Abstract
Karst aquifers provide tremendous benefits to the people in the Indian subcontinent, but their studies are limited due to scanty observational data.This study examines the ionic and stable isotopic composition of water samples (n = 233 collected between 2012 and 2014) from karst springs in the western Himalayas to determine geogenic and anthropogenic solute sources and karst aquifers recharge. A principal component analysis suggests that karst springs acquire Ca2+, Mg2+, HCO3−, Na+, K+, and SO4− through natural processes, including carbonate and silicate dissolution. With a pollution index of 38%, about 50–88% of the NO3−, F− and Cl− contributing to karst springs have an anthropogenic origin. Karst springs are under-saturated with respect to calcite and dolomite, have higher pCO2, and electrical conductivity is inversely related to discharge, suggesting potential of recharging waters to dissolve the host rocks along flow paths. The springs display a distinct seasonal pattern in isotope characteristics with lower values from March to May and from August to October, reflecting the recharge from the snowmelt. Occasional higher isotopic values in February, June, and July suggest episodic rainfall events. The lower values of slope (6.9 ± 0.4) and intercept (9.8 ± 1.4) along with higher d-excess (> 16‰) of the karst springs provide strong evidence of winter snow as the primary source of recharge. Based on the karst index, the karst springs were classified as moderately to well karstified in the Liddar and Bringi catchments while slightly karstified in the Kuthar catchment. The study increases the understanding of karst aquifer sensitivity, which is necessary for implementing water supply protection schemes within the region.
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The corresponding authors will be happy to collaborate and share the data with a bonafide researcher upon a reasonable request, which can be sent to the above email address.
References
Absar A, Prakash G, Aggarwal RK (1991) A preliminary conceptual model of Nubra Valley Geothermal System, Ladakh, J & K, India. J Geol Soc India 37(6):533–545
Atkinson TC (1977) Diffuse flow and conduit flow in limestone terrain in the Mendip Hills, Somerset (Great Britain). J Hydrol 35(1–2):93–110. https://doi.org/10.1016/0022-1694(77)90079-8
Bakalowicz M (2005) Karst groundwater: a challenge for new resources. Hydrogeol J 13:148–160
Bhat NA, Jeelani G (2015) Delineation of the recharge areas and distinguishing the sources of karst springs in Bringi watershed, Kashmir Himalayas using hydrochemistry and environmental isotopes. J Earth Sys Sci 124(8):1667–1676. https://doi.org/10.1007/s12040-015-0629-y
Bhat MI, Zinuddin SM, Rais A (1981) Panjal Trap chemistry and the birth of Tethys. Geol Mag 118(4):367–375. https://doi.org/10.1017/S0016756800032234
Blasch KW, Bryson JR (2007) Distinguishing sources of ground water recharge by using δ2H and δ18O. Groundwater 45(3):294–308. https://doi.org/10.1111/j.1745-6584.2006.00289.x
Bonacci O (2015) Surface waters and groundwater in Karst. In: Stevanovic Z (ed) Karst aquifers—characterization and engineering, professional practice in earth sciences. Springer Int Pub, Switzerland, vol 5, pp 149–169. https://doi.org/10.1007/978-3-319-12850-4_5
Cattell RB (1966) The scree test for the number of factors. Multivariate Behav Res 1(2):245–276. https://doi.org/10.1207/s15327906mbr0102_10
Chen Z, Auler AS, Bakalowicz M, Drew D, Griger F, Hartmann J, Jiang G, Moosdorf N, Richts A, Stevanović Z, Veni G, Goldscheider N (2017) The World Karst Aquifer Map** project: concept, map** procedure and map of Europe. Hydrogeol J 25(3):771–785. https://doi.org/10.1007/s10040-016-1519-3
