Abstract
Soil geochemical study was carried out in Ogudu-Ogbagba area of Osun State, Southwestern Nigeria to evaluate a prospect for gold mineralization. Ninety (90) soil samples from B-horizon were collected from the study area. The samples were air dried and sieved with a 177-μm sieve, while approximately 1.0 g each of the sieved samples was digested using hot aqua regia (3HCl + 1HNO3). The resulting solutions were analysed for Ag, Au, Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn, using Flame Atomic Absorption Spectrometer (AAS) at the Department of Geology, Obafemi Awolowo University Ile-Ife. The geochemical data were subjected to both qualitative and quantitative analyses using univariate and multivariate statistical methods. The data were also used to plot location point symbol and contour geochemical maps of these metals with Arc GIS software, Oasis Montaj and Suffer 11 softwares.
The results revealed that the ten (10) metals determined in the soils have anomalous concentration values, out of which only Au, Cd, Fe and Ni are considered to be significant because of their associations. These metals are suggested to be derived from primary sources.
The study concluded that gold mineralization exists in the study area with occurrence of minor sulphides. The spatial distribution of the elements as shown in the geochemical maps indicate the most promising areas for both primary and alluvial gold prospecting in the area with Cd and Ni as pathfinder elements are Ogudu area and the north-western part of Ajebandele.
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References
Abaa SI (1983) The structure and petrography of alkaline rocks of the Mada Younger Granite Complex, Nigeria. J Afr Earth Sc 3:107–113
Adeoti B (2009) Geology of Ogudu area. Unpublished Independent Map** exercise report, Federal University of Technology, Akure, Nigeria, Osun State Nigeria
Adepoju MO (2019) Geochemical soil survey for base and precious metals in Dagbala-Atte district, southwestern Nigeria. Int J Geosci 10(2):141–159. https://doi.org/10.4236/ijg.2019.102009
Adesiyan A, Adekoya A, Akinlua A, Torto N (2014) Statistical studies of soil geochemical data from Gbongan-Odeyinka area, southwestern Nigeria. Geoinformatics Geostat 2:1–9
Adesiyan TA, Adekoya JA, Alao-Daniel AB (2018) Distribution patterns of trace metals in soils of Gbongan-Orileowu area, southwestern Nigeria. IFE J Sci 20(3):577–598
Ajayi TR (1988) Integrated exploration and statistical studies of geochemical data ofamphibolites in Ife-Ilesa gold field, southwestern Nigeria. Unpubl PhD Thesis, Obafemi Awolowo University, Ile-Ife, Nigeria, 386
Ajibade AC (1980) Geotectonic evolution of the Zungeru region. Unpubl PhDThesis, University of Wales, Aberystwyth, Nigeria, p 303
Alexakis D (2008) Geochemistry of stream sediment as a tool for assessing contamination by arsenic, chromium and other toxic elements: East Attica region. Greece European Water 21(22):57–72
Anthony FL (2007) Atomic absorption spectroscopy: a tutorial. Appl Spectrosc Rev 34(3):173–189
Chao TT, Theobald PK Jr (1976) The significance of secondary iron and manganese oxides in geochemical exploration. Econ Geol 71:1560–1569
Closs LG, Nichol I (1975) The role of factor and regression analysis in the interpretation of geochemical reconnaissance data. Can J Earth Sci 12:1316–1330
de Swardt AMJ (1953) The geology of the country around Ilesa. Bull Geol Surv Niger 23:50–54
Dzigbodi-Adjimah K (1993) Geology and geochemical patterns of the Birrimian gold deposits, Ghana. West Africa Chemical Geology 47(1–3):305–320
Elueze A (1977) Geological and geochemical studies in the Ilesha schist belt in relation to gold mineralization. Unpublished M Phil, Thesis, University of Ibadan, Nigeria, p 298
Ferré E, Gleizes G, Caby R (2002) Obliquely convergent tectonics and granite emplacement in the Trans-Saharan belt of eastern Nigeria: a synthesis. Precambr Res 114:199–219
Freyssinet P (1993) Dispersion de l’or au Cours du Cuirrassement lateritique du Sud Mali: application a la prospection geochimique. Chron Rech Min no 510, 25–40. In: Breedt MC (1995) Gold exploration in tropical and sub-tropical terrains with special emphasis in Central and West Africa
Grant NK (1978) Structural distinction between a metasedimentary cover and an underlying basement in the 600 Ma old Pan-African domain of northwestern Nigeria. Geol Soc Am Bull 89:50–58
