Abstract
Ti-6Al-4 V is commonly used in gas turbine engines and is sometimes subject to wear during operation. To address this, cost-effective and environmentally friendly solutions are being explored, with a focus on solid-state additive manufacturing techniques such as cold spray (CS). CS can create a dense structure; however, the existing porosity adversely affects the mechanical properties. To reduce the need for post-heat-treatment, this paper considers inner-diameter high- velocity air-fuel (ID_HVAF) as an alternative repair method which is a relatively low-temperature HVAF process that can deposit coatings with microstructures close to those observed in CS coatings. ID_HVAF process can deposit particles at high velocities and relatively low temperatures so that a significant portion of the particles forming the coatings are deposited in the solid state. This work is based on the deposition of Ti-6Al-4 V coatings using the ID_HVAF gun. During deposition, increasing the nozzle length increases the particle velocity and substrate temperature. The particles hit a softer surface with higher kinetic energy, thus increasing the density of the samples. However, HVAF will still oxidize some Ti-6Al-4 V particles and produce vanadium oxide. To study the tribological behavior, Ti-6Al-4 V counterballs were used to simulate the dovetail interface. According to the result, the top deposited layers were densified by the application of counterbalance force. Compared to an α-β Ti-6Al-4 V bulk sample, the coatings have a smaller wear track width and a greater wear depth, resulting in less wear on the counterballs. Each of the three samples shows a combination of abrasive and adhesive wear. The low cohesion between the particles in the coatings results in smaller oxide debris with a greater amount on the wear track of the coatings. By acting as a roller between the counter ball and the coating, this debris can slightly reduce the coefficient of friction.
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References
H.J.C. Voorwald, R.C. Souza, W.L. Pigatin, and M.O.H. Cioffi, Evaluation of WC-17Co and WC-10Co-4Cr Thermal Spray Coatings by HVOF on the Fatigue and Corrosion Strength of AISI 4340 Steel, Surf. Coat. Technol., 2005, 190, p 155-164.
D. Tejero-Martin, M. Rezvani Rad, A. McDonlad, and T. Hussain, Beyond Traditional Coatings: A Review on Thermal-Sprayed Functional and Smart Coatings, J. Therm. Spray Technol., 2019, 28, p 598-644.
M.P. Samuel, A.K. Mishra, and R.K. Mishra, Additive Manufacturing of Ti-6Al-4V Aero Engine Parts: Qualification for Reliability, J. Fail. Anal. Prev., 2018, 18(1), p 136-144.
B. Yuan, C.M. Harvey, R.C. Thomson, G.W. Critchlow, and S. Wang, A New Spallation Mechanism of Thermal Barrier Coatings on Aero-Engine Turbine Blade, Theor. Appl. Mech. Lett., 2018, 8, p 7-11.
Q. Zhang, Z.L. Liang, M. Cao, Z.F. Liu, A.F. Zhang, and B.H. Lu, Microstructure and Mechanical Properties of Ti-6Al-4V Alloy Prepared by Selective Laser Melting Combined with Precision Forging, Trans Nonferrous Metals Soc China, 2017, 27, p 1036-1042.
M. Shunmugavel, A. Polishett, and G. Littlefair, Microstructure and Mechanical Properties of Wrought and Additive Manufactured Ti-6Al-4V Cylindrical Bars, Procedia Technol., 2015, 20, p 231-236.
S. Fouvry, P. Arnaud, A. Mignot, and P. Neubauer, Contact Size, Frequency and Cyclic Normal Force Effect on Ti-6Al-4V Fretting Wear Processes: An Approach Combining Friction Power and Contact Oxygenation, Tribol. Int., 2017, 113, p 460-473.
L. Mishnaevsky Jr. and K. Thomsen, Costs of Repair of Wind Turbine Blades: INFLUENCE of Technology Aspects, Wind Energy, 2020, 23, p 2247-2255.
C.J. Huang, H.J. Wu, Y.C. **e, W.Y. Li, C. Verdy, M.P. Planche, H.J. Liao, and G. Montavon, Advanced Brass-Based Composites via Cold-Spray Additive-Manufacturing and its Potential in Component Repairing, Surf. Coat. Technol., 2019, 371, p 211-223.
S. Yin, P. Cavaliere, B. Aldwell, R. Jenkins, H. Liao, W. Li, and R. Lupoi, Cold Spray Additive Manufacturing and Repair: Fundamentals and Applications, Addit. Manuf., 2018, 21, p 628-650.
A. Sova, S. Grigoriev, A. Okunkova, and I. Smurov, Potential of Cold Gas Dynamic Spray as Additive Manufacturing Technology, Int. J. Adv. Manuf. Technol., 2013, 69, p 2269-2278.
