Abstract
This paper presents the results of a study of the Novosibirsk Tin Plant influence on the level of tin content in the environment in the southern Western Siberia. Based on the NCEP/NCAR reanalysis data and the tin content in the atmospheric precipitation that falls in 2014–2018 at the radius of 200 km from the emission source, it has been found that 90% of the precipitation events with an increased tin content and 75% and 82% of all Sn fluxes fallen, respectively, in warm and cold seasons were brought to the study area by air masses previously passed over the territory of the Novosibirsk Tin Plant. During the period of observation (from April 2014 to October 2018), the mean, median and weighted mean values of tin concentrations in atmospheric precipitation in the Southern Western Siberia were 0.25; 0.11 and 0.17 μg L−1, respectively. A significantly higher volume-weighted mean concentration of Sn was in cold period due to high sorption activity of snowflakes, but atmospheric deposition fluxes of tin were slightly higher in the warm period due to the more abundant precipitation and the larger number of events. The contamination factor calculated relative to the background territory (Valdai National Park, European part of Russia) showed that atmospheric precipitation collected at the southern Western Siberia is moderately contaminated with Sn. The main factors controlling the fluxes of Sn (emitted from the Novosibirsk Tin Plant) on the territory of the south of Western Siberia are the direction of the surface air masses movement, the frequency and abundance of precipitation, as well as the seasonal features of tin distribution in the system air–precipitation.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12665-021-09970-3/MediaObjects/12665_2021_9970_Fig6_HTML.png)
Similar content being viewed by others
References
National Centers for Environmental Prediction/National Weather Service/NOAA/U.S. Department of Commerce, 1994, updated monthly. NCEP/NCAR Global Reanalysis Products, 1948-continuing. Research Data Archive at NOAA/PSL. https://psl.noaa.gov/data/gridded/data.ncep.reanalysis.html. Accessed 29 April 2020
Artamonova SYu, Popov NA (2017) Element composition of fallout, accumulated in snow blanket of Novosibirsk tin plant area. Interexpo GEO-Siberia 4(2):141–145 (in Russian)
Bermudez GMA, Jasan R, Plá R, Pignata ML (2012) Heavy metals and trace elements in atmospheric fall-out: Their relationship with topsoil and wheat element composition. J Hazard Mater 213:447–456. https://doi.org/10.1016/j.jhazmat.2012.02.023
Bisquert DS, Peñas-Castejón JM, Garcia-Fernandez G (2017) The impact of atmospheric dust deposition and trace elements levels on the villages surrounding the former mining areas in a semi-arid environment (SE Spain). Atmos Environ 152:256–269. https://doi.org/10.1016/j.atmosenv.2016.12.043
Britter R (2003) Urban air pollution phenomenology. In: Moussiopoulos N (ed) Air Quality in Cities. Springer, Berlin, Heidelberg, pp 21–30
Brusseau ML, Matthias AD, Comrie AC, Musil SA (2019) Atmospheric Pollution. In: Brusseau M, Pepper I, Gerba C (eds) Environmental and Pollution Science, 3rd edn. Academic Press, London, pp 293–309
Cable E, Deng Y (2018) Trace elements in atmospheric wet precipitation in the Detroit metropolitan area: Levels and possible sources. Chemosphere 210:1091–1098. https://doi.org/10.1016/j.chemosphere.2018.07.103
Chou C, Stetze O, Weingartner E, Jurány Z, Kanji ZA, Lohmann U (2011) Ice nuclei properties within a Saharan dust event at the Jungfraujoch in the Swiss Alps. Atmos Chem Phys 11:4725–4738. https://doi.org/10.5194/acp-11-4725-2011
Cong Z, Kang S, Zhang Y, Li X (2010) Atmospheric wet deposition of trace elements to central Tibetan Plateau. Appl Geochem 25(9):1415–1421. https://doi.org/10.1016/j.apgeochem.2010.06.011
Croft B, Pierce JR, Martin RV, Hoose C, Lohmann U (2012) Strong sensitivity of aerosol concentrations to convective wet scavenging parameterizations in a global model/ Atmos. Chem Phys 12:1687–1732. https://doi.org/10.3929/ethz-b-000060512
