Abstract
Hot extrusion was introduced to the Mg–10Gd–3Y–1.5Zn–0.5Zr alloy and microstructure evolution, texture configuration and elevated-temperature mechanical properties were investigated. The results show that the LPSO phase network-distributed along grain boundaries in the as-cast and homogenized alloys is broken and elongated after extrusion, and is streamlined along the extrusion direction (ED). After extrusion, a completely recrystallized microstructure with equiaxed grains of ~ 10 μm is formed. The most notable feature in as-extruded alloy is numerous fine lamellar structures in DRXed grains, which were identified as basal stacking faults (SFs) with nano-spaced by TEM analysis. The < 0001 > //TD texture results in the hard orientation of most grains along ED. The extruded alloy exhibits excellent elevated-temperature mechanical properties (UTS/287 MPa and YS/218 MPa at 300 °C; UTS > 200 MPa at 350 °C) along ED, which is significantly higher than alloys with similar composition or even higher rare earth content. The high elevated-temperature strength is mainly related to the fiber strengthening effect of streamline-distributed LPSO, the skeleton support effect of numerous SFs with nano spacing, and the texture strengthening effect of hard grain orientation.
Graphic Abstract
Similar content being viewed by others
Data Availability
The data that support the findings of this study are available on request from the corresponding author. The data are not publicly available due to privacy or ethical restrictions.
References
B.Q. Shi, L.Y. Zhao, X.L. Shang, B.H. Nie, D.C. Chen, C.Q. Li, Y.Q. Cheng, Reduction effect of final-pass heavy reduction rolling on the texture development, tensile property and stretch formability of ZWK100 alloy plates. J. Mater. Sci. Technol. 111, 211–223 (2022)
H.T. Jeong, W.J. Kim, The hot compressive deformation behavior of cast Mg-Gd-Y-Zn-Zr alloys with and without LPSO phase in their initial microstructures. J. Magnes. Alloys 10, 2901–2917 (2022)
H. Du, F. Li, P. Huo, Y. Wang, Microstructure evolution and ductility improvement mechanisms of magnesium alloy in interactive alternating forward extrusion. Trans. Nonferrous Met. Soc. China 32(8), 2557–2568 (2022)
X. Ren, Y. Huang, X. Zhang, H. Li, Y. Zhao, Influence of shear deformation during asymmetric rolling on the microstructure, texture, and mechanical properties of the AZ31B magnesium alloy sheet. Mater. Sci. Eng. A 800, 140306 (2021)
B.Q. Shi, L.Y. Zhao, D.C. Chen, C.Q. Li, Y. Dong, D. Wu, R.S. Chen, W. Ke, Characterization of a novel 14H-LPSO structure and related elevated-temperature mechanical behaviors in an extruded Mg–Y–Zn–Cu alloy. Mater. Sci. Eng. A 772, 138786 (2020)
A. Lindemann, J. Schmidt, M. Todte, T. Zeuner, Thermal analytical investigations of the magnesium alloys AM 60 and AZ 91 including the melting range. Thermochim. Acta 382(1), 269–275 (2002)
G. Li, J. Zhang, R. Wu, Y. Feng, S. Liu, X. Wang, Y. Jiao, Q. Yang, J. Meng, Development of high mechanical properties and moderate thermal conductivity cast Mg alloy with multiple RE via heat treatment. J. Mater. Sci. Technol. 34(7), 1076–1084 (2018)
M. Li, Y. Huang, Y. Liu, X. Wang, Z. Wang, Effects of heat treatment before extrusion on dynamic recrystallization behavior, texture and mechanical properties of as-extruded Mg-Gd-Y-Zn-Zr alloy. Mater. Sci. Eng. A 832, 142479 (2022)
