Abstract
This article presents an energy-efficient biochar kiln that produces biochar from agricultural crop residues. The kiln is designed to be easy to operate and has minimal requirements for special operations. It works by heating biomass in a combustion chamber using recirculated pyrogas. The study optimized the process parameters and economics of producing biochar from wheat straw using Response Surface Methodology (RSM) based on Central Composite Design (CCD). The sustainable pyrolyzer had a thermal efficiency of 43.69%, with steady-state operation at 517.68 ± 98.18 °C. It produced an average of 54.57 ± 1.86 kg of biochar per batch, using 36.96 ± 3.66 kg of subabul (Leucaena leucocephala) as fuel and 179.61 ± 2.87 kg of wheat straw as feedstock. Subabul is chosen as a fuel due to its rapid growth, high calorific value, low moisture content, efficient combustion, and minimal smoke emission. The thermogravimetric index (TGI) and calorific value of WSB were 7.14 and 25.91 ± 0.74 MJ/kg, respectively. The benefit–cost ratio and payback period were 2.27 ± 0.16 and 4.92 ± 0.44 months, respectively.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs12155-024-10786-9/MediaObjects/12155_2024_10786_Fig9_HTML.png)
References
Dai Y, Sun Q, Wang W et al (2018) Utilizations of agricultural waste as adsorbent for the removal of contaminants: a review. Chemosphere 211:235–253. https://doi.org/10.1016/j.chemosphere.2018.06.179
Kiong Kong K, Sing Sii H (2020) Design and construction of mobile Biochar Kiln for small farmers. IOP Conf Ser Mater Sci Eng 788:. https://doi.org/10.1088/1757-899X/788/1/012075
Duque-Acevedo M, Belmonte-Ureña LJ, Cortés-García FJ, Camacho-Ferre F (2020) Agricultural waste: review of the evolution, approaches and perspectives on alternative uses. Glob Ecol Conserv 22:e00902. https://doi.org/10.1016/j.gecco.2020.e00902
Kim Oanh NT, Permadi DA, Hopke PK et al (2018) Annual emissions of air toxics emitted from crop residue open burning in Southeast Asia over the period of 2010–2015. Atmos Environ 187:163–173. https://doi.org/10.1016/j.atmosenv.2018.05.061
Alhazmi H, Loy ACM (2021) A review on environmental assessment of conversion of agriculture waste to bio-energy via different thermochemical routes: current and future trends. Bioresour Technol Reports 14:100682. https://doi.org/10.1016/j.biteb.2021.100682
Ramola S, Belwal T, Srivastava RK (2020) Thermochemical conversion of biomass waste-based biochar for environment remediation. Handbook of nanomaterials and nanocomposites for energy and environmental applications. Springer International Publishing, Cham, pp 1–16
Lee XJ, Ong HC, Gan YY et al (2020) State of art review on conventional and advanced pyrolysis of macroalgae and microalgae for biochar, bio-oil and bio-syngas production. Energy Convers Manag 210:112707. https://doi.org/10.1016/j.enconman.2020.112707
Hawash SI, Farah JY, El-Diwani G (2017) Pyrolysis of agriculture wastes for bio-oil and char production. J Anal Appl Pyrolysis 124:369–372. https://doi.org/10.1016/j.jaap.2016.12.021
Dhar SA, Sakib TU, Hilary LN (2022) Effects of pyrolysis temperature on production and physicochemical characterization of biochar derived from coconut fiber biomass through slow pyrolysis process. Biomass Convers Biorefinery 12:2631–2647. https://doi.org/10.1007/s13399-020-01116-y
Amenaghawon AN, Anyalewechi CL, Okieimen CO, Kusuma HS (2021) Biomass pyrolysis technologies for value-added products: a state-of-the-art review. Environ Dev Sustain 23:14324–14378. https://doi.org/10.1007/s10668-021-01276-5
K N Y, T PD, P S, et al (2022) Lignocellulosic biomass-based pyrolysis: a comprehensive review. Chemosphere 286:131824. https://doi.org/10.1016/j.chemosphere.2021.131824
Zhu Y, Chen M, Li Q et al (2018) A porous biomass-derived anode for high-performance sodium-ion batteries. Carbon N Y 129:695–701. https://doi.org/10.1016/j.carbon.2017.12.103
Patel MR, Rathore N, Panwar NL (2021) Influences of biochar in biomethanation and CO2 mitigation potential. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-021-01855-6
El-Naggar A, Lee SS, Rinklebe J et al (2019) Biochar application to low fertility soils: a review of current status, and future prospects. Geoderma 337:536–554. https://doi.org/10.1016/j.geoderma.2018.09.034
Das SK, Ghosh GK (2020) Soil health management through low cost biochar technology. Biochar applications in agriculture and environment management. Springer International Publishing, Cham, pp 193–206
Patel MR, Panwar NL (2023) Biochar from agricultural crop residues: environmental, production, and life cycle assessment overview. Resour Conserv Recycl Adv 19:200173. https://doi.org/10.1016/j.rcradv.2023.200173