Decree of the Russian Federation Government № 1316-r of July 8, 2015 (2015) On approval of the list of pollutants subject to state regulation measures in the field of environmental protection. Moscow. https://www.prlib.ru/en/node/678152. Accessed 20 April 2020
Engelhard C, De Toffol S, Lek I, Rauch W, Dallinger R (2007) Environmental impacts of urban snow management - The alpine case study of Innsbruck. Sci Total Environ 382(2–3):286–294. https://doi.org/10.1016/j.scitotenv.2007.04.008
Federal State Statistics Service (2021) https://rosstat.gov.ru/. Accessed 20 April 2021
Filimonova LM, Bychinskii VA, Parshin AV (2015) Air pollution assessment in the area of aluminum production by snow geochemical survey. Russ Meteorol Hydrol 40(10):691–698. https://doi.org/10.3103/S1068373915100076
Fujita S, Takahashi A, Weng JH, Huang LF, Kim HK, Li CK, Huang F, Jeng FT (2000) Precipitation chemistry in East Asia. Atmosc Environ 34(4):525–537. https://doi.org/10.1016/S1352-2310(99)00261-7
Gashkina NA, Moiseenko TI, Dinu MI, Tatsii YG, Baranov DY (2020) Biogeochemical migration of elements in the system “Atmospheric Precipitation-Crown Waters–Soil Waters–Lake” in the background region (Valdai National Park). Geochem Int 58(7):835–849. https://doi.org/10.1134/S001670292005002X
Granjeiro JM, Cruz R, Leite PE, Gemini-Piperni S, Boldrini LC, Ribeiro AR (2020) Health and environment perspective of tin nanocompounds: A safety approach. In: Marcelo OO (ed) Tin Oxide Materials. Elsevier, Amsterdam, pp 133–162
Guo J, Kang S, Huang J, Zhang Q, Tripathee L, Sillanpää M (2015) Seasonal variations of trace elements in precipitation at the largest city in Tibet, Lhasa. Atmos Res 153:87–97. https://doi.org/10.1016/j.atmosres.2014.07.030
Guo J, Kang S, Huang J, Sillanpää M, Niu H, Sun X, He Y, Wang S, Tripathe L (2016) Trace elements and rare earth elements in wet deposition of Lijiang, Mt. Yulong region, southeastern edge of the Tibetan Plateau. J Environ Sci 52:18–28. https://doi.org/10.1016/j.jes.2016.03.016
Guo J, Kang S, Huang J, Sillanpää M, Niu H, Sun X, Tripathee L (2017) Trace elements and rare earth elements in wet deposition of Lijiang, Mt. Yulong region, southeastern edge of the Tibetan Plateau. J Environ Sci 52:18–28. https://doi.org/10.1016/j.jes.2016.03.016
Hakanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14(8):975–1001
Howe P, Watts P (2005) Tin and inorganic tin compounds. World Health Organization, Geneva
International Tin Association (ITA) report (2020) Global Tin Resources and Reserves. https://www.internationaltin.org/wp-content/uploads/2020/02/Global-Resources-Reserves-2020-Update.pdf. Accessed 2 September 2020
Kalnay E, Kanamitsu M, Kistler R, Collins W, Deaven D, Gandin L, Zhu Y (1996) The NCEP/NCAR 40-year reanalysis project. Bull Amer Meteor Soc 77(3):437–472. https://doi.org/10.1175/1520-0477(1996)077%3c0437:TNYRP%3e2.0.CO;2
Keresztesi Á, Nita IA, Birsan MV, Bodor Z (2020) Szép R (2020) The risk of cross-border pollution and the influence of regional climate on the rainwater chemistry in the Southern Carpathians. Romania Environ Sci Pollut Res 27:9382–9402. https://doi.org/10.1007/s11356-019-07478-9
Kokovkin VV, Raputa VF, Shuvaeva OV (2013) Monitoring heavy metals contamination of snow cover in Novosibirsk tin plant environs. Interexpo GEO-Siberia 4(2):36–41
Krasnoyarova BA, Revyakin VS, Kharlamova NF, Silant’eva MM, Chernykh DV (2016) Altai krai. In: Plyusnin VM (ed) Geography of Siberia in the early 21st century, vol 5. Academic publishing house GEO, Novosibirsk, pp 54–71
Krasovskaya AYu, Storozhko IV, Udalcov EA (2019) Analysis of the impact of the Novosibirsk tin plant on soil contamination with heavy metals. Intellectual potential of Siberia, pp 287–294
Labuzova O, Noskova T, Lysenko M, Ovcharenko E, Papina T (2016) Snow cover as a source of technogenic pollution of surface water during the snow melting period. Principy èkologii 4:33–41. https://doi.org/10.15393/j1.art.2016.5203
