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Chemometric Investigation of Platinum Electrodeposition on Titanium Substrates for Ethanol Electro-oxidation

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Abstract

The objective of this work is to employ chemometric tools to investigate the influence of the synthesis parameters in platinum electrodeposition on a titanium substrate using cyclic voltammetry. Through a 22 factorial design, using as response the maximum peak current density during the ethanol electro-oxidation, one can observe that the number of cycles and the scan rate are both significant, but the interaction between them is not. The maximum peak current density is observed for the electrode obtained with NC = 20 cycles and SR = 200 mV s−1. The structural characterization indicates that the surface irregularity of the substrate causes an uneven growth of the (200) and (220) crystallographic planes, which present different performances in the electro-oxidation of ethanol. The response surface methodology indicates that the best experimental condition is that obtained with 10 cycles and 218 mV s−1. The Pt/Ti electrodes prepared with the optimized parameters are promising.

Graphical Abstract

A 22 factorial design was applied to prepare Pt/Ti for ethanol eletro-oxidation. Pt electrodeposits have shown an atypical “house of cards” morphology. Preferential orientation of Pt on Ti surface are related to better activity. Response surface methodology points 10 cycles at 218 mV s−1 as the best condition.

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Availability of Data and Materials

All experimental data was presented in this manuscript and in Supplementary Materials. Any further details can be accessed by contacting the corresponding author.

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Funding

The authors thank the funding agency CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico—proc. n. 437718/2016–5). J.P.T. da Silva Santos thanks CAPES (Coordenação de Aperfeiçoamento de Pessoa de Nível Superior) for the scholarship, to LAMUME - Laboratório Multiusuário de Microscopia Eletrônica (Instituto de Física – UFBA), and M.F. Gromboni thanks Fundação de Amparo à Pesquisa no Estado de São Paulo, FAPESP (#2019/00288–0), FAPESP/CDMF (#2013/07296–2).

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Authors and Affiliations

  1. Instituto de Química, Departamento de Físico-Química, Grupo de Pesquisa em Eletroquímica e Materiais – GPEEM. Trav. Barão de Jeremoabo, Universidade Federal da Bahia, 147, Campus de Ondina, Salvador, Bahia, 40170-280, Brazil

    João Paulo Tenório da Silva Santos & Valéria Cristina Fernandes

  2. Departamento de Química, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

    Sherlan Guimarães Lemos

  3. Centro de Ciências Exatas e de Tecnologia. LIEC, Universidade Federal de São Carlos, Rod. Washington Luís, Km 235, Monjolinho, São Carlos, SP, 13565905, Brazil

    Murilo Fernando Gromboni

  4. Universidade Federal de Alagoas. Av. Manoel Severino Barbosa, Arapiraca, S/N, Bom Sucesso - AL, 57309-005, Brazil

    Vinicius Del Colle

  5. Instituto de Química, Departamento de Química Geral e Inorgânica, Universidade Federal da Bahia, Laboratório de Catálise E Materiais. Trav. Barão de Jeremoabo, 147, Campus de Ondina, Salvador, Bahia, 40170-280, Brazil

    Artur José Santos Mascarenhas

Authors
  1. João Paulo Tenório da Silva Santos
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  2. Sherlan Guimarães Lemos
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  3. Murilo Fernando Gromboni
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  4. Vinicius Del Colle
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  5. Artur José Santos Mascarenhas
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  6. Valéria Cristina Fernandes
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Contributions

J.P.T. da Silva Santos performed the majority of electrochemical experiments and prepared the figures and tables. M. F. Gromboni performed the XRD characterization of electrodeposits and interpretation. S.G. Lemos has planned the chemometric experiments and helped the results interpretation. V. Del Colle helped in the interpretation of the electrochemical experiments. A.J.S. Mascarenhas and V.C. Fernandes have written the main manuscript text and the interpretation of the results. V.C. Fernandes is the main researcher responsible for the project and the formal doctoral supervisor of J.P.T. da Silva Santos.

Corresponding author

Correspondence to Valéria Cristina Fernandes.

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da Silva Santos, J.P.T., Lemos, S.G., Gromboni, M.F. et al. Chemometric Investigation of Platinum Electrodeposition on Titanium Substrates for Ethanol Electro-oxidation. Electrocatalysis 14, 570–580 (2023). https://doi.org/10.1007/s12678-023-00817-y

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