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Sensory detection of selective substituted acyl chloride and nitrobenzene-sulfonyl chloride by interaction with 1-amino-4-hydroxy-9,10-anthraquinone using spectrophotometry and cyclic voltammetry

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Abstract

Chemical compounds belonging to the quinone class are known for their cyclic diketone structures. Anthraquinone derivatives have been used as sensing materials and dyes or pigments. The spectroscopic and voltammetric sensing capacity of 1-amino-4-hydroxy-9,10-anthraquinone was utilised to sense 2-bromobenzene-sulfonyl chloride, 4-nitrobenzene-sulfonyl chloride, benzoyl chloride, 2-chlorobenzoyl chloride, and 4-bromobenzoyl chloride. These substituted acyl chlorides and nitrobenzene-sulfonyl chloride are important intermediates in various reactions, and the product formation is highly dependent on their concentration. Therefore, it is crucial to take special care as all these compounds are carcinogenic. All studies were carried out in ethanol solvent. Results showed that 1-AHAQ could be effectively used as a UV–visible sensor for sensing 2-bromobenzene-sulfonyl chloride. 1-AHAQ demonstrates good results as a fluorescence sensor for sensing 4-bromobenzene-sulfonyl chloride and behaves as a good voltammetric sensor for sensing 4-nitrobenzene-sulfonyl chloride.

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Authors and Affiliations

  1. Department of Chemistry, Government College Women University Faisalabad, Faisalabad, 38000, Pakistan

    Bushra Tariq, Sadia Asim & Sobia Noreen

  2. Department of Chemistry, Government College University Faisalabad, Faisalabad, 38000, Pakistan

    Asim Mansha

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  1. Bushra Tariq
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  2. Asim Mansha
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Contributions

Concept and design of this article is collective contribution of all authors. They all read and approve the final manuscript of this research article. Bushra Tariq along with Sadia Asim plays a vital role in collecting data regarding the absorption and emission studies of 1-amino-4-hydroxy-9,10-Anthraquinone and effect of salts on selected fluorophore to be used as sensor. The voltammetric studies regarding the effect of salts on 1-amino-4-hydroxy-9,10-anthraquinone and its uses as voltammetric sensor were carried out by Asim Mansha and Sobia Noreen. The first draft of manuscript was written by Bushra Tariq which was later refined by Sadia Asim, Sobia Noreen and Asim Mansha.

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The review article entitled “sensory detection of selective substituted acyl chloride and nitrobenzene-sulfonyl chloride by interaction with1-amino-4-hydroxy-9,10-anthraquinone using spectrophotometry and cyclic voltammetry”. All the authors involved in the write up of this article do not have any conflict of interest.

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Tariq, B., Mansha, A., Asim, S. et al. Sensory detection of selective substituted acyl chloride and nitrobenzene-sulfonyl chloride by interaction with 1-amino-4-hydroxy-9,10-anthraquinone using spectrophotometry and cyclic voltammetry. Chem. Pap. (2024). https://doi.org/10.1007/s11696-024-03546-8

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