by novel iron and iron–zirconium modified activated carbon derived from chemical carbonization of Tectona grandis sawdust: isotherm, kinetic, thermodynamic and breakthrough curve modelling. Environ Res 200:111431. https://doi.org/10.1016/j.envres.2021.111431
Belhachemi M, Addoun F (2011) Comparative adsorption isotherms and modeling of methylene blue onto activated carbons. Appl Water Sci 1:111–117. https://doi.org/10.1007/s13201-011-0014-1
Al-Malack MH, Dauda M (2017) Competitive adsorption of cadmium and phenol on activated carbon produced from municipal sludge. J Environ Chem Eng 5:2718–2729
Lütke SF, Igansi AV, Pegoraro L et al (2019) Preparation of activated carbon from black wattle bark waste and its application for phenol adsorption. J Environ Chem Eng 7:103396. https://doi.org/10.1016/j.jece.2019.103396
Tao J, Huo P, Fu Z et al (2019) Characterization and phenol adsorption performance of activated carbon prepared from tea residue by NaOH activation. Environ Technol 40:171–181. https://doi.org/10.1080/09593330.2017.1384069
Nirmala G, Murugesan T, Rambabu K et al (2021) Adsorptive removal of phenol using banyan root activated carbon. Chem Eng Commun 208:831–842. https://doi.org/10.1080/00986445.2019.1674839
Lua AC (2020) A detailed study of pyrolysis conditions on the production of steam-activated carbon derived from oil-palm shell and its application in phenol adsorption. Biomass Conv Bioref 10:523–533. https://doi.org/10.1007/s13399-019-00447-9
Mojoudi N, Mirghaffari N, Soleimani M et al (2019) Phenol adsorption on high microporous activated carbons prepared from oily sludge: equilibrium, kinetic and thermodynamic studies. Sci Rep 9:19352. https://doi.org/10.1038/s41598-019-55794-4
Maazou SDB, Hima HI, Alma MMM et al (2017) Elimination of the chromium by the elaborate activated coal and characterized from the c-ockle of the core of Balanites aegyptiaca. Int J Biol Chem Sci 11:3050–3065
Dehbi A, Dehmani Y, Omari H et al (2020) Hematite iron oxide nanoparticles (α-Fe2O3): synthesis and modelling adsorption of malachite green. J Environ Chem Eng 8:103394
Storck S, Bretinger H, Maier WF (1998) Characterization of micro- and mesoporous solids by physisorption methods and pore-size analysis. Appl Catal A 174:137–146. https://doi.org/10.1016/S0926-860X(98)00164-1
Son Y-R, Park S-J (2020) Preparation and characterization of mesoporous activated carbons from nonporous hard carbon via enhanced steam activation strategy. Mater Chem Phys 242:122454
Janković B, Manić N, Dodevski V et al (2019) Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization. J Clean Prod 236:117614
Lv S, Li C, Mi J, Meng H (2020) A functional activated carbon for efficient adsorption of phenol derived from pyrolysis of rice husk, KOH-activation and EDTA-4Na-modification. Appl Surf Sci 510:145425
Sayğılı H, Sayğılı GA (2019) Optimized preparation for bimodal porous carbon from lentil processing waste by microwave-assisted K2CO3 activation: spectroscopic characterization and dye decolorization activity. J Clean Prod 226:968–976
Zhang J, Gao J, Chen Y et al (2017) Characterization, preparation, and reaction mechanism of hemp stem based activated carbon. Results Phys 7:1628–1633
Shirbhate VA, Gulwade DP, Bhandarkar SE, Narsing SV (2020) Preparation and spectroscopic characterization of Pistachio nut shell’s activated carbon using ZnCl2 for removal of transition metal ions. Mater Today: Proc 29:1259–1264
Li Y, Li Y, He X et al (2019) Efficient synthesis of alkynyl carbon materials derived from CaC2 through solvent-free mechanochemical strategy for supercapacitors. SN Appl Sci 1(2):1–9
Kan Y, Yue Q, Li D et al (2017) Preparation and characterization of activated carbons from waste tea by H3PO4 activation in different atmospheres for oxytetracycline removal. J Taiwan Inst Chem Eng 71:494–500
Kra DO, Allou NB, Atheba P et al (2019) Preparation and characterization of activated carbon based on wood (Acacia auriculeaformis, Côte d’Ivoire). J Encapsulation Adsorpt Sci 09:63. https://doi.org/10.4236/jeas.2019.92004
Giraldo L, Moreno-Piraján JC (2014) Study of adsorption of phenol on activated carbons obtained from eggshells. J Anal Appl Pyrol 106:41–47