Chu H, Wei J, Wang R, **n B (2017) Characterizing the interaction of groundwater and surface water in the karst aquifer of Fangshan, Bei**g (China). Hydrogeol J 25:575–588. https://doi.org/10.1007/s10040-016-1507-7
Clark I, Fritz P (1997) Environmental isotopes in hydrogeology. CRC Press/Lewis Publishers, Boca Raton, New York, p 342. https://doi.org/10.1002/047147844X.gw211
Coplen TB (1995) New manuscript guidelines for the reporting of stable hydrogen, carbon, and oxygen isotope ratio data. J Petrol 24(5–6):707–712. https://doi.org/10.1093/oxfordjournals.petrology.a037273
Coward JMH, Waltham AC, Bowser RJ (1972) Karst springs in the Vale of Kashmir. J Hydrol 16(3):213–223
Craig H (1961) Isotopic variation in meteoric waters. Science 133:1702–1703. https://doi.org/10.1126/science.133.3465.1702
Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16(4):436–468. https://doi.org/10.1111/j.2153-3490.1964.tb00181.x
Dar FA, Perrin J, Riotte J, Gebauer HD, Narayana AC, Shakeel A (2011) Karstification in the Cuddapah Sedimentary basin, southern India: implications for groundwater resources. Acta Carsol 40(3):457–472. https://doi.org/10.3986/ac.v40i3.5
Dar FA, Perrin J, Narayana AC, Ahmed S (2014a) Review: carbonate aquifers and future perspectives of karst hydrogeology in India. Hydrogeol J 22(7):1493–1506
Dar RA, Romshoo SA, Chandra R, Ahmad I (2014b) Tectono–geomorphic study of the Karewa Basin of Kashmir Valley. J Asian Earth Sci 92:143–156. https://doi.org/10.1016/j.jseaes.2014.06.018
Das BK, Kaur P (2001) Major ion chemistry of Renuka lake and weathering processes, Sirmaur district, Himachal Pradesh, India. Env Geol 40:908–917. https://doi.org/10.1007/s002540100268
Datta NK (1983) Geology, evolution and hydrocarbon prospects of Kashmir Valley. Pet Asia J 11:171–179
Dragon K, Gorski J (2015) Identification of groundwater chemistry origins in a regional aquifer system (Wielkopolska region, Poland). Environ Earth Sci 73:2153–2167. https://doi.org/10.1007/s12665-014-3567-0
Dubey DP, Tiwari RN, Dwivedi U (2006) Evaluation of pollution susceptibility of Karst Aquifers of Rewa town (Madhya Pradesh) using “DRASTIC” approach. J Environ Sci Eng 48(2):113–118
Esteller MV, Andreu JM (2005) Anthropic effects on hydrochemical characteristics of the Valle de Toluca aquifer (central Mexico). Hydrogeol J 13(2):378–390. https://doi.org/10.1007/s10040-004-0395-4
Ford D, Williams P (2007) Karst hydrogeology and geomorphology. Wiley, Sussex, pp 1–554
Frumkin A (2013) New developments of karst geomorphology concepts, editor(s): John F. Shroder. Treat Geomorphol Acad Press 6:1–13. https://doi.org/10.1016/B978-0-12-374739-6.00112-3
Fynn OF, Yidana SM, Chegbeleh LP, Yiran GB (2016) Evaluating groundwater recharge processes using stable isotope signatures—the Nabogo catchment of the White Volta, Ghana. Arab J Geosci 9(4):279. https://doi.org/10.1007/s12517-015-2299-0
Gat JR (1981) Paleoclimate conditions in the Levant as revealed by the isotopic composition of paleowaters, Israel. Meteorol Res Paper 3:13–28
Ghasemizadeh R, Hellweger F, Butscher C, Padilla I, Vesper D, Field M, Alshawabkeh A (2012) Review: groundwater flow and transport modeling of karst aquifers, with particular reference to the North Coast Limestone aquifer system of Puerto Rico. Hydrogeol J 20(8):1441–1461. https://doi.org/10.1007/s10040-012-0897-4
Goldscheider N, Mádl-Szőnyi J, Erőss A, Schill E (2010) Thermal water resources in carbonate rock aquifers. Hydrogeol J 18:1303–1318. https://doi.org/10.1007/s10040-010-0611-3
