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On the Microstructure and Mechanical Properties of Mg-Gd Alloy with Combined Zn and Ca Addition

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Abstract

The effects of combined addition of Zn and Ca to Mg-1Gd alloy (Mg-1Gd-1.5Zn-1Ca wt.%) on its microstructure and mechanical properties were studied. The results showed that the fine and coarse Mg2Ca and Ca2Mg6Zn3 phase particles were formed in the matrix by the combined additions of Zn and Ca. A drastic refinement of dynamic recrystallized grains was observed in the extruded Mg-1Gd-1.5Zn-1Ca alloy sheet. A remarkable yield strength enhancement and minor ductility decrement have been observed, where strength remarkably increases from 73 to 153 MPa along ED and from 119 to 182 MPa along TD and the ductility decreases from 25.1 to 18.8% along ED and from 13.6 to 9.8% along TD. The SEM and TEM analysis showed that the formed high-density fine Mg2Ca and Ca2Mg6Zn3 particles and the co-segregations of Ca and Zn in grain boundaries led to the fine structure and the strength enhancement.

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References:

  1. D. Gu, J. Peng, J. Wang, Z. Liu and F. Pan, Effect of Mn Modification on the Corrosion Susceptibility of Mg-Mn Alloys by Magnesium Scrap, Acta Metall. Sin., 2021, 34(1), p 1–11.

    Article  CAS  Google Scholar 

  2. J. Song, J. She, D. Chen and F. Pan, Latest Research Advances on Magnesium and Magnesium Alloys Worldwide, J. Magn. Alloys, 2020, 8(1), p 1–41.

    Article  CAS  Google Scholar 

  3. Y.Y. Zhou, P.H. Fu, L.M. Peng, D. Wang, Y.X. Wang, B. Hu, M. Liu, K.S. Anil and W.J. Ding, Precipitation Modification in Cast Mg–1Nd–1Ce–Zr alloy by Zn Addition, J. Magn. Alloy, 2019, 7, p 113–123.

    Article  CAS  Google Scholar 

  4. J. Zhao, B. Jiang, Y. Yuan, A. Tang, H. Sheng, T. Yang, G. Huang, D. Zhang and F. Pan, Influence of Zn Addition on the Microstructure, Tensile Properties and Work-Hardening Behavior of Mg-1Gd alloy, Mater. Sci. Eng. A, 2020, 772, 138779.

    Article  CAS  Google Scholar 

  5. L. Li, T. Wang, Y. Wang, C.C. Zhang, H. Lv, H. Lin, W.B. Yu and C.J. Huang, Effects of Ytterbium Addition and Heat Treatment on the Mechanical Properties and Biocorrosion Behaviors of Mg-Zn-Zr alloy, J. Magnes. Alloy., 2020, 8, p 499–507.

    Article  CAS  Google Scholar 

  6. P. Hidalgo-Manrique, J.D. Robson and M.T. Pérez-Prado, Precipitation Strengthening and Reversed Yield Stress Asymmetry in Mg Alloys Containing Rare-Earth Elements: a Quantitative Study, Acta Mater., 2017, 124, p 456–467.

    Article  CAS  Google Scholar 

  7. D. Zhang, Q. Yang, K. Guan, B. Li, N. Wang, P. Qin, B. Jiang, C. Sun, X. Qin, Z. Tian, Z. Cao and J. Meng, A high-Strength Low-Rare-Earth-Alloyed Magnesium Alloy Via Traditional Hot-Extrusion, J. Alloys Compd., 2019, 810, 151967.

    Article  CAS  Google Scholar 

  8. W.T. Sun, X.G. Qiao, M.Y. Zheng, X.J. Zhao, H.W. Chen, N. Gao and M.J. Starink, Achieving Ultra-High Hardness of Nanostructured Mg-8.2Gd-3.2Y-1.0Zn-0.4Zr Alloy Produced by a Combination of High Pressure Torsion and Ageing Treatment, Scripta Mater., 2018, 155, p 21–25. https://doi.org/10.1016/j.scriptamat.2018.06.009

    Article  CAS  Google Scholar 

  9. W.X. Wu, L. **, J. Dong and W.J. Ding, Deformation Behavior and Texture Evolution in an Extruded Mg–1Gd Alloy During Uniaxial Compression, Mater. Sci. Eng., 2014, 593, p 48–54.

    Article  CAS  Google Scholar 

  10. S. Kim, J. Jung, B.S. You and S.H. Park, Microstructure and Texture Variation with Gd Addition in Extruded Magnesium, J. Alloys Compd., 2017, 695, p 344–350.