X. Wang, Y. Wang, C. Ni, Y. Fang, X. Yu, P. Zhang, Effect of Gd content on microstructure and dynamic mechanical properties of solution-treated Mg−xGd−3Y−0.5Zr alloy. Trans. Nonferrous Met. Soc. China 32(7), 2177–2189 (2022)
C. Xu, S.W. Xu, M.Y. Zheng, K. Wu, E.D. Wang, S. Kamado, G.J. Wang, X.Y. Lv, Microstructures and mechanical properties of high-strength Mg–Gd–Y–Zn–Zr alloy sheets processed by severe hot rolling. J. Alloy. Compd. 524, 46–52 (2012)
J.F. Nie, X. Gao, S.M. Zhu, Enhanced age hardening response and creep resistance of Mg–Gd alloys containing Zn. Scripta Mater. 53(9), 1049–1053 (2005)
A. Singh, Y. Osawa, H. Somekawa, T. Mukai, Ultra-fine grain size and isotropic very high strength by direct extrusion of chill-cast Mg–Zn–Y alloys containing quasicrystal phase. Scripta Mater. 64(7), 661–664 (2011)
Y. Kawamura, K. Hayashi, A. Inoue, T. Masumoto, Rapidly solidified powder metallurgy Mg(97)Zn(1)Y(2)Alloys with excellent tensile yield strength above 600 MPa. Mater. Trans. 42(7), 1172–1176 (2001)
T. Homma, N. Kunito, S. Kamado, Fabrication of extraordinary high-strength magnesium alloy by hot extrusion. Scripta Mater. 61(6), 644–647 (2009)
S.M. Ramezani, A. Zarei-Hanzaki, H.R. Abedi, A. Salandari-Rabori, R. Minarik, Achievement of fine-grained bimodal microstructures and superior mechanical properties in a multi-axially forged GWZ magnesium alloy containing LPSO structures. J. Alloy. Compd. 793, 134–145 (2019)
Q.M. Peng, Y.M. Wu, D.Q. Fang, J. Meng, L.M. Wang, Microstructures and properties of Mg–7Gd alloy containing Y. J. Alloy. Compd. 430(1), 252–256 (2007)
K. Liu, L.L. Rokhlin, F.M. Elkin, D. Tang, J. Meng, Effect of ageing treatment on the microstructures and mechanical properties of the extruded Mg–7Y–4Gd–1.5Zn–0.4Zr alloy. Mater. Sci. Eng. A 527(3), 828–834 (2010)
B. Li, K. Guan, Q. Yang, X. Niu, D. Zhang, S. Lv, F. Meng, Y. Huang, N. Hort, J. Meng, Microstructures and mechanical properties of a hot-extruded Mg−8Gd−3Yb−1.2Zn−0.5Zr (wt%) alloy. J. Alloy. Compd. 776, 666–678 (2019)
H.R. Jafari Nodooshan, G. Wu, W. Liu, G. Wei, Y. Li, S. Zhang, Effect of Gd content on high temperature mechanical properties of Mg–Gd–Y–Zr alloy. Mater. Sci. Eng. A 651, 840–847 (2016)
H. Liu, F. Xue, J. Bai, A. Ma, J. Jiang, Formation Behavior of 14H long period stacking ordered structure in Mg–Y–Zn cast alloys with different α-Mg fractions. J. Mater. Sci. Technol. 32(12), 1267–1273 (2016)
Y.M. Zhu, A.J. Morton, J.F. Nie, Growth and transformation mechanisms of 18R and 14H in Mg–Y–Zn alloys. Acta Mater. 60(19), 6562–6572 (2012)
Y.M. Zhu, A.J. Morton, J.F. Nie, The 18R and 14H long-period stacking ordered structures in Mg–Y–Zn alloys. Acta Mater. 58(8), 2936–2947 (2010)
C. Xu, M.Y. Zheng, Y.Q. Chi, X.J. Chen, K. Wu, E.D. Wang, G.H. Fan, P. Yang, G.J. Wang, X.Y. Lv, S.W. Xu, S. Kamado, Microstructure and mechanical properties of the Mg–Gd–Y–Zn–Zr alloy fabricated by semi-continuous casting. Mater. Sci. Eng. A 549, 128–135 (2012)
Q. Yang, B.L. **ao, D. Wang, M.Y. Zheng, K. Wu, Z.Y. Ma, Formation of long-period stacking ordered phase only within grains in Mg–Gd–Y–Zn–Zr casting by friction stir processing. J. Alloy. Compd. 581, 585–589 (2013)