Goldscheider N, Chen Z, Auler A, Bakalowicz M, Broda S, Drew D, Hartmann J, Jiang G, Moosdorf N, Stevanovic Z, Veni G (2020) Global distribution of carbonate rocks and karst water resources. Hydrogeol J 28:1661–1677. https://doi.org/10.1007/s10040-020-02139-5
Goldscheider N, Drew D (2007) Methods in Karst hydrogeology. IAHS Taylor & Francis, London, p 280
Gunn J (2007) Contributory area definition for groundwater source protection and hazard mitigation in carbonate aquifers. In: Parise M, Gunn J (eds) Natural and anthropogenic hazards in karst areas: recognition, analysis and mitigation. Geol Society London, vol 279, pp 97109. https://doi.org/10.1144/SP279.9
Gutiérrez F (2010) Hazards associated with karst. In: Alcántara-Ayala I, Goudie A (eds) Geomorphological hazards and disaster prevention (pp 161–176). Cambridge University Press, Cambridge. https://doi.org/10.1017/CBO9780511807527.013
Hartmann A, Goldscheider N, Wagener T, Lange J, Weiler M (2014) Karst water resources in a changing world: review of hydrological modeling approaches. Rev Geophys 52:218–242. https://doi.org/10.1002/2013RG000443
He X, Wu J, Guo W (2019) Karst spring protection for the sustainable and healthy living: the examples of Niangziguan spring and Shuishentang spring in Shanxi, China. Expo Health 11(2):153–165. https://doi.org/10.1007/s12403-018-00295-4
Heinz B, Birk S, Liedl R, Geyer T, Straub KL, Andresen J, Bester K, Kappler A (2009) Water quality deterioration at a karst spring (Gallusquelle, Germany) due to combined sewer overflow: evidence of bacterial and micro-pollutant contamination. Environ Geol 4:797–808
Jeelani G (2004) Effect of subsurface lithology on hydrochemistry of springs of a part of Kashmir Himalaya. Himal Geol 25(2):145–151
Jeelani G (2005) Chemical quality of the spring waters of Anantnag, Kashmir. J Geol Soc India 66(4):453–462
Jeelani G (2007) Hydrogeology of hard rock aquifer in Kashmir Valley: complexities and uncertainties. In: Ahmed S, Jayakumar R, Salih A (eds) Groundwater dynamics in hard rock aquifers: sustainable management and optimal monitoring network design. Capital, New Delhi, pp 243–248
Jeelani G (2008) Aquifer response to regional climate variability in a part of Kashmir Himalaya in India. Hydrogeol J 16:1625–1633. https://doi.org/10.1007/s10040-008-0335-9
Jeelani G (2010) Chemical and microbial contamination of Anantnag springs, Kashmir Valley. J Himal Ecol Sustain Dev 5:176–183
Jeelani G, Deshpande RD (2017) Isotope fingerprinting of precipitation associated with western disturbances and Indian summer monsoons across the Himalayas. J Earth Syst Sci 126:108. https://doi.org/10.1007/s12040-017-0894-z
Jeelani G, Bhat NA, Shivanna K (2010) Use of δ18O tracer to identify stream and spring origins of a mountainous catchment: a case study from Liddar watershed, Western Himalaya, India. J Hydrol 393(3–4):257–264. https://doi.org/10.1016/j.jhydrol.2010.08.021
Jeelani G, Bhat NA, Shivanna K, Bhat MY (2011) Geochemical characterization of surface water and spring water in SE Kashmir Valley, western Himalaya: implications to water–rock interaction. J Earth Syst Sci 120(5):921–932. https://doi.org/10.1007/s12040-011-0107-0
Jeelani G, Kumar US, Kumar B (2013) Variation of δ18O and δD in precipitation and stream waters across the Kashmir Himalaya (India) to distinguish and estimate the seasonal sources of stream flow. J Hydrol 481:157–165
Jeelani G, Shah RA, Hussain (2014) Hydrogeochemical assessment of groundwater in Kashmir Valley, India. J Ear Syst Sci 123(5):1031–1043