    Article  CAS  Google Scholar 

  11. J.P. Hadorn, T.T. Sasaki, T. Nakata, T. Ohkubo, S. Kamado and K. Hono, Solute Clustering and Grain Boundary Segregation in Extruded Dilute Mg-Gd Alloys, Scripta Mater., 2014, 93, p 28–31.

    Article  CAS  Google Scholar 

  12. I. Jung, M. Sanjari, J. Kim and S. Yue, Role of RE in the Deformation and Recrystallization of Mg alloy and a New Alloy Design Concept for Mg–RE Alloys, Scripta Mater., 2015, 102, p 1–6.

    Article  CAS  Google Scholar 

  13. J. Zhao, B. Jiang, Y. Yuan, Q. Wang, M. Yuan, A.T. Tang, G. Huang, D. Zhang and F. Pan, Understanding the Enhanced Ductility of Mg-Gd with Ca and Zn Microalloying by Slip Trace Analysis, J. Mater. Sci. Techno., 2021, 95, p 20–28.

    Article  CAS  Google Scholar 

  14. W. Fu, R.H. Wang, H. Xue, J. Kuang, J.Y. Zhang, G. Liu and J. Sun, Effects of Zr Addition on the Multi-Scale Second-Phase Particles and Fracture Behavior for Mg-3Gd-1Zn Alloy, J. Alloy. Comp., 2018, 747, p 197–210.

    Article  CAS  Google Scholar 

  15. X.Y. Fang, D.Q. Yi, J.F. Nie, X.J. Zhang, B. Wang and L.R. **ao, Effect of Zr, Mn and Sc Additions on the Grain Size of Mg–Gd Alloy, J. Alloy. Comp., 2009, 470, p 311–316.

    Article  CAS  Google Scholar 

  16. W. Rong, Y. Zhang, Y. Wu, Y. Chen, T. Tang, L. Peng and D. Li, Fabrication of High Strength Mg-Gd-Zn-Zr alloys via Differential-Thermal Extrusion, Mater. Char., 2017, 131, p 380–387.

    Article  CAS  Google Scholar 

  17. W.T. Sun, X.G. Qiao, M.Y. Zheng, N. Hu, N. Gao and M.J. Starink, Evolution of Long-Period Stacking Ordered Structure and Hardness of Mg-8.2Gd-3.8Y-1.0Zn-0.4Zr Alloy During Processing by High Pressure Torsion, Mater. Sci. Eng.: A, 2018, 738, p 238–252. https://doi.org/10.1016/j.msea.2018.09.063

    Article  CAS  Google Scholar 

  18. T. Xu, Y. Yan, X. Peng, J. Song and F. Pan, Overview of advancement and development trend on magnesium alloy, J. Magnes. Alloy., 2019, 5, p 536–544.

    Article  Google Scholar 

  19. Qi. Wen, K.-K. Deng, J.-Y. Shi, B.-P. Zhang and W. Liang, Effect of Ca Addition on the Microstructure and Tensile Properties of Mg–4.0Zn–2.0Gd Alloys, Mater. Sci. Eng.: A, 2014, 609, p 1–6. https://doi.org/10.1016/j.msea.2014.04.093

    Article  CAS  Google Scholar 

  20. Z.R. Zeng, M.Z. Bian, S.W. Xu, C.H.J. Davies, N. Birbilis and J.F. Nie, Effects of Dilute Additions of Zn and Ca on Ductility of Magnesium Alloy Sheet, Mater. Sci. Eng. A, 2016, 674, p 459–471.

    Article  CAS  Google Scholar 

  21. B. Zhang, Y. Wang, L. Geng and C. Lu, Effects of Calcium on Texture and Mechanical Properties of Hot-Extruded Mg-Zn-Ca Alloys, Mater. Sci. Eng. A, 2012, 539, p 56–60.

    Article  CAS  Google Scholar 

  22. M.M. Hoseini-Athar, R. Mahmudi, R.P. Babu and P. Hedström, Effect of Zn Addition on Dynamic Recrystallization Behavior of Mg-2Gd Alloy During High-Temperature Deformation, J. Alloy. Comp., 2019, 806, p 1200–1206.

    Article  CAS  Google Scholar 

  23. M.M. Hoseini-Athar, R. Mahmudi, R.P. Babu and P. Hedström, Microstructure, Texture, and Strain-Hardening Behavior of Extruded Mg–Gd–Zn Alloys, Mater. Sci. Eng. A, 2020, 772, 138833.

    Article  CAS  Google Scholar 

  24. H.C. Pan, G.W. Qin, M. Xu, H. Fu, Y.P. Ren, F.S. Pan, Z.Y. Gao, C.Y. Zhao, Q.S. Yang, J. She and B. Song, Enhancing Mechanical Properties of Mg-Sn Alloys by Combining Addition of Ca and Zn, Mater. Des., 2015, 83, p 736–744.