X. Liu, Z.Q. Zhang, W.Y. Hu, Q.C. Le, L. Bao, J.Z. Cui, Effects of extrusion speed on the microstructure and mechanical properties of Mg-9Gd-3Y-15Zn-08Zr alloy. J. Mater. Sci. Technol. 32(4), 313–319 (2016)
M. Matsuda, S. Ando, M. Nishida, Dislocation structure in rapidly solidified Mg97Zn1Y2 alloy with long period stacking order phase. Mater. Trans. 46(2), 361–364 (2005)
D.J. Li, X.Q. Zeng, J. Dong, C.Q. Zhai, W.J. Ding, Microstructure evolution of Mg-10Gd-3Y-1.2Zn-0.4Zr alloy during heat-treatment at 773 K. J. Alloy. Compd. 468(1–2), 164–169 (2009)
L. Liu, X. Zhou, S. Yu, J. Zhang, X. Lu, X. Shu, Z. Su, Effects of heat treatment on mechanical properties of an extruded Mg-4.3Gd-3.2Y-1.2Zn-0.5Zr alloy and establishment of its Hall-Petch relation. J. Magnes. Alloys 10(2), 501–512 (2022)
T. Chen, Z.Y. Chen, J.B. Shao, R.K. Wang, L.H. Mao, C.M. Liu, Evolution of LPSO phases in a Mg-Zn-Y-Gd-Zr alloy during semi-continuous casting, homogenization and hot extrusion. Mater. Des. 152, 1–9 (2018)
J. Wang, J. Meng, D.P. Zhang, D.X. Tang, Effect of Y for enhanced age hardening response and mechanical properties of Mg-Gd-Y-Zr alloys. Mater. Sci. Eng. A 456(1–2), 78–84 (2007)
N.Y. Liu, Z.Y. Zhang, L.M. Peng, W.J. Ding, Microstructure evolution and mechanical properties of Mg-Gd-Sm-Zr alloys. Mater. Sci. Eng. A 627, 223–229 (2015)
B. Li, B.G. Teng, E.D. Wang, Effects of accumulative rolling reduction on the microstructure characteristic and mechanical properties of Mg-Gd-Y-Zn-Zr sheets processed by hot rolling. Mater. Sci. Eng. A 765, 138317 (2019)
M. Yamasaki, T. Anan, S. Yoshimoto, Y. Kawamura, Mechanical properties of warm-extruded Mg-Zn-Gd alloy with coherent 14H long periodic stacking bordered structure precipitate. Scripta Mater. 53(7), 799–803 (2005)
Y. Jono, M. Yamasaki, Y. Kawamura, Effect of LPSO phase-stimulated texture evolution on creep resistance of extruded Mg-Zn-Gd alloys. Mater. Trans. 54(5), 703–712 (2013)
M. Yamasaki, M. Sasaki, M. Nishijima, K. Hiraga, Y. Kawamura, Formation of 14H long period stacking ordered structure and profuse stacking faults in Mg-Zn-Gd alloys during isothermal aging at high temperature. Acta Mater. 55(20), 6798–6805 (2007)
E. Abe, Y. Kawamura, K. Hayashi, A. Inoue, Long-period ordered structure in a high-strength nanocrystalline Mg-1 at% Zn-2 at% Y alloy studied by atomic-resolution Z-contrast STEM. Acta Mater. 50(15), 3845–3857 (2002)
Z.Q. Yang, M.F. Chisholm, G. Duscher, X.L. Ma, S.J. Pennycook, Direct observation of dislocation dissociation and Suzuki segregation in a Mg-Zn-Y alloy by aberration-corrected scanning transmission electron microscopy. Acta Mater. 61(1), 350–359 (2013)
C. Xu, J.P. Pan, T. Nakata, X.G. Qiao, Y.Q. Chi, M.Y. Zheng, S. Kamado, Hot compression deformation behavior of Mg-9Gd-2.9Y-1.9Zn-0.4Zr-0.2Ca (wt%) alloy. Mater. Charact. 124, 40–49 (2017)
S.K. Das, Y. Kang, T. Ha, I. Jung, Thermodynamic modeling and diffusion kinetic experiments of binary Mg–Gd and Mg–Y systems. Acta Mater. 71, 164–175 (2014)
M. Matsuda, S. Ii, Y. Kawamura, Y. Ikuhara, M. Nishida, Interaction between long period stacking order phase and deformation twin in rapidly solidified Mg97Zn1Y2 alloy. Mater. Sci. Eng. A 386(1), 447–452 (2004)