X. Yan, C. Huang, C. Chen, R. Bolot, L. Dembinski, R. Huang, W. Ma, H. Liao, and M. Liu, Additive Manufacturing of WC Reinforced Maraging Steel 300 Composites by Cold Spray and Selective Laser Melting, Surf. Coat. Technol., 2019, 371, p 161-171.
C. Chen, Y. **e, X. Yan, S. Yin, H. Fukanuma, R. Huang, R. Zhao, J. Wang, Z. Ren, M. Liu, and H. Liao, Effect of Hot Isostatic Pressing (HIP) on Microstructure and Mechanical Properties of Ti- 6Al-4V Alloy Fabricated by Cold Spray Additive Manufacturing, Addit. Manuf., 2019, 27, p 595-605.
S. Bagherifard, S. Monti, M.V. Zuccoli, M. Riccio, J. Kondas, and M. Guagliano, Cold Spray Deposition for Additive Manufacturing of Freeform Structural Components Compared to Selective Laser Melting, Mater. Sci. Eng. A, 2018, 721, p 339-350.
X. **e, Y. Ma, C. Chen, G. Ji, C. Verdy, H. Wu, Z. Chen, S. Yuan, B. Normand, S. Yin, and H. Liao, Cold Spray Additive Manufacturing of Metal Matrix Composites (MMCs) Using a Novel Nano TiB2-Reinforced 7075Al powder, J Alloys Compds, 2020, 819, p 152962.
P.L. Fauchais, J.V.R. Heberlein, and M.I. Boulos, Thermal Spray Fundamentals from Powders to Parts, 1st ed. Springer, Berlin, 2015.
T. Schmidt, F. Gartner, H. Assadi, and H. Kreye, Development of a Generalized Parameter Window for Cold Spray Deposition, Acta Mater., 2006, 54, p 729-742.
M. Hassani-Gangaraj, D. Veysset, V.K. Champagne, K.A. Nelson, and C.A. Schuh, Adiabatic Shear Instability is not Necessary for Adhesion in Cold Spray, Acta Mater., 2018, 158, p 430-439.
J. **e, Simulation of cold spray particle deposition process, Thèse, Le Grade de Docteur, L’institut national des sciences appliquées de Lyon, (2014)
J. **e, D. Nelias, H.W. Berre, K. Ogawa, and Y. Ichikawa, Simulation of the Cold Spray Particle Deposition Process, J. Tribol., 2015, 137(4), p 041101.
S. Rahmati and A. Ghaei, The Use of Particle/Substrate Material Models in Simulation of Cold- Gas Dynamic-Spray Process, J. Therm. Spray Technol., 2014, 23, p 530-540.
M. Yu, W.-Y. Li, F.F. Wang, X.K. Suo, and H.L. Liao, Effect of Particle and Substrate Preheating on Particle Deformation Behavior on Cold Spraying, Surf. Coat. Technol., 2013, 220, p 174-178.
P. Khamsepour, C. Moreau, and A. Dolatabadi, Numerical Simulation of the Effect of Particle and Substrate Pre-Heating on Porosity Level and Residual Stress of As-Sprayed Ti6Al4V Components, J. Therm. Spray Technol., 2021, 31, p 70-83.
P. Khamsepour, J. Oberste-Berghaus, M. Aghasibeig, C. Moreau, and A. Dolatabadi, The Effect of Spraying Parameters of the Inner-Diameter High-Velocity Air-Fuel (ID-HVAF) Torch on Characteristics of Ti-6Al-4V In-Flight Particles and Coatings Formed at Short Spraying Distances, J. Therm. Spray Technol., 2023, 32, p 568-585.
J. Oberste-Berghaus, M. Aghasibeig, A. Burgess, P. Khamsepour, C. Moreau, and A. Dolatabadi, Exploring Miniaturized HVOF Systems for the Deposition of Ti-6Al-4V, J. Therm. Spray Technol., 2023, 32, p 760-772.
P. Khamsepour, C. Moreau, and A. Dolatabadi, Effect of Particle and Substrate Pre-Heating on the Oxide Layer and Material Jet Formation in Solid-state Spray Deposition: A Numerical Study, J. Therm. Spray Technol., 2023, 32, p 1153-1166.
R.M. Molak, H. Araki, W. Watanabe, H. Katanoda, N. Ohno, and S. Kuroda, Effects of Spray Parameters and Post-Spray Heat Treatment on Microstructure and Mechanical Properties of Warm-Sprayed Ti-6Al-4V Coatings, J. Therm. Spray Technol., 2017, 26, p 627-647.