    Article  CAS  Google Scholar 

  25. Y. Chai, B. Jiang, J. Song, Bo. Liu, G. Huang, D. Zhang and F. Pan, Effects of Zn and Ca Addition on Microstructure and Mechanical Properties of as-extruded Mg-1.0Sn Alloy Sheet, Mater. Sci. Eng.: A, 2019, 746, p 82–93. https://doi.org/10.1016/j.msea.2019.01.028

    Article  CAS  Google Scholar 

  26. J. Zhao, B. Jiang, Y. Yuan, A. Tang, Q. Wang, T. Yang, G. Huang, D. Zhang and F. Pan, Influence of Ca and Zn Synergistic Alloying on the Microstructure, Tensile Properties and Strain Hardening of Mg-1Gd Alloy, Mater. Sci. Eng. A, 2020, 785, 139344.

    Article  CAS  Google Scholar 

  27. J.D. Robson, D.T. Henry and B. Davis, Particle Effects on Recrystallization in Magnesium–Manganese Alloys: Particle-Stimulated Nucleation, Acta Mater., 2009, 57, p 2739–2747.

    Article  CAS  Google Scholar 

  28. T. Hu, F. Wang, R. Zheng, W. **ao, Y. Li, S. Lyu and C. Ma, Effects of B and Sn Additions on the Microstructure and Mechanical Property of Mg-3Al-1Si Alloy, J. Alloy. Comp., 2019, 796, p 1–8.

    Article  CAS  Google Scholar 

  29. Z.R. Zeng, Y.M. Zhu, S.W. Xu, M.Z. Bian, C.H.J. Davies, N. Birbilis and J.F. Nie, Texture Evolution During Static Recrystallization of Cold-Rolled Magnesium Alloys, Acta Mater., 2016, 105, p 479–494.

    Article  CAS  Google Scholar 

  30. S. Agnew, M. Yoo and C. Tome, Application of Texture Simulation to Understanding Mechanical Behavior of Mg and solid Solution Alloys Containing Li or Y, Acta Mater., 2001, 49(20), p 4277–4289.

    Article  CAS  Google Scholar 

  31. H. Pan, G. Qin, Y. Huang, Y. Ren, X. Sha, X. Han, Z.-Q. Liu, C. Li, X. Wu, H. Chen, C. He, L. Chai, Y. Wang and J.-F. Nie, Development of low-Alloyed and Rare-Earth-Free Magnesium Alloys Having Ultra-High Strength, Acta Mater., 2018, 149, p 350–363.

    Article  CAS  Google Scholar 

  32. H.H. Yu, C.Z. Li, Y.C. **n, A. Chapuis, X.X. Huang and Q. Liu, The Mechanism for the High Dependence of the Hall-Petch Slope for Twinning/Slip on Texture in mg Alloys, Acta Mater., 2017, 128, p 313–326.

    Article  CAS  Google Scholar 

  33. J.F. Nie, Effects of Precipitate Shape and Orientation on Dispersion Strengthening in Magnesium Alloys, Scr. Mater., 2003, 48, p 1009–1015.

    Article  CAS  Google Scholar 

  34. B. Zhang, Y. Wang, L. Geng and C. Lu, Effects of Calcium on Texture and Mechanical Properties of Hot-Extruded Mg–Zn–Ca alloys, Mater. Sci. Eng. A, 2012, 539, p 56–60.

    Article  CAS  Google Scholar 

  35. K.-C. Wu, J.-W. Yeh and S.-Y. Chang, Refined Microstructure and Improved Mechanical Properties of High-Ratio Extruded AZ91−xSn Magnesium Alloy, Mater. Chem. Phys., 2015, 162, p 757–763.

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are grateful for the Hunan Provincial Natural Science Foundation of China (Grant no. 2022JJ40025), the Scientific Research Fund of Hunan Provincial Education Department (Grant no. 21B0726, 21B0712, 21C0653), the National Natural Science Foundation of China (U2037601, U1910213, 51971044 and 52001037), the Natural Science Foundation of Chongqing (Project No. cstc2019jcyj-msxmX0234), and the Chongqing Science and Technology Commission (cstc2019yszx-jcyjX0004).

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Zhao, J., Liu, Y., Jiang, B. et al. On the Microstructure and Mechanical Properties of Mg-Gd Alloy with Combined Zn and Ca Addition. J. of Materi Eng and Perform 32, 7363–7371 (2023). https://doi.org/10.1007/s11665-022-07643-1

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