K. Wang, J. Wang, X. Peng, S. Gao, H. Hu, L. Zeng, F. Pan, Microstructure and mechanical properties of Mg-Gd-Y-Zn-Mn alloy sheets processed by large-strain high-efficiency rolling. Mater. Sci. Eng. A 748, 100–107 (2019)
X. Yang, X. Zhou, S. Yu, J. Zhang, X. Lu, X. Chen, L. Lu, W. Huang, Y. Liu, Tensile behavior at various temperatures of the Mg-Gd-Y-Zn-Zr alloys with different initial morphologies of LPSO phases prior to extrusion. Mater. Sci. Eng. A 851, 143634 (2022)
Z.J. Yu, Y. Huang, X. Qiu, Q. Yang, W. Sun, Z. Tian, D.P. Zhang, J. Meng, Fabrication of magnesium alloy with high strength and heat-resistance by hot extrusion and ageing. Mater. Sci. Eng. A 578, 346–353 (2013)
X. Hou, Z. Cao, L. Wang, S. Xu, S. Kamado, L. Wang, Microstructure and mechanical properties of extruded Mg–8Gd–2Y–1Nd–0.3Zn–0.6Zr alloy. Mater. Sci. Eng. A 528(25), 7805–7810 (2011)
L.Y. Chen, J.Q. Xu, H. Choi, M. Pozuelo, X.L. Ma, S. Bhowmick, J.M. Yang, S. Mathaudhu, X.C. Li, Processing and properties of magnesium containing a dense uniform dispersion of nanoparticles. Nature 528(7583), 539 (2015)
T. Chen, Z. Chen, J. Shao, R. Wang, L. Mao, C. Liu, The role of long-period stacking ordered phases in the deformation behavior of a strong textured Mg-Zn-Gd-Y-Zr alloy sheet processed by hot extrusion. Mater. Sci. Eng. A 750, 31–39 (2019)
K. Hagihara, A. Kinoshita, Y. Sugino, M. Yamasaki, Y. Kawamura, H.Y. Yasuda, Y. Umakoshi, Effect of long-period stacking ordered phase on mechanical properties of Mg97Zn1Y2 extruded alloy. Acta Mater. 58(19), 6282–6293 (2010)
C. Xu, M.Y. Zheng, S.W. Xu, K. Wu, E.D. Wang, G.H. Fan, S. Kamado, X.D. Liu, G.J. Wang, X.Y. Lv, Microstructure and mechanical properties of Mg–Gd–Y–Zn–Zr alloy sheets processed by combined processes of extrusion, hot rolling and ageing. Mater. Sci. Eng. A 559, 844–851 (2013)
K. Oh-Ishi, C.L. Mendis, T. Homma, S. Kamado, T. Ohkubo, K. Hono, Bimodally grained microstructure development during hot extrusion of Mg–2.4 Zn–0.1 Ag–0.1 Ca–0.16 Zr (at.%) alloys. Acta Mater. 57(18), 5593–5604 (2009)
Q. Yang, B.L. **ao, Q. Zhang, M.Y. Zheng, Z.Y. Ma, Exceptional high-strain-rate superplasticity in Mg–Gd–Y–Zn–Zr alloy with long-period stacking ordered phase. Scripta Mater. 69(11), 801–804 (2013)
Z. Yu, C. Xu, J. Meng, X. Zhang, S. Kamado, Effects of pre-annealing on microstructure and mechanical properties of as-extruded Mg-Gd-Y-Zn-Zr alloy. J. Alloy. Compd. 729, 627–637 (2017)
Acknowledgements
The authors are grateful for the financial supported by The National Natural Science Foundation of China (U1837207).
Funding
National Natural Science Foundation of China, U1837207, Yuanchun Huang.
Author information
Authors and Affiliations
Contributions
XW was involved in conceptualization, investigation, methodology, results analysis, writing original draft. YH contributed to funding acquisition, review and editing, project administration. YZ was involved in investigation, validation and methodology.
Corresponding author
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wang, X., Zhao, Y. & Huang, Y. Characterization of Hot-Extruded Mg–Gd–Y–Zn–Zr Alloy Containing a Novel Lamellar Structure and Related High Elevated-Temperature Mechanical Properties. Met. Mater. Int. 29, 2556–2570 (2023). https://doi.org/10.1007/s12540-023-01391-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12540-023-01391-0