Abstract
In order to study the effect of magnetron sputtering Al coating on the performance of micro-arc oxidation film, a layer of pure aluminum coating was first sputtered on the surface of TC4 titanium alloy, and then, a composite ceramic oxide film was prepared on the surface of TC4 titanium alloy using micro-arc oxidation (MAO) technology to improve the performance of the material and analyze its wear mechanism. The effects of magnetron sputtered Al coatings on the phase composition, surface morphology, elemental content and wear resistance of the micro-arc oxide composite film layers were characterized using a variety of assays. The results showed that new diffraction peaks of α- Al2O3 and γ-Al2O3 phases appeared in the Al-MAO composite film layer. The hardness of the MAO film layer increased by 30% after magnetron sputtering Al coating, the thickness increased by 61%, the roughness Ra and Rz decreased by 77% and 74%, respectively, and the wear resistance improved significantly. The wear mechanisms of MAO film layer are fatigue wear, adhesive wear and abrasive wear, and the wear mechanisms of Al-MAO film layer are abrasive wear and adhesive wear.
Similar content being viewed by others
Data Availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
**ng Z.K., Tang E.J., R. Duan, H.M Yan, Tao X.U. Research on Structure and Properties of Micro-Arc Anodic Oxidation Film on TC4 Titanium Alloy[J/OL]. Materials Protection, 2005[2022–11–07].
I.A. Bataev, D.O. Mul, A.A. Bataev, O.G. Lenivtseva, M.G. Golkovski, Y.S. Lizunkova and R.A. Dostovalov, Structure and Tribological Properties of Steel After Non-Vacuum Electron Beam Cladding of Ti, Mo and Graphite Powders[J], Mater Charact, 2016, 112, p 60–67.
W.U. **angqing and X. Faqin, Study of Microarc Oxidation Technique on Titanium Alloy Surface [J], Mater. Rep., 2005, 19(6), p 3.
B. Feng, J.Y. Chen, S.K. Qi, L. He, J.Z. Zhao and X.D. Zhang, Carbonate Apatite Coating on Titanium Induced Rapidly by Precalcification[J], Biomaterials, 2002, 23(1), p 173–179.
M. Yang, W. Zhang, J. Chen, Y. Li, T. Huang, N. Tang and P. Li, Corrosion and Electrochemical Impedance Properties of Ti6Al4V Alloy and Ti-3Zr-2Sn-3Mo-25Nb Alloy Treated by Micro-arc Oxidation Process[J], Int. J. Electrochem. Sci., 2019, 14(9), p 8699–8708.
F.U., Yin-Hui, L.I., Yuan-Pu, X.T Yang Effects of Pickling as Pretreatment and Heat Treatment as Post-Treatment on Cyanide-Free Gold Electroplating of TC4 Titanium Alloy[J/OL]. Electroplating & Finishing, 2018[2022–11–07].
J. Feng, J. Wang, K. Yang, and J. Rong, Microstructure and Performance of YTaO4 Coating Deposited by Atmospheric Plasma Spraying on TC4 Titanium Alloy Surface[J/OL], Surface Coat. Technol., 2021, 431, p 128004.
S. Guiqin, L. Jie, L. Youming, and W. Shihong, Fretting Wear and The Preventions of TC4 Titanium Alloy [J], J. Bei**g Univ. Aeronaut. Astronaut., 1995, 02, p 5–9.
W.E.I. Zhongshan, W.A.N.G. Min, Z.U.O. Dunwen, L.I.U. Liufa, and D.I.N.G. Wenjiang, Improvement of Fretting Wear Performance of TC4 Alloy by Mo Ion implantation [J], Mech. Sci. Technol. Aerospace Eng., 2005, 06, p 679–681.
Y. Wang, W. Zhao, W. Wu, C. Wang, X. Wu and Q. Xue, Fabricating Bionic Ultraslippery Surface on Titanium Alloys With Excellent Fouling-Resistant Performance[J/OL], ACS Appl. Bio Mater., 2018, 2(1), p 155–162.
X.U, **ao-**g, L.H., Zhu, X.L., Sheng, T.F., Zhang, M. Liu, X.Y. Niu Bioactivity of TC4 Titanium Alloy Surface After Electrochemical Polishing and Anodic oxidation[J/OL]. Mater. Mech. Eng. 2013[2022–11–07].