N.W. Khun, A.W.Y. Tan, W. Sun, and E. Liu, Wear and Corrosion Resistance of Thick Ti-6Al- 4V Coating Deposited on Ti-6Al-4V Substrate via High-Pressure Cold Spray, J. Therm. Spray Technol., 2017, 26, p 1393-1407.
V.N.V. Munagala, T.B. Torgerson, T.W. Scharf, and R.R. Chromik, High Temperature Friction and Wear Behavior of Cold-Sprayed Ti-6Al-4V and Ti6Al4V-TiC Composite Coatings, Wear, 2019, 426, p 357-369.
N.W. Khun, A.W.Y. Tan, W. Sun, and E. Liu, Effect of Heat Treatment Temperature on Microstructure and Mechanical and Tribological Properties of Cold Sprayed Ti-6Al-4V Coatings, Tribol. Trans., 2017, 60, p 1033-1042.
P. Sirvent, M.A. Garrido, S. Lozano-Perez, and P. Poza, Oscillating and Unidirectional Sliding Wear Behaviour of Cold Sprayed Ti-6Al-4V Coating on Ti-6Al-4V Substrate, Surf. Coat. Technol., 2020, 382, 125152.
N.W. Khun, A.W.Y. Tan, W. Sun, and E. Liu, Effects of Nd: YAG Laser Surface Treatment on Tribological Properties of Cold-Sprayed Ti-6Al-4V Coatings Tested against 100Cr6 Steel under Dry Condition, Tribol. Trans., 2019, 62, p 391-402.
A. Roy, N. Sharifi, V.N.V. Munagala, S.A. Alidokhtb, P. Patel, M. Makowiec, R.R. Chromik, C. Moreau, and P. Stoyanov, Microstructural Evolution and Tribological Behavior of Suspension Plasma Sprayed CuO as High-Temperature Lubricious Coatings, Wear, 2023, 524–525, 204874.
A. Roy, V.N.V. Munagala, P. Patel, N. Sharifi, S.A. Alidokhtb, M. Makowiec, R.R. Chromik, C. Moreau, and P. Stoyanov, Friction and Wear Behavior of Suspension Plasma Sprayed Tantalum Oxide Coatings at Elevated Temperatures, Surf. Coat. Technol., 2023, 452, 129097.
P. Tonge, A. Roy, P. Patel, C.J. Beall, and P. Stoyanov, Environmentally Friendly Bonded MoS2 Solid Film Lubricants for Aerospace Applications: Closing the Gap, Sustain. Mater. Technol., 2023, 35, p e00552.
E.P. Whitenton and P.J. Blau, A Comparison of Methods for Determining Wear Volume and Surface Parameters of Spherically Tipped Sliders, Wear, 1998, 124, p 291-309.
N. Wu, F. Yang, W. Sun, G. Yang, Y. Liang, S. Zhang, and J. Wang, In-Flight Oxidation of Fe- Based Amorphous Particle During HVAF Spraying: Numerical Simulation and Experiment, J. Therm. Spray Technol., 2023, 32, p 2187-2201.
Y.-S. Lee, M. Niinomi, M. Nakai, K. Narita, and K. Cho, Predominant Factor Determining Wear Properties of β-type and (α+β)-type Titanium Alloys in Metal-to-Metal Contact for Biomedical Applications, J. Mech. Behav. Biomed. Mater., 2015, 41, p 208-220.
M. Fellah, N. Hezil, M. Touhami, M. AbdulSamad, A. Obrosov, D.O. Bokov, E. Marchenko, A. Montagne, A. Iost, and A. Alhussein, Structural, Tribological and Antibacterial Properties of (α + β) Based ti-Alloys for Biomedical Applications, J Mater Res Technol, 2020, 9, p 14061-14074.
V.N.V. Mungala and R.R. Chromik, The Role of Metal Powder Properties on the Tribology of Cold Spray Ti6Al4V-TiC Metal Matrix Composites, Surf. Coat. Technol., 2021, 411, 126974.
K. Kato, Wear in Relation to Friction: A Review, Wear, 2000, 241, p 151-157.
Acknowledgment
The authors would like to thank Drs. Jorg Oberste-Berghaus and Maniya Aghasibeig, Rakesh Bhaskaran Nair Saraswathy and Fadhel Ben-Ettouil for their help in conducting this research.
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Khamsepour, P., Stoyanov, P., Dolatabad, A. et al. Microstructure and Tribological Behavior of Low-Temperature HVAF Ti6Al4V Coatings. J Therm Spray Tech (2024). https://doi.org/10.1007/s11666-024-01800-9
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DOI: https://doi.org/10.1007/s11666-024-01800-9