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Precise Measurement of Qn Species Distributions in Modified Silicate Glass Using Phase-Adjusted Spinning Sideband NMR Experiment

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Abstract

Quantification of the distribution of Q(n) species, representing the number of bridging oxygens (n) around a silicate tetrahedra in potassium disilicate glass, is achieved using the two-dimensional Phase-Adjusted Spinning Sideband (2D PASS) sequence. Furthermore, we compare the relative concentrations of each Q(n) species obtained through the PASS method with a previous study utilizing the Magic Angle Flip** (MAF) technique on the same glass composition. While MAF has been employed in prior research to enhance the precision of Q(n) species measurements in glasses, it necessitates a specialized probe capable of reorienting the rotor axis. In contrast, alternatives like MAT or 2D PASS are more appealing as they can be implemented using a conventional MAS probe. In this study, we demonstrate that the PASS experiment provides comparable accuracy to MAF while significantly reducing the required time.

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Acknowledgements

The author Manasi Ghosh is grateful to Science and Engineering Research Board (SERB)-POWER research grant (file no. SPG/2021/000303), Department of Science and Technology (DST), Government of India, IoE-BHU Seed Grant-II (Dev. Scheme No. 6031(B), for financial support.

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Authors and Affiliations

  1. Department of Physics, Dr. Harisingh Gour Central University, Sagar, 470003, Madhya-Pradesh, India

    Prince Sen & Krishna Kishor Dey

  2. Physics Section, Mahila Maha Vidyalaya, Banaras Hindu University, Varanasi, 221005, Uttar-Pradesh, India

    Bijay Laxmi Pradhan & Manasi Ghosh

  3. Department of Zoology, Dr. Harisingh Gour Central University, Sagar, 470003, Madhya-Pradesh, India

    Lekhan Lodhi

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  1. Prince Sen
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Contributions

Dr. Krishna Kishor Dey had performed all the experiments. Prince Sen, Bijay Laxmi Pradhan, Lekhan Lodhi, had analyze the data, and make Figures of the manuscript under the guidance of Dr. Manasi Ghosh and Dr. Krishna Kishor Dey. Dr. Manasi Ghosh and Dr. Krishna Kishor Dey had prepared the manuscript.

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Correspondence to Manasi Ghosh or Krishna Kishor Dey.

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Sen, P., Pradhan, B.L., Lodhi, L. et al. Precise Measurement of Qn Species Distributions in Modified Silicate Glass Using Phase-Adjusted Spinning Sideband NMR Experiment. Silicon 15, 8065–8071 (2023). https://doi.org/10.1007/s12633-023-02639-5

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