Hawkes HE (1957) Principles of geochemical prospecting. United States Geological Survey Bulletin 1000-F 225–355
Jenne EA (1968) Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: the significant role of hydrous Mn- and Fe-oxides. Gould RF (Ed.) In: Trace inorganics in water. American Chemical Society, Hdv Chim Ser 73, Washington DC 337–387
Key RM, De Waele B, Liyungu AK (2004) A multielement baseline geochemical database from western extension of the central Africa copper belt in northwestern Zambia. Appl Earth Sci (Trans Inst Min Metall b) 113:1–15
Knight KV, lapworth DJ, Key RM, Johnson CC, Adekanmi MA, Arisekola TM (2011) A summary report, Nigerian Geochemical map** technical assistant project. British Geological survey commissioned report CR/10/054, 150
Levinson AA (1974) Introduction to exploration geochemistry. Applied Publication Limited, Calgary, p 1965
Kroner A, Ekwueme BN, Pidgeon RT (2001) The oldest rock in West Africa: SHRIMP zircon age for Early Archean migmatitic orthogneiss at Kaduna, Northern Nigeria. J Geol 109:399–406
Morsy M (1997) Tin-rare metal mineralization th near Mersa Alam. Proc. 30 Int’l Geol. Congr., 19 225–239. In Mohamed A. MORSY, International Archives of photogrammetry and Remote sensing 32, Part B 2000
Muntean J, Taufen P (2022) Geochemical exploration for gold through transported alluvial cover in Nevada: examples from the Cortez Mine. Econ Geol 106:809–833
Nowlan GA (1976) Concretionary manganese-iron oxides in streams and their usefulness as a sample medium for geochemical prospecting. JGeochemistry Explor 6:193–210
Nude PM, Asigri JM, Yidana SM, Arhin E, Foli G, Kutu JM (2012) Identifying pathfinder elements for gold in multi-element soil geochemical data from the Wa-Lawra Belt, northwest Ghana: a multivariate statistical approach. Int J Geosci 3:62–70
Olade MA, Elueze AA (1979) Petrochemistry of the amphibolites and Precambrian crustal evolution in the Pan-African domain of southwestern Nigeria. Precambr Res 8:303–318
Owoeye AB, Ajayi TR, Adesiyan TA (2015) Stream sediment geochemistry of Telemu and its environs. A tool in baseline assessment of mineralization potential. J Environ Earth Sci 5(8):140–172
Oyinloye AO (1997) Ore petrology and chemical composition of gold and associated sulphides in the Iperindo primary gold deposits in Ilesa area, southwestern Nigeria: implication on stages of mineralization. Afr J Sci Technol 1:71–81
Rahaman MA (1981) Recent advances in the study of the Basement Complex of Nigeria: In Oluyide et al. (Eds) Precambrian geology of Nigeria, published by Geological Survey of Nigeria. Esho Printers, Kaduna. 1st Symposium on Precambrian Geology of Nigeria, Kaduna 3 (abstract)
Reimann C, de Caritat P (1998) Chemical elements in the environment – fact sheets for the geochemist and environmental scientist. Springer-Verlag, Berlin-Heidelberg, p 398
Rose AW, Hawkes HE, Webb JS (1979) Geochemistry in mineral exploration. 2nd Edition, Academic Press London 1–21, 234–322.
Sunkari ED, Appiah-Twum M, Lermi A (2019) Spatial distribution and trace element geochemistry of laterites in Kunche area: implications for Au exploration targets in NW Ghana. J Afr Earth Sci 158:4. https://doi.org/10.1016/j.jafrearsci.2019.103519
Taylor SR (1965) The application of trace element data to problems in petrology. Phys Chem Earth 6(2):133–213
Turner DC (1983) Upper Proterozoic schist belts in the Nigerian sector of the Pan-African province of West Africa. Precambr Res 21:55–79
Ure AM, Berrow ML (1982) The elemental constituents of soils Bowen HJM (Ed) In Environmental chemistry. Royal Soc London Spec Rep Ser 2:94–204
Woakes M, Bafor BE (1983) Primary gold mineralization in Nigeria. In: Forster RF (ed) Gold 82, The geology and genesis of gold deposits. Geol Soc Zimbabwe Special Pub no 1, Balkema, Rotterdam pp 661–672
Acknowledgements
The study is part of the first author Master thesis at the Department of Geology, Obafemi Awolowo University, Ile-Ife, Nigeria. The authors would like to thank the Department for the facilities provided in support of the research.
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Salami, M., Adetunji, A., Olorunfemi, A.O. et al. Geochemical soil survey for gold in Ogudu-Ogbagba Area, Osun State, southwestern Nigeria. Arab J Geosci 17, 24 (2024). https://doi.org/10.1007/s12517-023-11821-3
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DOI: https://doi.org/10.1007/s12517-023-11821-3