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Isothermal Sections of Ti-Mn-Zr Ternary System at 1020 and 800 °C

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Abstract

Phase relations of Ti-Mn-Zr ternary system at 1020 and 800 °C have been investigated mainly by metallographic observations, x-ray diffraction and electron microprobe analysis.A new ternary compound named K was detected, which shows a remarkable homogeneity range both at 1020 and 800 °C. The isothermal section at 1020 °C contains 8 single-phase regions, 13 two-phase regions and 6 three-phase regions, while the isothermal section at 800 °C consists of 9 single-phase regions, 15 two-phase regions and 7 three-phase regions. The continuous solid solution (Ti,Zr)Mn2 shows a wide homogeneous range both at 1020  and 800 °C, and the phase TiMn4 exists at 1020 °C and disappears at 800 °C.

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References

  1. H. Oesterreicher and H. Bittner, Studies of Hydride Formation in Ti1−xZrxMn2, Mater. Res. Bull., 1978, 13(1), p 83-88

    Article  Google Scholar 

  2. I. Jacob, A. Stern, A. Moran, D. Shaltiel, and D. Davidov, Hydrogen Absorption in (ZrxTi 1− x) B2 (B ≡ Cr, Mn) and the Phenomenological Model for the Absorption Capacity in Pseudo-Binary Laves-Phase Compounds, J. Less Common Met., 1980, 73(2), p 369-376

    Article  Google Scholar 

  3. J.L. Bobet, B. Chevalier, and B. Darriet, Crystallographic and Hydrogen Sorption Properties of TiMn2 Based Alloys, Intermetallics, 2000, 8(4), p 359-363

    Article  Google Scholar 

  4. S.V. Mitrokhin, T.N. Bezuglaya, and V.N. Verbetsky, Structure and Hydrogen Sorption Properties of (Ti, Zr)–Mn–V Alloys, J. Alloy Compd., 2002, 330, p 146-151

    Article  Google Scholar 

  5. V. Ivanchenko, T. Pryadko, V. Dekhtyarenko, and T. Kosorukova, Hydrogen Absorbing Properties of a Ti–Zr–Mn Eutectic Alloy, Chem. Met. Alloys, 2008, 1(2), p 133-136

    Google Scholar 

  6. V.G. Ivanchenko, V.A. Dekhtyarenko, and T.V. Pryadko, Hydrogen-Sorption Properties of (Ti, Zr) Mn2–x Intermetallic Alloy, Powder Metall. Met. Ceram., 2013, 52(5-6), p 340-344

    Article  Google Scholar 

  7. T.Z. Huang, Z. Wu, X.B. Yu, J.Z. Chen, B.J. **a, T.S. Huang, and N.X. Xu, Hydrogen Absorption–Desorption Behavior of Zirconium-Substituting Ti–Mn Based Hydrogen Storage Alloys, Intermetallics, 2004, 12(1), p 91-96

    Article  Google Scholar 

  8. S.V. Maksimova, V.F. Khorunov, V.G. Ivanchenko, and T.V. Pryadko, An Application of the Ti-Zr-Mn System Alloys for Brazing of Titanium Aluminides, Metallofizikai Noveishie Tekhnologii, 2012, 34(4), p 497-507

    Google Scholar 

  9. S.V. Maksimova, V.F. Khorunov, and V.G. Ivanchenko, Brazing of 48-2-2 Intermetallic Alloys with a Brazing Alloy of the Ti–Zr–Mn System, Weld. Int., 2012, 26(8), p 639-642

    Article  Google Scholar 

  10. K.C. Hari Kumar, P. Wollants, and L. Delacy, Thermodynamic Assessment of the Ti–Zr System and Calculation of the Nb–Ti–Zr Phase Diagram, J. Alloy Compd., 1994, 206(1), p 121-127

    Article  Google Scholar 

  11. N. Saunders, COST 507, Thermochemical Database for Light Metal Alloys, Vol 2, I. Ansara, A.T. Dinsdale, and M.H. Rand, Ed., European Commission, EUR 18499, Luxembourg, 1998, p 153-155