Han Y, Zhang Q, Wu L (2020) Influence on the adsorption of phenol on single-walled carbon nanotubes caused by NaCl and an electrostatic field in saline. Desalination 477:114270
Sellaoui L, Kehili M, Lima EC et al (2019) Adsorption of phenol on microwave-assisted activated carbons: modelling and interpretation. J Mol Liq 274:309–314
Yousef RI, El-Eswed B (2009) The effect of pH on the adsorption of phenol and chlorophenols onto natural zeolite. Colloids Surf A 334:92–99
Awad AM, Shaikh SMR, Jalab R et al (2019) Adsorption of organic pollutants by natural and modified clays: a comprehensive review. Sep Purif Technol 228:115719. https://doi.org/10.1016/j.seppur.2019.115719
Ashanendu M, Sudip K (2019) Phenol adsorption from wastewater using clarified sludge from basic oxygen furnace. J Environ Chem Eng 7(4):103259. https://doi.org/10.1016/j.jece.2019.103259
Z-Flores E, Abatal M, Bassam A, et al (2017) Modeling the adsorption of phenols and nitrophenols by activated carbon using genetic programming. J Clean Prod 161:860–870. https://doi.org/10.1016/j.jclepro.2017.05.192
Mamane OS, Zanguina A, Daou I, Natatou I (2016) Préparation et caractérisation de charbons actifs à base de coques de noyaux de Balanites Eagyptiaca et de Zizyphus Mauritiana. J Soc Ouest-Afr Chim 41:59–67
Bamba D, Dongui B, Trokourey A et al (2009) Etudes comparées des méthodes de préparation du charbon actif, suivies d’un test de dépollution d’une eau contaminée au diuron. J soc Ouest-Afr chim 28:41–52
Hernández-Barreto DF, Giraldo L, Moreno-Piraján JC (2020) Dataset on adsorption of phenol onto activated carbons: equilibrium, kinetics and mechanism of adsorption. Data Brief 32:106312
Liu X-Q, Ding H-S, Wang Y-Y et al (2016) Pyrolytic temperature dependent and ash catalyzed formation of sludge char with ultra-high adsorption to 1-naphthol. Environ Sci Technol 50:2602–2609
Dąbrowski A, Podkościelny P, Hubicki Z, Barczak M (2005) Adsorption of phenolic compounds by activated carbon—a critical review. Chemosphere 58(8):1049–1070
Lorenc-Grabowska E, Gryglewicz G, Diez M (2013) Kinetics and equilibrium study of phenol adsorption on nitrogen-enriched activated carbons. Fuel 114:235–243
Kumar A, Jena HM (2016) Removal of methylene blue and phenol onto prepared activated carbon from Fox nutshell by chemical activation in batch and fixed-bed column. J Clean Prod 137:1246–1259
Fu Y, Shen Y, Zhang Z et al (2019) Activated bio-chars derived from rice husk via one- and two-step KOH-catalyzed pyrolysis for phenol adsorption. Sci Total Environ 646:1567–1577
Yoon SU, Mahanty B, Ha HM, Kim CG (2016) Phenol adsorption on surface-functionalized iron oxide nanoparticles: modeling of the kinetics, isotherm, and mechanism. J Nanopart Res 18:1–10
Cheng WP, Gao W, Cui X et al (2016) Phenol adsorption equilibrium and kinetics on zeolite X/activated carbon composite. J Taiwan Inst Chem Eng 62:192–198
Gupta A, Balomajumder C (2015) Simultaneous removal of Cr(VI) and phenol from binary solution using Bacillus sp. immobilized onto tea waste biomass. J Water Process Eng 6:1–10
Acknowledgements
The authors would like to thank the Deanship of Scientific Research at Umm Al-Qura University for supporting this work by Grant Code: 20- SCI-1-01-0006. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2018R1A5A1025137).
Funding
Deanship of Scientific Research at Umm Al-Qura University, Grant Code: 20- SCI-1–01-0006. National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2018R1A5A1025137).
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YD, TL, and AM, formal analysis, visualization, data curation, writing-original draft preparation. YT, HL, and AAA, investigation, resources, project administration, funding acquisition, writing—review and editing. H-SL and SA, conceptualization, methodology, validation, supervision.
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Dehmani, Y., Lamhasni, T., Mohsine, A. et al. Adsorption removal of phenol by oak wood charcoal activated carbon. Biomass Conv. Bioref. 14, 8015–8027 (2024). https://doi.org/10.1007/s13399-022-03036-5
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DOI: https://doi.org/10.1007/s13399-022-03036-5