Osman AI, Fawzy S, Farghali M et al (2022) Biochar for agronomy, animal farming, anaerobic digestion, composting, water treatment, soil remediation, construction, energy storage, and carbon sequestration: a review. Environ Chem Lett 20:2385–2485. https://doi.org/10.1007/s10311-022-01424-x
Karimi M, Shirzad M, Silva JAC, Rodrigues AE (2022) Biomass/Biochar carbon materials for CO2 capture and sequestration by cyclic adsorption processes: a review and prospects for future directions. J CO2 Util 57:101890. https://doi.org/10.1016/j.jcou.2022.101890
An N, Zhang L, Liu Y et al (2022) Biochar application with reduced chemical fertilizers improves soil pore structure and rice productivity. Chemosphere 298:134304. https://doi.org/10.1016/j.chemosphere.2022.134304
Allohverdi T, Mohanty AK, Roy P, Misra M (2021) A review on current status of biochar uses in agriculture. Molecules 26:5584. https://doi.org/10.3390/molecules26185584
Kavitha B, Reddy PVL, Kim B et al (2018) Benefits and limitations of biochar amendment in agricultural soils: a review. J Environ Manage 227:146–154. https://doi.org/10.1016/j.jenvman.2018.08.082
Lee JY, Lee SE, Lee DW (2022) Current status and future prospects of biological routes to bio-based products using raw materials, wastes, and residues as renewable resources. Crit Rev Environ Sci Technol 52:2453–2509. https://doi.org/10.1080/10643389.2021.1880259
Yang L, Wang XC, Dai M, et al (2021) Shifting from fossil-based economy to bio-based economy: status quo, challenges, and prospects. Energy 228:. https://doi.org/10.1016/j.energy.2021.120533
Zhao Y, Qamar SA, Qamar M et al (2021) Sustainable remediation of hazardous environmental pollutants using biochar-based nanohybrid materials. J Environ Manage 300:113762. https://doi.org/10.1016/j.jenvman.2021.113762
Hossain N, Bhuiyan MA, Pramanik BK et al (2020) Waste materials for wastewater treatment and waste adsorbents for biofuel and cement supplement applications: a critical review. J Clean Prod 255:120261. https://doi.org/10.1016/j.jclepro.2020.120261
Shackley S, Hammond J, Gaunt J, Ibarrola R (2011) The feasibility and costs of biochar deployment in the UK. Carbon Manag 2:335–356
De Corato U, De Bari I, Viola E, Pugliese M (2018) Assessing the main opportunities of integrated biorefining from agro-bioenergy co/by-products and agroindustrial residues into high-value added products associated to some emerging markets: a review. Renew Sustain Energy Rev 88:326–346. https://doi.org/10.1016/j.rser.2018.02.041
Gabhane JW, Bhange VP, Patil PD et al (2020) Recent trends in biochar production methods and its application as a soil health conditioner: a review. SN Appl Sci 2:1–21. https://doi.org/10.1007/s42452-020-3121-5
Wongsiriamnuay T, Tippayawong N (2010) Non-isothermal pyrolysis characteristics of giant sensitive plants using thermogravimetric analysis. Bioresour Technol 101:5638–5644. https://doi.org/10.1016/j.biortech.2010.02.037
Narde SR, Remya N (2022) Biochar production from agricultural biomass through microwave-assisted pyrolysis: predictive modelling and experimental validation of biochar yield. Environ Dev Sustain 24:11089–11102. https://doi.org/10.1007/s10668-021-01898-9
Mia S, Uddin N, Al Mamun Hossain SA et al (2015) Production of biochar for soil application: a comparative study of three Kiln models. Pedosphere 25:696–702. https://doi.org/10.1016/S1002-0160(15)30050-3
Alahakoon AMYW, Karunarathna AK, Dharmakeerthi RS, Silva FHCA (2022) Design and development of a double-chamber down draft (DcDD) pyrolyzer for biochar production from rice husk. J Biosyst Eng 47:458–467. https://doi.org/10.1007/s42853-022-00159-5
Te WZ, Muhanin KNM, Chu Y-M, et al (2021) Optimization of pyrolysis parameters for production of biochar from banana peels: evaluation of biochar application on the growth of Ipomoea aquatica. Front Energy Res 8:. https://doi.org/10.3389/fenrg.2020.637846
Gelman A (2005) Analysis of variance—why it is more important than ever. Ann Stat 33:. https://doi.org/10.1214/009053604000001048
Vieira FR, Romero Luna CM, Arce GLAF, Ávila I (2020) Optimization of slow pyrolysis process parameters using a fixed bed reactor for biochar yield from rice husk. Biomass Bioenerg 132:105412. https://doi.org/10.1016/j.biombioe.2019.105412
Bhaskar T, Bhavya B, Singh R et al (2011) Thermochemical Conversion of biomass to biofuels. Biofuels. Elsevier, pp 51–77
Zhang L, Xu C, (Charles), Champagne P, (2010) Overview of recent advances in thermo-chemical conversion of biomass. Energy Convers Manag 51:969–982. https://doi.org/10.1016/j.enconman.2009.11.038