Jeelani G, Shah RA, Deshpande RD, Fryar AE, Perrin J, Mukherjee A (2017a) Distinguishing and estimating recharge to karst springs in snow and glacier dominated mountainous basins of the western Himalaya, India. J Hydrol 550:239–252. https://doi.org/10.1016/j.jhydrol.2017.05.001
Jeelani G, Shah RA, Jacob N, Deshpande RD (2017b) Estimation of snow and glacier melt contribution to Liddar stream in a mountainous basin, Western Himalaya: an isotopic approach. Isotopes Environ Health Stud 53(1):18–35. https://doi.org/10.1080/10256016.2016.1186671
Jeelani G, Deshpande RD, Shah RA, Hassan W (2017c) Influence of southwest monsoons in the Kashmir Valley, western Himalayas. Isotopes Environ Health Stud 53(4):400–412. https://doi.org/10.1080/10256016.2016.1273224
Jeelani G, Shah RA, Fryar AE, Deshpande RD, Mukherjee A, Perrin J (2018a) Hydrological processes in glacierized high-altitude basins of the western Himalayas. Hydrogeol J 26(2):615–628. https://doi.org/10.1007/s10040-017-1666-1
Jeelani G, Shah RA, Deshpande RD (2018b) Assessment of Groundwater in Karst System of Kashmir Himalayas, India. In: Mukherjee A (eds) Groundwater of South Asia. Springer Nature, Singapore, pp 85–100. https://doi.org/10.1007/978-981-10-3889-1_6
Jeelani G, Shah RA, Deshpande RD, Dimri AP, Mal S, Sharma A (2021) Isotopic analysis to quantify the role of the Indian monsoon on water resources of selected river basins in the Himalayas. Hydrol Proces 35(11):14406
Joshi K, Rai SP, Sinha R, Gupta S, Densmore AL, Rawat YS, Shekhar S (2018) Tracing groundwater recharge sources in the northwestern Indian alluvial aquifer using water isotopes (δ18O, δ2H and 3H). J Hydrol 559:835–847. https://doi.org/10.1016/j.jhydrol.2018.02.056
Jung H, Koh DC, Kim YS, Jeen SW, Lee J (2020) Stable isotopes of water and nitrate for the identification of groundwater flowpaths: a review. Water 12(1):138. https://doi.org/10.3390/w12010138
Kaiser HF (1960) The application of electronic computers to factor analysis. Educ Psychol Meas 20(1):141–151
Katz BG, Coplen TB, Bullen TD, Davis JH (1997) Use of chemical and isotopic tracers and geochemical modeling to characterize the interactions between ground water and surface water in mantled karst. Groundwater 35(6):1014–1028. https://doi.org/10.1111/j.1745-6584.1997.tb00174.x
Kou Y, Li Z, Hua K, Li Z (2019) Hydrochemical characteristics, controlling factors, and solute sources of streamflow and groundwater in the Hei River catchment, China. Water 11(11):2293. https://doi.org/10.3390/w11112293
Lee SK, Nam KA, Hoe YH, Min HY, Kim EY, Ko H, Kim S et al (2003) Synthesis and evaluation of cytotoxicity of stilbene analogues. Arch Pharm Res 26(4):253–257. https://doi.org/10.1007/bf02976951
Li P, Zhang Y, Yang N, **g L, Yu P (2016) Major ion chemistry and quality assessment of groundwater in and around a mountainous tourist town of China. Expo Health 8(2):239–252. https://doi.org/10.1007/s12403-016-0198-6
Li P, Wu J, Tian R, He S, He X, Xue C, Zhang K (2018) Geochemistry, hydraulic connectivity and quality appraisal of multilayered groundwater in the Hongdunzi Coal Mine, northwest China. Mine Water Environ 37(2):222–237. https://doi.org/10.1007/s10230-017-0507-8
Li P, Tian R, Liu R (2019) Solute geochemistry and multivariate analysis of water quality in the Guohua Phosphorite Mine, Guizhou Province, China. Expo Health 11(2):81–94. https://doi.org/10.1007/s12403-018-0277-y
Liu T, Gao X, Zhang X, Li C (2020) Distribution and assessment of hydrogeochemical processes of F-rich groundwater using PCA model: a case study in the Yuncheng Basin, China. Acta Geochim 39(2):216–225. https://doi.org/10.1007/s11631-019-00374-6