F. Müller, M. Lessel, S. Grandthyll, K. Jacobs, S. Huefner, S. Gsell, M. Weinl and M. Schreck, Increasing the Wear Resistance by Interstitial Alloying with Boron via Chemical Vapor Deposition[J], Langmuir, 2013, 29(14), p 4543–4550.
M. Yang, W. Zhang, Y. Li, X. Gong, L. Nie, Lu. **gxiang, N. Tang and P. Li, Optimisation of Process Parameters and Characterisation of Composite Ceramic Coating with NaF Additive on Ti-3Zr-2Sn-3Mo-25Nb by Micro-Arc Oxidation[J], Trans. IMF, 2020, 98, p 1–6.
Y. Mei, T. Ning, C. **, H. Tingyu, Y. Honglang, L. Yang, W. Dan and L. Wei, Effect of Current Density on Micro-Arc Oxidation Properties of TC11 Titanium Alloy [J], Rare Metal. Mater. Eng., 2020, 49(02), p 404–411.
M. Yang, W. Zhang, Y. Li, X. Gong, L. Nie, J. Lu, N. Tang and P. Li, Optimisation of Process Parameters and Characterisation of Composite Ceramic Coating with NaF Additive on Ti-3Zr-2Sn-3Mo-25Nb by Micro-Arc Oxidation[J], Trans. Inst. Metal Finish., 2020, 98(6), p 314–319.
M. Yang, J. Wang, L. Liu, N. Tang and H. Zhang, Study of Biocompatibility in Ceramic Coating Doped with NaF on Ti-3Zr-2Sn-3Mo-25Nb by Micro-Arc Oxidation[J], Trans. Inst. Met. Finish., 2021, 99(6), p 306–312.
J. Wang, L. Liu, M. Yang, W. **n, S. Li, W. Zhang and H. Zhang, Modification Effect of Graphene Oxide on Oxidation Coating of Ti-3Zr-2Sn-3Mo-25 Nb Near-β Titanium Alloy, J. Alloys Compds., 2022, 901, p 163561. https://doi.org/10.1016/j.jallcom.2021.163561
Y.M. Wang, B.L. Jiang, L.X. Guo and T.Q. Lei, Tribological Behavior of Microarc Oxidation Coatings Formed on Titanium Alloys Against Steel in Dry and Solid Lubrication Sliding[J], Appl. Surf. Sci., 2006, 252(8), p 2989–2998.
C. Martini, L. Ceschini, F. Tarterini, J.M. Paillard and J.A.P.E.O. Curran, Layers Obtained From Mixed Aluminate–Phosphate Baths on Ti-6AL-4V: Dry Sliding Behaviour and Influence of a PTFE Topcoat[J], Wear, 2010, 269(11), p 747–756.
E. Arslan, Y. Totik, E.E. Demirci and I. Efeoglu, Wear and Adhesion Resistance of Duplex Coatings Deposited on Ti6AL4V Alloy Using MAO and CFUBMS[J], Surf. Coat. Technol., 2013, 214, p 1–7.
M.W. Peretti, Titanium for Non-Aerospace Applications, JOM, 2012, 64(5), p 551–552.
Acknowledgments
The authors are thankful to State Key Laboratory of Long-life High Temperature Materials (Grant Numbers: DTCC28EE200795), Natural Science Foundation of Sichuan Province of China (Grant Numbers: 2022NSFSC0325) and Sichuan Vanadium and Titanium Industry Development Research Center (Grant Numbers: 2019VTCY-Y-03) for support this research.
Author information
Authors and Affiliations
Contributions
Cenyi Wang involved in data analysis and writing, **n Wu and Mei Yang took part in methodology, Yong Wang and Guobin **e involved in formal analysis, **anju Zhang, **gyi Wang and Zhizhong Lv took part in validation.
Corresponding author
Ethics declarations
Conflicts of interests
The authors have no relevant financial or non-financial interests to disclose.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wang, C., Wang, Y., **e, G. et al. Effect of Aluminum by Magnetron Sputtering on the Micro-Arc Oxide Film Layer of Titanium Alloy. J. of Materi Eng and Perform (2024). https://doi.org/10.1007/s11665-024-09541-0
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11665-024-09541-0