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Experimental analysis of the performance of a passive direct alcoholic fuel cell with different alcoholic fuels and blends of methanol-alcoholic additives

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Abstract

Passive direct methanol fuel cells (DMFC) are most suitable for charging of portable electronic devices. Fuel and oxidant are supplied through diffusion and natural convection processes on the anode and cathode sides of the passive DMFC, respectively. This paper presents the details of experimental studies on the use of different anodic fuels i.e., ethanol, 1-propanol, 2-propanol, methanol in an alcoholic fuel cell. And also, the effect of adding these alcohols as additives to the methanol fuel on the performance of a passive DMFC is presented. For each one of the alcoholic fuels, the concentration of the fuel was varied from 0.5 M to 5 M, and the impact of fuel concentration on the performance of the cell was studied. Similarly, with methanol along with the other alcohol additives as the fuel in the passive DMFC, the additives concentration was varied from 0.5 M to 2.5 M insteps of 0.5 M and the methanol concentration was varied from 1 M to 5 M in steps of 1 M. The experimental results showed that among the anodic alcoholic fuels, 2-propanol generated the peak power density of 4.416 mW cm−2 at 4 M concentration. Similarly, it was also observed that among all the additives, the 2-propanol at 2 M concentration along with methanol at 4 M concentration produced the maximum power density.

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References

  1. Khoshmanesh S and Mirzaei M 2011 Performance Evaluation of a Direct Methanol Fuel Cell: Combination of Three-Dimensional Computational Fluid Dynamic Modelling and One-Dimensional Diffusion Layer Mathematical Modelling. Proceedings of the Institution of Mechanical Engineers Part A: Journal of Power and Energy. 225(6): 718–733

    CAS  Google Scholar 

  2. Boni Muralikrishna S, Rao Srinivasa, Naga Srinivasulu G and Narayana Ch Venkata 2019 Effect of Anode Gas Diffussion Layer Thickness and Porosity on the Performance of Passive Direct Methanol Fuel Cell. Chemical Product and Process Modeling. 14(4): 1–22

    Google Scholar 

  3. Rom Yang Sae, Kim Sang Kyung, Jung Doo Hwan, Kim Tae**, Kim Han Sung and Peck Dong-Hyun 2018 Effects of Ethanol in Methanol Fuel on the Performance of Membrane Electrode Assemblies for Direct Methanol Fuel Cells. Journal of Industrial and Engineering Chemistry. 66(October): 100–106

    Google Scholar 

  4. Meng Wang, Chen Ming, Yang Zhaoyi, Wang Yituo, Wang Yingrui, Liu Guicheng, Lee Joong Kee and Wang **ndong 2018 A Study on Fuel Additive of Methanol for Room Temperature Direct Methanol Fuel Cells. Energy Conversion and Management. 168(April): 270–275

    Google Scholar 

  5. Dianxue Cao and Bergens Steven H 2003 A Direct 2-Propanol Polymer Electrolyte Fuel Cell. Journal of Power Sources. 124(1): 12–17

    Article  ADS  Google Scholar 

  6. Alipour Ali, Rowshanzamir Soosan and Javad Mohammad 2016 Investigation of NaOH Concentration Effect in Injected Fuel on the Performance of Passive Direct Methanol Alkaline Fuel Cell with Modified Cation Exchange Membrane. Energy. 94: 589–599

    Article  Google Scholar 

  7. Munjewar Seema S, Thombre Shashikant B and Patil Awanikumar P 2019 Passive Direct Alcohol Fuel Cell Using Methanol and 2-Propanol Mixture as a Fuel. Ionics. 25(5): 2231–2241

    Article  Google Scholar 

  8. Zakil F Ahmad, S K Kamarudin and S Basri 2016 Modified Nafion Membranes for Direct Alcohol Fuel Cells: An Overview

  9. Claude Lamy, Lima Alexandre, LeRhun Véronique, Delime Fabien, Coutanceau Christophe and Léger Jean-Michel 2002 Recent Advances in the Development of Direct Alcohol Fuel Cells (DAFC). Journal of Power Sources. 105(2): 283–296