Lone S, Jeelani G, Deshpande RD, Mukherjee A (2019) Stable isotope (δ18O and δD) dynamics of precipitation in a high altitude Himalayan cold desert and its surroundings in Indus river basin, Ladakh. Atmos Res 221:46–57. https://doi.org/10.1016/j.atmosres.2019.01.025
López-Chicano M, Bouamama M, Vallejos A, Pulido-Bosch A (2001) Factors which determine the hydrogeo chemical behaviour of karstic springs. A case study from the Betic Cordilleras, Spain. Appl Geochem 16(9–10):1179–1192. https://doi.org/10.1016/S0883-2927(01)00012-9
Maurya AS, Shah M, Deshpande RD, Gupta SK (2009) Protocol for δ18O and δD analyses of water sample using Delta V plus IRMS in CF mode with gas bench II for IWIN National Programme at PRL, Ahmedabad. In: 11th ISMAS Triennial Conference of Indian Society for Mass Spectrometry (vol 314, pp 314–317). Indian Society for Mass Spectrometry Hyderabad
McGuire KJ, DeWalle DR, Gburek WJ (2002) Evaluation of mean residence time in subsurface waters using oxygen-18 fluctuations during drought conditions in the mid Appalachians. J Hydrol 261:132–149. https://doi.org/10.1016/S0022-1694(02)00006-9
Middlemiss CS (1910) Revision of Silurian-Trias sequence of Kashmir. Rec Geol Surv India 40(3):206–260
Mudarra M, Andreo B (2011) Relative importance of the saturated and the unsaturated zones in the hydrogeological functioning of karst aquifers: the case of alta cadena (southern spain). J Hydrol 397:263–280. https://doi.org/10.1016/j.jhydrol.2010.12.005
Mustafa O, Merkel B (2015) Classification of karst springs based on discharge and water chemistry in Makook karst system, Kurdistan Region, Iraq. Freiberg Online Geosci 39:1–24
Nesrine N, Rachida B, Ahmed R (2015) Multivariate statistical analysis of saline water–a case study: sabkha Oum LeKhialate (Tunisia). Int J Environ Sci Dev 6(1):40. https://doi.org/10.7763/IJESD.2015.V6.558
Ophori DU, Toth J (1989) Characterization of groundwater flow by field map** and numerical simulation, Ross Creek Basin, Alberta, Canada. Groundwater 27(2):193–201. https://doi.org/10.1111/j.1745-6584.1989.tb00440.x
Parise M (2016) How confident are we about the definition of boundaries in karst? Difficulties in managing and planning in a typical transboundary environment. In: Stevanovic Z, Kresic N, Kukuric N (eds) Karst without boundaries. CRC Press, Boca Raton, vol 23, pp 27–38. https://doi.org/10.1201/b21380-4
Parise M, Gabrovsek F, Ravbar N (2018) Recent advances in karst research: from theory to fieldwork and applications. Geol Soc Lond Spec Pub 466:124. https://doi.org/10.1144/SP466.26
Parkhurst DL, Appelo CA (2013) Description of input and examples for PHREEQC (Version 3)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. In: Chapter 43 of section A, Groundwater Books, Modelling Techniques. https://pubs.usgs.gov/tm/06/a43
Peng H, Mayer B, Harris S, Krouse HR (2004) A 10-year record of stable isotope ratios of hydrogen and oxygen in precipitation at Calgary, Alberta, Canada. Tellus B56:147–159. https://doi.org/10.3402/tellusb.v56i2.16410
Perrin J, Pochon A, Jeannin PY, Zwahlen F (2004) Vulnerability assessment in karstic areas: validation by field experiments. Environ Geol 46:237–245. https://doi.org/10.1007/s00254-004-0986-3
Price RM, Swart PK, Willoughby HE (2008) Seasonal and spatial variation in the stable isotopic composition of δ18O and δD of precipitation in south Florida. J Hydrol 358:193–205. https://doi.org/10.1016/j.jhydrol.2008.06.003
Qian H, Li P, Wu J, Zhou Y (2013) Isotopic characteristics of precipitation, surface and ground waters in the Yinchuan Plain, northwest China. Environ Earth Sci 70(1):57–70. https://doi.org/10.1007/s12665-012-2103-3
