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Enhancement of Capacitive Properties of Ce-Doped MnAl2O4 Electrode for High Performance Energy Storage Applications

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Abstract

The assessment of long-term stability is a crucial factor in the context of pseudocapacitive materials. However, do** has been found to be an effective method for enhancing the stability and capacitive properties of materials. This investigation objective was to determine the Ce do** effect on MnAl2O4 material for electrochemical properties. The outstanding electrochemical properties of Ce-doped MnAl2O4 material can be ascribed to its intrinsic characteristics, such as its crystal structure, morphology and high surface area. This enhancement can be attributed to the improved BET surface area (93.82 m2 g−1) and the presence of a mesoporous structure. Furthermore, specific capacitances (Csp) of Ce-doped MnAl2O4 were found to be 1313.79 F g−1, with energy density of 45.25 Wh kg−1 and enhanced power density of 249 W kg−1 at 1 A g−1, indicating a promising electrochemical performance. Moreover, the Ce-doped MnAl2O4 electrode demonstrates exceptional cyclability, maintaining its performance over 5000 consecutive cycles, while also exhibit low impedance characteristics (Rct = 0.15 Ω). The current investigation explores a potential novel method to produce distinctive Ce-doped MnAl2O4 electrode materials, which are promising candidates with long-term cycling stability and high energy density for application in supercapacitors (SCs).

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

This research project was funded by the Deanship of Scientific Research and Libraries, Princess Nourah bint Abdulrahman University, through the Program of Research Project Funding After Publication, Grant No. (RPFAP-12-1445).

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Authors and Affiliations

  1. Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, 54000, Pakistan

    Mukhtiar Hussain & Mahmood Ali

  2. Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, 11671, Riyadh, Saudi Arabia

    Lamia Abu El Maati & Muneerah Amer Alomar

  3. Department of Chemistry, Government College University Lahore, Lahore, 54000, Pakistan

    Muhammad Abdullah

  4. Institute of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan, 64200, Pakistan

    Salma Aman

  5. Department of Physics, Government Graduate College Taunsa Sharif, Taunsa Sharif, 32100, Pakistan

    Hafiz Muhammad Tahir Farid

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Hussain, M., El Maati, L.A., Alomar, M.A. et al. Enhancement of Capacitive Properties of Ce-Doped MnAl2O4 Electrode for High Performance Energy Storage Applications. JOM (2024). https://doi.org/10.1007/s11837-024-06563-w

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