Log in

Thermodynamic Modelling of Effect of Flux on the Liquidus Temperatures and Phase transitions in Coal Ash

  • Research Articles
  • Published:
Journal of the Geological Society of India

Abstract

Plant shutdowns due to the accumulation of ash materials in the boilers is a commonly practiced problem in thermal power sectors. Cleaning of ash products at regular intervals need to be necessary for maintaining the good furnace operation conditions. Use of slagging technology is the best practice for the removal of high temperature ash products, in which the melting temperature of ash is lowered by using the additive technology. In this paper, the properties of ash products formed during the combustion of low grade Indian coal were analyzed in terms of proximate and ash fusion temperature analysis. The effect of flux addition on the slagging behavior of Indian coal ash was analyzed. The AFT analysis of Indian origin coal ash shows that it is of non-fusible type. The formation of high temperature stable phases like kaolinite and quartz are the reason for high AFT temperatures in Indian origin coal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Banerjee, A., Mishra, P. R., Mohanty, A., Chakravarty, K., Biswas, R. D., Sahu, R. and Chakravarty, S. (2016) Distribution of mineral species in different coal seams of Talcher coalfield and its transformation behavior at varying temperatures. Internat. Jour. Coal Sci. Tech., v.3(2), pp.97–103.

    Article  Google Scholar 

  • Bilen, M. (2019) Ash melting behaviour of some low-grade Turkish coals and some imported steam coals. Combustion Theory and Modelling, v.23(6), pp.1105–1118.

    Article  Google Scholar 

  • Chakravarty, S., Mohanty, A., Banerjee, A., Tripathy, R., Mandal, G. K., Basariya, M. R., & Sharma, M. (2015) Composition, mineral matter characteristics and ash fusion behavior of some Indian coals. Fuel, v.150, pp.96–101.

    Article  Google Scholar 

  • Han, J., Yu, D., Wu, J., Yu, X., Liu, F., Wang, J. and Xu, M. (2019) Fine Ash Formation and Slagging Deposition during Combustion of Silicon-Rich Biomasses and Their Blends with a Low-Rank Coal. Energy & Fuels, v.33(7), pp.5875–5882.

    Article  Google Scholar 

  • He, C., Bai, J., Ilyushechkin, A., Zhao, H., Kong, L., Li, H. and Li, W. (2019) Effect of chemical composition on the fusion behaviour of synthetic high-iron coal ash. Fuel, v.253, pp.1465–1472.

    Article  Google Scholar 

  • Huang, Z., Li, Y., Lu, D., Zhou, Z., Wang, Z., Zhou, J. and Cen, K. (2013) Improvement of the coal ash slagging tendency by coal washing and additive blending with mullite generation. Energy & Fuels, v.27(4), pp.2049–2056.

    Article  Google Scholar 

  • Johnson, S. A., Wurster, J. and Comer, J. P. (2018) U.S. Patent No. 9,951,287. Washington, DC: U.S. Patent and Trademark Office.

  • Kim, J.H., Kim, G.B. and Jeon, C.H. (2017) Prediction of correlation between ash fusion temperature of ASTM and Thermo-Mechanical Analysis. Applied Thermal Engg., v.125, pp.1291–1299.

    Article  Google Scholar 

  • Kong, L., Bai, J., Bai, Z., Guo, Z. and Li, W. (2014) Improvement of ash flow properties of low-rank coal for entrained flow gasifier. Fuel, v.120, pp.122–129.

    Article  Google Scholar 

  • Lin, R., Lin, C., Li, Y. and Lin, B. (2019) Study on the synergistic effect of calcium and aluminum on improving ash fusion temperature of semi-coke. Internat. Jour. Coal Preparation and Utilization, pp.1–9.

  • Mishra, P.R., Sahu, R. and Chakravarty, S. (2020) Viscosity Analysis of Indian Origin Coal by Using FactSage at Different Temperatures. Trans. Indian Institute of Metals, v.73(1), pp.207–214.

    Article  Google Scholar 

  • Neupane, B., Ju, Y., Silwal, B.R., Singh, P.K. and Huang, C. (2017). Structural investigations of Eocene coals from foreland basin of central Nepal Himalaya. Energy Exploration and Exploitation, v.35(6), pp.713–733.

    Article  Google Scholar 

  • Park, W. and Oh, M.S. (2008) Slagging of petroleum coke ash using Korean anthracites. Jour. Industrial Engg. Chemistry, v.14(3), pp.350–356.

    Article  Google Scholar 

  • Shepard Jr., R.N. and Rozelle, P.L. (2002) U.S. Patent No. 6,484,651. Washington, DC: U.S. Patent and Trademark Office.

  • Singh, A. K., Singh, P. K., Singh, M. P., & Banerjee, P. K. (2015) Utilization of the permian coal deposits of West Bokaro, India: A petrochemical evaluation. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, v.37(10), pp.1081–1088.

    Article  Google Scholar 

  • Vassilev, S. V., Kitano, K., Takeda, S. and Tsurue, T. (1995) Influence of mineral and chemical composition of coal ashes on their fusibility. Fuel Processing Tech., v.45(1), pp.27–51.

    Article  Google Scholar 

  • Wang, G., Jensen, P. A., Wu, H., Frandsen, F.J., Laxminarayan, Y., Sander, B. and Glarborg, P. (2019) KOH capture by coal fly ash. Fuel, v.242, pp.828–836.

    Article  Google Scholar 

  • Wu, C., Wang, B., Zheng, J. and Li, H. (2019) Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature. Chinese Jour. Chemical Engg., v.27(5), pp.1200–1206.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Naresh Kumar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, N., Venugopal, R., Soren, S. et al. Thermodynamic Modelling of Effect of Flux on the Liquidus Temperatures and Phase transitions in Coal Ash. J Geol Soc India 96, 87–90 (2020). https://doi.org/10.1007/s12594-020-1508-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12594-020-1508-y

Navigation