    Article  ADS  Google Scholar 

  10. Lee Choong Gon, Ojima Hiroyuki and Umeda Minoru 2008 Electrooxidation of C1 to C3 Alcohols with Pt and Pt Ru Sputter Deposited Interdigitated Array Electrodes. Electrochimica Acta. 53(7): 3029–3035

    Article  CAS  Google Scholar 

  11. Khaled Elsaid, Abdelfatah Shereen, Elabsir Ahmed Maher Abdel, Hassiba Raid J, Ghouri Zafar Khan and Vechot Luc 2021 Direct Alcohol Fuel Cells: Assessment of the Fuel’s Safety and Health Aspects. International Journal of Hydrogen Energy. 46(59): 30658–30668

    Article  Google Scholar 

  12. Gojković S L J, Tripković A V and Stevanović R M 2007 Mixtures of Methanol and 2-Propanol as a Potential Fuel for Direct Alcohol Fuel Cells. Journal of the Serbian Chemical Society. 72(12): 1419–1425

    Article  Google Scholar 

  13. Gupta Sagar Sen and Datta Jayati 2005 An Investigation into the Electro-Oxidation of Ethanol and 2-Propanol for Application in Direct Alcohol Fuel Cells (DAFCs). Journal of Chemical Sciences. 117(4): 337–344

    Article  Google Scholar 

  14. Anita Nagy Krisztina, Tóth Ildikó Y, Ballai Gergő, Varga Ágnes Timea, Szenti Imre, Sebők Dániel, Kopniczky Judit, Hopp Béla and Kukovecz Ákos 2020 Wetting and Evaporation on a Carbon Cloth Type Gas Diffusion Layer for Passive Direct Alcohol Fuel Cells. Journal of Molecular Liquids. 304(April): 112698

    Google Scholar 

  15. Boni Muralikrishna S, Rao Srinivasa and Naga Srinivasulu G 2019 Influence of Intermediate Liquid Electrolyte Layer on the Performance of Passive Direct Methanol Fuel Cell. International Journal of Green Energy. 16(15): 1475–1484

    Article  Google Scholar 

  16. Muralikrishna Boni, Surapaneni Srinivasa Rao, Golagani Naga Srinivasulu and Manupati Sateesh Kumar 2021 Experimental Investigations on the Effect of Current Collector Open Ratio on the Performance of a Passive Direct Methanol Fuel Cell with Liquid Electrolyte Layer. Chemical Papers. 75(1): 27–38

    Article  Google Scholar 

  17. Azam A M I N, Lee S H, Masdar M S, Zainoodin A M and Kamarudin S K 2019 Parametric Study on Direct Ethanol Fuel Cell (DEFC) Performance and Fuel Crossover. International Journal of Hydrogen Energy. 44(16): 8566–8574

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Mechanical Engineering, Maharaj Vijayaram Gajapathi Raj College of Engineering, Vizianagaram, Andhra Pradesh, India

    Muralikrishna Boni

  2. Automobile Engineering Section, D A Government Polytechnic, Ongole, Prakasam District, Andhra Pradesh, India

    Venkateswarlu Velisala

  3. Automobile Engineering Section, Government Polytechnic Atmakur, SPSR Nellore, Andhra Pradesh, India

    Venkateswarlu Velisala

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  1. Muralikrishna Boni
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  2. Venkateswarlu Velisala
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Correspondence to Muralikrishna Boni.

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Boni, M., Velisala, V. Experimental analysis of the performance of a passive direct alcoholic fuel cell with different alcoholic fuels and blends of methanol-alcoholic additives. Sādhanā 49, 54 (2024). https://doi.org/10.1007/s12046-023-02419-2

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