Qian H, Wu J, Zhou Y, Li P (2014) Stable oxygen and hydrogen isotopes as indicators of lake water recharge and evaporation in the lakes of the Yinchuan Plain. Hydrol Process 28:3554–3562. https://doi.org/10.1002/hyp.9915
Rashrash S, Ghawar B, Hweesh A (2015) Evaluating groundwater pollution using hydrochemical data: case study (Al Wahat Area East of Libya). J Wat Resour Protect 7:369–377. https://doi.org/10.4236/jwarp.2015.74029
Rao NS, Rao JP, Subrahmanyam A (2007) Principal component analysis in groundwater quality in a develo** urban area of Andhra Pradesh. J Geol Soc India 69(5):959–969
Rasool R, Fayaz A, Shafiq M, Singh H, Ahmed P (2021) Land use land cover change in Kashmir Himalaya: linking remote sensing with an indicator based DPSIR approach. Ecol Indic 125:107447. https://doi.org/10.1016/j.ecolind.2021.107447
Ren X, Li P, He X, Su F, Elumalai V (2021) Hydrogeochemical processes affecting groundwater chemistry in the central part of the Guanzhong Basin, China. Arch Environ Contam Toxicol 80(1):74–91. https://doi.org/10.1007/s00244-020-00772-5
Savio D, Stadler P, Reischer GH, Demeter K, Linke RB, Blaschke AP, Mach RL, Kirschner AKT, Stadler H, Farnleitner AH (2019) Spring water of an alpine karst aquifer is dominated by a taxonomically stable but discharge-responsive bacterial community. Front Microbiol 10:28. https://doi.org/10.3389/fmicb.2019.00028
Serianz L, Rman N, Brencic M (2020) Hydrogeochemical characterization of a warm spring system in a carbonate mountain range of the Eastern Julian Alps. Slovenia Water 12:1427. https://doi.org/10.3390/w12051427
Shah RA, Jeelani G (2016) Vulnerability of karst aquifer to contamination: a case study of Liddar catchment, Kashmir Himalayas. J Himal Ecol Sustain Dev 11:58–72
Shah RA, Jeelani G, Jacob N (2017) Estimating mean residence time of karst groundwater in mountainous catchments of Western Himalaya, India. Hydrol Sci J 62(8):1230–1242. https://doi.org/10.1080/02626667.2017.1313420
Shah RA, Jeelani G, Goldscheider N (2018) Karst geomorphology, cave development and hydrogeology in the Kashmir valley, Western Himalaya, India. Acta Carsol 47(1):5–21. https://doi.org/10.3986/ac.v47i1.5178
Shibasaki T, Balakrishna S, Yoshimura T, Venkatanarayana B, Furukama H, Venkateswara RT, Chuman N, Ramanohan RY, Venkateswaalu K (1985) Karstification process of carbonate rocks in the Cuddapah sedimentary Basin, Indian Peninsular Shield. J Fac Mar Sci Technol Tokai Univ 21:31–45
Singh Y (1985) Hydrogeology of the karstic area around Rewa, MP, India. In: Karst water resources, Proc. of the Ankara-Antalya Symposium. IAHS Publ. No. 161, IAHS, Wallingford, UK
Singh Y, Dubey DP (1997) Deep zone karst aquifers as a boon in central India. In: Beck BF, Stephenson JB (eds) The Engineering geology and hydrogeology of Karst Terranes. A. A. Balkema Publisher, Rotterdam, pp 245–249
Solder JE, Beisner KR (2020) Critical evaluation of stable isotope mixing end-members for estimating groundwater recharge sources: case study from the South Rim of the Grand Canyon, Arizona, USA. Hydrogeol J 28:1575–1591. https://doi.org/10.1007/s10040-020-02194-y
Stevanović Z (2019) Karst waters in potable water supply: a global scale overview. Environ Earth Sci 78:662. https://doi.org/10.1007/s12665-019-8670-9
Szramek K, Walter LM, Kanduč T, Ogrinc N (2011) Dolomite versus Calcite weathering in hydrogeochemically diverse watersheds established on bedded carbonates (Sava and Soča Rivers, Slovenia). Aquat Geochem 17(4–5):357–396
Tang C, ** H, Liang Y (2021) Using isotopic and hydrochemical indicators to identify sources of sulfate in Karst groundwater of the Niangziguan Spring Field, China. Water 13:390. https://doi.org/10.3390/w13030390