Li M, Wang L, Liu J, Gao W, Song T, Sun Y, Li L, Li X, Wang Y, Liu L, Daellenbach KR, Paasonen PJ, Kerminen VM, Kulmala M, Wang Y (2020) Exploring the regional pollution characteristics and meteorological formation mechanism of PM2.5 in North China during 2013–2017. Environ Int 134:105283. https://doi.org/10.1016/j.envint.2019.105283
Liu WH, Zhao JZ, Ouyang ZY, Söderlund L, Liu GH (2005) Impacts of sewage irrigation on heavy metal distribution and contamination in Bei**g, China. Environ Int 31:805–812. https://doi.org/10.1016/j.envint.2005.05.042
Lü P, Han G, Wu Q (2017) Chemical characteristics of rainwater in karst rural areas, Guizhou Province, Southwest China. Acta Geochim 36:1–5. https://doi.org/10.1007/s11631-017-0238-3
Ma Y, Tang Y, Xu H, Zhang X, Liu H, Wang S, Zhang W (2019) Bulk/wet deposition of trace metals to rural, industrial, and urban areas in the Yangtze River Delta, China. Ecotox Environ Safety 169:185–191. https://doi.org/10.1016/j.ecoenv.2018.11.002
Marina-Montes C, Pérez-Arribas LV, Escudero M, Anzano J, Cáceres JO (2020) Heavy metal transport and evolution of atmospheric aerosols in the Antarctic region. Sci Total Environ 721:137702. https://doi.org/10.1016/j.scitotenv.2020.137702
Montoya-Mayor R, Fernández-Espinosa AJ, Seijo-Delgado I, Ternero-Rodríguez M (2013) Determination of soluble ultra-trace metals and metalloids in rainwater and atmospheric deposition fluxes: A 2-year survey and assessment. Chemosphere 92(8):882–891. https://doi.org/10.1016/j.chemosphere.2013.02.044
Nordberg GF, Fowler BA, Nordberg M (2014) Handbook on the Toxicology of Metals. Academic press, London
Noskova TV, Eyrikh AN, Dryupina EYu, Serykh TG, Ovcharenko EA, Papina TS (2014) Study of the quality of snow cover in Barnaul. Polzunovskiy Vestnik 3:208–212
Noskova TV, Eyrikh SS, Ovcharenko EA, Uskov TN, Papina TS (2015) Assessment of urban snow disposal sites on contamination of small rivers and adjacent territories. Bulletin AB RGS 37(2):10–15
Noskova TV (2017) Assessment of the impact of urban areas on pollution with phenol, formaldehyde and aluminum (III) surface water in the Upper Ob river basin near Barnaul. Dissertation, Institute for water and environmental problems of the Siberian Branch of the Russian Academy of Sciences
Pan YP, Wang YS (2015) Atmospheric wet and dry deposition of trace elements at 10 sites in Northern China. Atmos Chem Phys 15:951–972. https://doi.org/10.5194/acp-15-951-2015
Paramonov M, Gronholm T, Virkkula A (2011) Below cloud scavenging of aerosol particles by snow at an urban site in Finland. Boreal Environ Res 16(4):304–320
Pearce J, Wallace T (2015) Tin Chemicals Roadmap Ltd. ITRI Ltd, St Albans
Pearson C, Howard D, Moore C, Obrist D (2019) Mercury and trace metal wet deposition across five stations in Alaska: controlling factors, spatial patterns, and source regions. Atmos Chem Phys 19(10):6913–6929. https://doi.org/10.5194/acp-19-6913-2019
Ponomarenko TV, Larichkin FD, Sidorov DV (2016) Assessment of the tin industry creation prospects in the Republic of Kazakhstan. J of Min Inst 221:742–748
Radomskaya VI, Yusupov DV, Pavlova LM (2016) The analysis of chemical elements fallout within atmospheric precipitation on the Blagoveschensk city territory. Izvestia RAS SamSC 18(2–2):488–492
Sahoo PK, Dall’Agnol R, Salomão GN, Junior JSF, Silva MS, Souza Filho PWM et al (2019) High resolution hydrogeochemical survey and estimation of baseline concentrations of trace elements in surface water of the Itacaiúnas River Basin, Southeastern Amazonia. J Geochemical Explor 205:106321. https://doi.org/10.1016/j.gexplo.2019.06.003
Sidorova MYu (2012) Geo-ecological assessment of pollution of the territory of Novosibirsk and its small rivers. Dissertation, Institute for Water and Environmental Problems of the Siberian Branch of the Russian Academy of Sciences (IWEP SB RAS)
Siromlya TI (2018) Environmental assessment of impact on soils and plants of the Novosibirsk tin plant. Healthy soils are a guarantee of sustainable development, pp 123–126
State Report “On the state and protection of the environment the Novosibirsk region in 2018” (2019a) Ministry of Natural Resources and Environment of the Novosibirsk region Publ., Novosibirsk