    Google Scholar 

  12. H. Flandorfer, J. Gröbner, and A. Stamou, Experimental Investigation and Thermodynamic Calculation of the Ternary System Mn-Y-Zr, Zeitschrift für Metallkunde, 1997, 88(7), p 529-538

    Google Scholar 

  13. J.L. Murray, The Mn−Ti (Manganese-Titanium) System, Bull. Alloy Phase Diagr., 1981, 2(3), p 334-343

    Article  Google Scholar 

  14. J.L. Murray, Phase Diagram of Binary Titanium Alloys, ASM International, Materials Park, 1987

    Google Scholar 

  15. I. Ansara, COST507, Vol 2, Thermochemical Database for Light Metal Alloys , I. Ansara, A.T. Dinsdale, and M.H. Rand, Ed., European Commission, EUR 18499EN, Luxembourg, 1998, p 241-244

    Google Scholar 

  16. L.Y. Chen, C.H. Li, K. Wang, H.Q. Dong, X.G. Lu, and W.Z. Ding, Thermodynamic Modeling of Ti–Cr–Mn Ternary System, Calphad, 2009, 33(4), p 658-663

    Article  Google Scholar 

  17. Ž. Blažina and R. Trojko, On Friauf-Laves Phases in the Zr1− xAlxT2, Zr1− x SixT2 and Zr1− xTixT2 (T ≡ Mn, Fe, Co) Systems, J. Less Common Met., 1987, 133(2), p 277-286

    Article  Google Scholar 

  18. V.G. Ivanchenko, T.V. Pryadko, I.S. Gavrylenko, and V.V. Pogorelaya, Phase Equilibria in the Ti–TiMn2–ZrMn2–Zr Partial System, Chem. Met. Alloys, 2006, 1, p 67-72

    Google Scholar 

  19. T.B. Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, Binary Alloy Phase Diagrams, ASM International, Materials Park, 1990

    Google Scholar 

  20. P. Villars, Pearson’s Handbook, Desk Edition, Crystallographic Data for Intermetallic Phases, ASM, Materials Park, 1997

    Google Scholar 

  21. R.M. Waterstrat, B.N. Das, and P.A. Beck, Phase Relationships in Titanium-Manganese System, Trans. Metall. Soc. AIME, 1962, 224(3), p 512-518

    Google Scholar 

  22. J.L. Murray, The Mn−Ti (Manganese-Titanium) System, Bull. Alloy Phase Diagr., 1981, 2(3), p 334-343

    Article  Google Scholar 

  23. R.M. Waterstrat, Identification of Intermediate Phases in the Manganese-Titanium System, Trans. Metall. Soc. AIME, 1961, 221(4), p 687-690

    Google Scholar 

  24. Y.L. Tang, G.S. Shao, and N.F. Shen, The Space Group Getermination of a Metastable Phase in a Rapidly Solidified AI-8.8Fe-3Ti Alloy With CBED, J. Chin. Electron Microsc. Soc., 1991, 10(3), p 277-280

    Google Scholar 

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Acknowledgment

The authors would like to thank for the financial support from the National Natural Science Fund of China (Grant No. 51171210).

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  1. School of Materials Science and Engineering, Central South University, Changsha, 410083, Hunan, People’s Republic of China

    Y. Wu, Z. Y. **e, H. S. Liu & Z. P. **

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  1. Y. Wu
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  2. Z. Y. **e
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  3. H. S. Liu
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Correspondence to Y. Wu or H. S. Liu.

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Wu, Y., **e, Z.Y., Liu, H.S. et al. Isothermal Sections of Ti-Mn-Zr Ternary System at 1020 and 800 °C. J. Phase Equilib. Diffus. 36, 262–273 (2015). https://doi.org/10.1007/s11669-015-0380-8

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  • DOI: https://doi.org/10.1007/s11669-015-0380-8

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