Di Blasi C, Branca C, Galgano A (2017) On the experimental evidence of exothermicity in wood and biomass pyrolysis. Energy Technol 5:19–29. https://doi.org/10.1002/ente.201600091
Kung KS, Thengane SK, Lim CJ et al (2020) Thermal loss analysis and improvements for biomass conversion reactors. Energy Convers Manag 218:112924. https://doi.org/10.1016/j.enconman.2020.112924
Taherymoosavi S, Joseph S, Pace B, Munroe P (2018) A comparison between the characteristics of single- and mixed-feedstock biochars generated from wheat straw and basalt. J Anal Appl Pyrolysis 129:123–133. https://doi.org/10.1016/j.jaap.2017.11.020
Rathore NS, Pawar A, Panwar NL (2021) Kinetic analysis and thermal degradation study on wheat straw and its biochar from vacuum pyrolysis under non-isothermal condition. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-021-01360-w
Kumar M, Gupta RC (1996) Subabul: a wood species for electricity generation. Energy Sources 18:807–812. https://doi.org/10.1080/00908319608908812
De Melo BV, De Sá ME, Schaefer CEGR et al (2005) Properties of black soil humic acids from high altitude rocky complexes in Brazil. Geoderma 127:104–113. https://doi.org/10.1016/j.geoderma.2004.11.020
Sangsuk S, Buathong C, Suebsiri S (2020) High-energy conversion efficiency of drum kiln with heat distribution pipe for charcoal and biochar production. Energy Sustain Dev 59:1–7. https://doi.org/10.1016/j.esd.2020.08.008
Tripathi M, Sahu JN, Ganesan P (2016) Effect of process parameters on production of biochar from biomass waste through pyrolysis: a review. Renew Sustain Energy Rev 55:467–481. https://doi.org/10.1016/j.rser.2015.10.122
You S, Wang X (2019) On the Carbon abatement potential and economic viability of biochar production systems. Biochar from biomass and waste. Elsevier, pp 385–408
Kumar Mishra R, Jaya Prasanna Kumar D, Narula A et al (2023) Production and beneficial impact of biochar for environmental application: a review on types of feedstocks, chemical compositions, operating parameters, techno-economic study, and life cycle assessment. Fuel 343:127968. https://doi.org/10.1016/j.fuel.2023.127968
Singh S, Chakraborty JP, Mondal MK (2020) Pyrolysis of torrefied biomass: optimization of process parameters using response surface methodology, characterization, and comparison of properties of pyrolysis oil from raw biomass. J Clean Prod 272:122517. https://doi.org/10.1016/j.jclepro.2020.122517
Arafat Hossain M, Ganesan P, Jewaratnam J, Chinna K (2017) Optimization of process parameters for microwave pyrolysis of oil palm fiber (OPF) for hydrogen and biochar production. Energy Convers Manag 133:349–362. https://doi.org/10.1016/j.enconman.2016.10.046
Potnuri R, Rao CS, Surya DV et al (2023) Utilizing support vector regression modeling to predict pyro product yields from microwave-assisted catalytic co-pyrolysis of biomass and waste plastics. Energy Convers Manag 292:117387. https://doi.org/10.1016/j.enconman.2023.117387
Chen Z, Niu B, Zhang L, Xu Z (2018) Vacuum pyrolysis characteristics and parameter optimization of recycling organic materials from waste tantalum capacitors. J Hazard Mater 342:192–200. https://doi.org/10.1016/j.jhazmat.2017.08.021
Poddar S, Sarat Chandra Babu J (2021) Modelling and optimization of a pyrolysis plant using swine and goat manure as feedstock. Renew Energy 175:253–269. https://doi.org/10.1016/j.renene.2021.04.120
Acknowledgements
The authors are grateful to the Indian Council of Agricultural Research, Govt. of India, for providing financial aid to complete the research project under the Consortium Research Platform (CRP) on Energy from Agriculture.
Author information
Authors and Affiliations
Contributions
Maga Ram Patel: data curation, investigation, writing—original draft. Narayan Lal Panwar: conceptualization, data curation, formal analysis, investigation, supervision, writing—review and editing. Chitranjan Agrawal, Trilok Gupta, Kamalesh Kumar Meena, Sanwal Singh Meena: formal analysis, writing—review and editing.
Corresponding author
Ethics declarations
Ethical Approval and Consent to Participate.
This study does not involve any human participants or animals. All authors willingly provided informed consent to participate in this research.
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Patel, M.R., Panwar, N.L., Agrawal, C. et al. Design, Development, and Optimization of Sustainable Pyrolyzer for Biochar Production from Agricultural Crop Residue. Bioenerg. Res. (2024). https://doi.org/10.1007/s12155-024-10786-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12155-024-10786-9