State Report “On the state and use of mineral resources of the Russian Federation in 2018” (2019b) Ministry of Natural Resources and Environment of the Russian Federation Publ., Moscow
State Report “On the state and use of mineral resources of the Russian Federation in 2013” (2014) Ministry of Natural Resources and Environment of the Russian Federation Publ., Moscow
State Report “On the state and use of mineral resources of the Russian Federation in 2014” (2015) Ministry of Natural Resources and Environment of the Russian Federation Publ., Moscow
State Report “On the state and use of mineral resources of the Russian Federation in 2016 and 2017” (2018) Ministry of Natural Resources and Environment of the Russian Federation Publ., Moscow
Thorne RJ, Pacyna JM, Sundseth K, Pacyna EG (2018) Fluxes of Trace Metals on a Global Scale. In: DellaSala DA, Goldstein MI (eds) Encyclopedia of the Anthropocene. Elsevier, Amsterdam, pp 93–102
Tripathee L, Guo J, Kang S, Paudyal R, Sharma CM, Huang J, Sillanpää M (2020) Measurement of mercury, other trace elements and major ions in wet deposition at Jomsom: The semi-arid mountainvalley of the Central Himalaya. Atmos Res 234:104691. https://doi.org/10.1016/j.atmosres.2019.104691
Tueros I, Rodríguez JG, Borja A, Solaun O, Valencia V, Millán E (2008) Dissolved metal background levels in marine waters, for the assessment of the physico-chemical status, within the European Water Framework Directive. Sci Total Environ 407(1):40–52. https://doi.org/10.1016/j.scitotenv.2008.08.026
Tume P, González E, King RW, Monsalve V, Roca N, Bech J (2018) Spatial distribution of potentially harmful elements in urban soils, city of Talcahuano, Chile. J Geochemical Explor 184:333–344. https://doi.org/10.1016/j.gexplo.2016.12.007
Vlasov D, Kasimov N, Eremina I, Shinkareva G, Chubarova N (2021) Partitioning and solubilities of metals and metalloids in spring rains in Moscow megacity. Atmos Pollut Res 12(1):255–271. https://doi.org/10.1016/j.apr.2020.09.012
WHO (2000) Air Quality Guidelines for Europe. WHO Regional Publications, Eur. Ser. No91. Regional Office for Europe, Copenhagen, Denmark
WHO (2011) Guidelines for drinking-water quality. WHO chronicle, 38(4).
Wu Q, Han G, Tao F, Tang Y (2012) Chemical composition of rainwater in a karstic agricultural area, Southwest China: the impact of urbanization. Atmos Res 111:71–78. https://doi.org/10.1016/j.atmosres.2012.03.002
Wu Y, Xu Z, Liu W et al (2016) Chemical compositions of precipitation at three non-urban sites of Hebei Province, North China: influence of terrestrial sources on ionic composition. Atmos Res 181:115–123. https://doi.org/10.1016/j.atmosres.2016.06.009
Wu Y, Zhang J, Ni Z, Liu S, Jiang Z, Huang X (2018) Atmospheric deposition of trace elements to Daya Bay, South China Sea. Mar Pollut Bull 127:672–683. https://doi.org/10.1016/j.marpolbul.2017.12.046
**ng J, Song J, Yuan H, Wang Q, Li X, Li N, Qu B (2017) Atmospheric wet deposition of dissolved trace elements to Jiaozhou Bay, North China: Fluxes, sources and potential effects on aquatic environments. Chemosphere 174:428–436. https://doi.org/10.1016/j.chemosphere.2017.02.004
Acknowledgements
This work was carried out under the investigational program of the IWEP SB RAS. Authors’ special thanks go to the staff of the Chemical Analytical Centre who took part in the research.
Funding
This work was supported by the Russian Academy of Sciences (Basic Research Program SB RAS 2013–2020, project AAAA-A17-117041210242-1) and the Russian Foundation for Basic Research (RFBR) (Project No 19-05-50057).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Stepanets, V.N., Malygina, N.S., Lovtskaya, O.V. et al. Regional-scale impacts of the major tin plant on the chemical composition of atmospheric precipitation in the south of Western Siberia (Russia). Environ Earth Sci 80, 701 (2021). https://doi.org/10.1007/s12665-021-09970-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12665-021-09970-3