Abstract
Two-dimensional layered tin diselenide (SnSe2) is a promising material for NO2 gas detection at room temperature because of its high adsorption energy of NO2 and a good intrinsic conductivity. However, there are only a few reports on dependence on its morphology and NO2 gas detection properties. Here, we investigate the correlation with the morphologies and NO2 gas detection properties of SnSe2 synthesized by a hydrothermal route. With increasing the reaction time, the morphologies of SnSe2 are changed from disk-like shape to flower-like hierarchical one caused by the inherent self-assembly behavior, while preserving the hexagonal crystal structure. Based on various morphologies of SnSe2, we fabricated gas sensor devices with interdigitated electrodes. Among various morphologies of SnSe2, the hierarchical SnSe2 device exhibits the highest NO2 gas detection properties at room temperature, achieving gas response of 22% toward 100 ppm NO2 and superior gas selectivity with respect to other gas species. This is attributed to the higher specific surface area of hierarchical morphology than other morphologies and improved crystallinity.
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References
Kaur, N., Zappa, D., Comini, E.: Shelf life study of NiO nanowire sensors for NO2 detection. Electron. Mater. Lett. 15, 743–749 (2019)
Wang, X., Liu, Y., Dai, J., Chen, Q., Huang, X., Huang, W.: Solution-processed p-SnSe/n-SnSe2 hetero-structure layers for ultrasensitive NO2 detection. Eur. J. Chem. 26, 3870–3876 (2020)
Kim, B.-J., Song, I.-G., Kim, J.-S.: In2O3-based micro gas sensor for detecting NOx gases. Electron. Mater. Lett. 10, 209–513 (2014)
Choi, S.-J., Kim, I.-D.: Recent developments in 2D nanomaterials for chemiresistive-type gas sensors. Electron. Mater. Lett. 14, 221–260 (2018)
Kim, J.H., Sung, J.S., Son, Y.M., Vasiliev, A.A., Malyshev, V.V., Koltypin, E.A., Eryshkin, A.V., Godovski, DYu., Pisyakov, A.V., Yakimov, S.S.: Propane/Butane semiconductor gas sensor with low power consumption. Sens. Actuators B Chem. 44, 452–457 (1997)
D’Olimpio, G., Farias, D., Kuo, C.-N., Ottaviano, L., Lue, C.S., Boukhvalov, D.W., Politano, A.: Tin diselenide (SnSe2) Van Der Waals semiconductor: surface chemical reactivity, ambient stability. Chem. Opt. Sens. Mater. 15, 1154 (2022)
Sun, G.-J., Lee, J.K., Lee, W.I., Dwivedi, R.P., Lee, C., Ko, T.: Ethanol sensing properties and dominant sensing mechanism of NiO-decorated SnO2 nanorod sensors. Electron. Mater. Lett. 13, 260–269 (2017)
Kumar, M., Rani, S., Singh, Y., Singh Gour, K., Nand Singh, V.: Tin-selenide as a futuristic material: properties and applications. RSC Adv. 11, 6477–6503 (2021)
Camargo Moreira, Ó.L., Cheng, W.-Y., Fuh, H.-R., Chien, W.-C., Yan, W., Fei, H., Xu, H., Zhang, D., Chen, Y., Zhao, Y., et al.: High selectivity gas sensing and charge transfer of SnSe2. ACS Sens. 4, 2546–2552 (2019)
Kumar Rai, R., Islam, S., Roy, A., Agrawal, G., Kumar Singh, A., Ghosh, A., Ravishankar, N.: Morphology controlled synthesis of low bandgap SnSe2 with high photodetectivity. Nanoscale 11, 870–877 (2019)
Ramasamy, P., Manivasakan, P., Kim, J.: Phase controlled synthesis of SnSe and SnSe2 hierarchical nanostructures made of single crystalline ultrathin nanosheets. CrystEngComm 17, 807–813 (2015)
Wang, T., Wang, Y., Zheng, S., Sun, Q., Wu, R., Hao, J.: Design of hierarchical SnSe2 for efficient detection of trace NO2 at room temperature. CrystEngComm 23, 6045–6052 (2021)
D’Olimpio, G., Genuzio, F., Menteş, T.O., Paolucci, V., Kuo, C.-N., Al Taleb, A., Lue, C.S., Torelli, P., Farías, D., Locatelli, A., et al.: Charge redistribution mechanisms in SnSe2 surfaces exposed to oxidative and humid environments and their related influence on chemical sensing. J. Phys. Chem. Lett. 11, 9003–9011 (2020)
Li, Y., Dai, M., Bai, J., Wang, Y., Li, Y., Wang, C., Liu, F., Sun, P., Wang, T., Lu, G.: Ppb-level NO2 sensing properties at room temperature of ultra-thin SnS2 nanopetals annealed at different temperatures. Sens. Actuators B Chem. 370, 132398 (2022)
Hu, X., Song, G., Li, W., Peng, Y., Jiang, L., Xue, Y., Liu, Q., Chen, Z., Hu, J.: Phase-controlled synthesis and photocatalytic properties of SnS, SnS2, and SnS/SnS2 heterostructure nanocrystals. Mater. Res. Bull. 48, 2325–2332 (2013)
Chee, S.-S., Gréboval, C., Magalhaes, D.V., Ramade, J., Chu, A., Qu, J., Rastogi, P., Khalili, A., Dang, T.H., Dabard, C., et al.: Correlating structure and detection properties in HgTe nanocrystal films. Nano Lett. 21, 4145–4151 (2021)
Wu, R., Hao, J., Wang, T., Zheng, S., Wang, Y.: Carbon-do**-induced energy-band modification and vacancies in SnS2 nanosheets for room-temperature Ppb-level NO2 detection. Inorg. Chem. Front. 8, 5006–5015 (2021)
Shin, S.-H., Park, J.-H., Ahn, B.-W., Ro, J.C., Suh, S.-J.: Facile synthesis of template-free SnS2 with different morphologies and excellent gas-sensing performance for NO2 gas-sensor applications. Phys. Status Solidi A 2100827 (2022)
Zhu, Q., Wang, H., Yang, J., **e, C., Zeng, D., Zhao, N.: Red phosphorus: an elementary semiconductor for room-temperature NO2 gas sensing. ACS Sens. 3, 2629–2636 (2018)
Acknowledgements
This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2021R1F1A1059833), the Ministry of Trade, Industry and Energy (MOTIE) and Korea Evaluation Institute of Industrial Technology (No. 20017545), and the Starting growth Technological R&D Program (S3194304) funded by the Ministry of SMEs and Startups (MSS, Korea).
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Hwa, Y., Seok, B. & Chee, SS. Correlating Morphology and NO2 Gas Detection at Room Temperature in Layered Tin Diselenide. Electron. Mater. Lett. 19, 212–217 (2023). https://doi.org/10.1007/s13391-022-00389-x
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DOI: https://doi.org/10.1007/s13391-022-00389-x