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Catalytic hydrogenation of disinfection by-product bromate by cobalt and nickle prussian blue analogues with borohydride

  • Environmental Engineering
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Abstract

As disinfection is employed extensively, disinfection by-product bromate has become an emerging environmental issue due to its carcinogenic toxicity. For develo** an effective alternative approach for reducing bromate, cobalt and nickel-based Prussian Blue (PB) analogues are proposed here for incorporating a convenient reducing agent, NaBH4 (i.e., a H2-rich reagent) for reducing bromate to bromide as cobalt and nickel are recognized as effective metals for catalyzing hydrolysis of NaBH4, and PB exhibits versatile catalytic activity. While CoPB and NiPB are comprised of the same crystalline structure, CoPB exhibits slightly higher specific surface area, more reductive surface, and more superior electron transfer than NiPB, enabling CoPB to accelerate bromate reduction. CoPB also exhibits a higher affinity towards NaBH4 than NiPB based on density functional theory calculations. Moreover, CoPB also exhibits a relatively low activation energy (i.e., 59.5 kJ/mol) of bromate reduction than NiPB (i.e., 63.2 kJ/mol). Furthermore, bromate reduction by CoPB and NiPB could be also considerably enhanced under acidic conditions, and CoPB and NiPB could still effectively remove bromate even in the presence of nitrate, sulfate and phosphate. CoPB and NiPB are also validated to be recyclable for reducing bromate, indicating that CoPB and NiPB are promising heterogeneous catalysts for reducing bromate.

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Acknowledgements

The authors are grateful for the funding granted from the Ministry of Science and Technology, and technical support from the National Center for High-Performance Computing, Taiwan. The authors gratefully acknowledge the use of SQUID000200 of MOST111-2731-M-006-001 belonging to the Core Facility Center of National Cheng Kung University.

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Authors and Affiliations

  1. Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan

    Po-Hsin Mao & Kun-Yi Andrew Lin

  2. School of Environmental Engineering, University of Seoul, Seoul, 02504, Korea

    Young-Kwon Park

  3. Department of Chemical Engineering and R&D Center for Membrane Technology, Chung Yuan Christian University, 200 Chung Pei Rd., Chungli, Taoyuan, Taiwan

    Yi-Feng Lin

  4. Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology, VNU-HCM, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, 700000, Viet Nam

    Bui Xuan Thanh

  5. International School, Thai Nguyen University, Thai Nguyen city, 250000, Viet Nam

    Duong Dinh Tuan

  6. Environment Research Center and Department of Environmental Health Engineering, Isfahan University of Medical Sciences, Isfahan, Iran

    Afshin Ebrahimi

  7. Residues and Resource Reclamation Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, Singapore, 637141, Singapore

    Grzegorz Lisak

  8. School of Civil and Environmental Engineering, Nanyang Technological University, Singapore, 639798, Singapore

    Grzegorz Lisak

  9. Department of Basic Science and Physical Education, Faculty of Science at Sriracha, Kasetsart University, Sriracha Campus, Chonburi, Thailand

    Thanit Tangcharoen

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  1. Po-Hsin Mao
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Correspondence to Yi-Feng Lin or Kun-Yi Andrew Lin.

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11814_2023_1445_MOESM1_ESM.pdf

Catalytic hydrogenation of disinfection by-product bromate by cobalt and nickle prussian blue analogues with borohydride

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Mao, PH., Park, YK., Lin, YF. et al. Catalytic hydrogenation of disinfection by-product bromate by cobalt and nickle prussian blue analogues with borohydride. Korean J. Chem. Eng. 40, 2876–2885 (2023). https://doi.org/10.1007/s11814-023-1445-8

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