Vesper DJ, White WB (2003) Metal transport to karst springs during storm flow: an example from Fort Campbell, Kentucky/Tennessee, USA. J Hydrol 276:20–36. https://doi.org/10.1016/S0022-1694(03)00023-4
Vinnarasi F, Srinivasamoorthy K, Saravanan K, Gopinath S, Prakash R, Ponnumani G, Babu C (2021) Chemical weathering and atmospheric carbon dioxide (CO2) consumption in Shanmuganadhi, South India: evidences from groundwater geochemistry. Environ Geochem Health 43(2):771–790. https://doi.org/10.1007/s10653-020-00540-3
Vogelbacher A, Kazakis N, Voudouris K, Bold S (2019) Groundwater vulnerability and risk assessment in A Karst Aquifer of Greece using EPIK Method. Environ 6:116. https://doi.org/10.3390/environments6110116
Vreča P, Kern Z (2020) Use of water isotopes in hydrological processes. Water 12(8):2227. https://doi.org/10.3390/w12082227
Wadia DN (1975) Geology of India. Tata McGraw Hill Co, New Delhi, p 344
Waltham AC (1972) Caving in the Himalaya. Himal J 31:9. http://www.himalayanclub.org/hj/31/9/caving-in-the-himalaya
Wang F, Chen H, Lian J, Fu Z, Nie Y (2020) Seasonal recharge of spring and stream waters in a Karst catchment revealed by isotopic and hydrochemical analyses. J Hydrol. https://doi.org/10.1016/j.jhydrol.2020.125595
Wei M, Wu J, Li W, Zhang Q, Su F, Wang Y (2021) Groundwater geochemistry and its impacts on groundwater arsenic enrichment, variation, and health risks in Yongning County, Yinchuan Plain of northwest China. Expo Health. https://doi.org/10.1007/s12403-021-00391
Wu J, Li P, Qian H, Duan Z, Zhang X (2014) Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: case study in Laoheba phosphorite mine in Sichuan, China. Arab J Geosci 7(10):3973–3982. https://doi.org/10.1007/s12517-013-1057-4
Wu J, Li P, Wang D, Ren X, Wei M (2020) Statistical and multivariate statistical techniques to trace the sources and affecting factors of groundwater pollution in a rapidly growing city on the Chinese Loess Plateau. Hum Ecol Risk Assess 26(6):1603–1621. https://doi.org/10.1080/10807039.2019.1594156
Younos T, Schreiber M, Kosič Ficco K (2019) Karst water environment: advances in research, management and policy. Springer Cham. https://doi.org/10.1007/978-3-319-77368-1
Yu S, Chae G, Oh J, Kim SH, Kim D, Yun ST (2021) Hydrochemical and isotopic difference of spring water depending on flow type in a stratigraphically complex karst area of South Korea. Front Ear Sci 9
Zakhem AB, Charideh A, Kattaa B (2017) Using principal component analysis in the investigation of groundwater hydrochemistry of Upper Jezireh Basin, Syria. Hydrol Sci J 62(14):2266–2279. https://doi.org/10.1080/02626667.2017.1364845
Zhao S, Hu H, Tian F, Tie Q, Wang L, Liu Y, Shi C (2017) Divergence of stable isotopes in tap water across China. Sci Rep 7:43653. https://doi.org/10.1038/srep43653
Acknowledgements
The research work was funded by the Department of Science and Technology (DST), Government of India, under the research project DST No: SERB/F/1554/2012. The first author is also thankful to the Director, Wadia Institute of Himalayan Geology (WIHG), Dehradun, India, for the permission to publish this work. The assigned identification number of the manuscript is WIHG/0128.
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Shah, R.A., Jeelani, G., Yadav, J.S. et al. Hydrogeochemical and stable isotopic evidence to different water origins of karst springs in the western Himalayas, India. Environ Earth Sci 81, 297 (2022). https://doi.org/10.1007/s12665-022-10397-7
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DOI: https://doi.org/10.1007/s12665-022-10397-7