Abstract
The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements (REE) and trace elements (Sc, Co, V, and Th) concentrations in these sandstones revealed that they likely derived from a single source. The steep light rare earth elements (LREE) and flat, heavy rare earth element (HREE) patterns, negative Eu anomaly, and high ΣREE contents in sandstones suggest its derivation from a suggests that a passive continental margin environment and originated from felsic source rocks. The average concentration of ΣREE is 93.5 ppm, which is lower than that of the average crustal compositions like Upper Continental Crust and Post Archean Australian Shale. The higher proportion of LREE compared to HREE implies that these sandstones were recycled and derived from a distal source. The Th/Co, Th/Sc, La/Sc, La/Co, Eu/Eu* and (La/Lu)cn elemental ratios indicated that these Late Miocene–Pliocene sandstones were derived from felsic rocks located in the marginal region of the Arabian Shield.
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References
Ahmad MZ, Singh P (2020) Implication of weathering and mineral sorting on rare earth element geochemistry of pleistocene–holocene sediments from Cauvery delta, south India. J Earth Syst Sci 129(1):14. https://doi.org/10.1007/s12040-019-1279-2
Al-Rawi Y, Sadik JM (1981) Sedimentology of the Dibdibba clastic formation. Iraqi Geol J 14(1):55–69
Al-Saad H et al (2002) Stratigraphy and sedimentology of the Hofuf formation in the state of Qatar in relation to the tectonic evolution of the East Arabian Block. Neues Jahrb Fur Geol Palaontol Abh 7:426–448. https://doi.org/10.1127/njgpm/2002/2002/426
Allegre C, Michard G (1974) Introduction to geochemistry. D. Reidel Publishing Company, Dordrecht-Holland
AlShuaibi AA, Khalaf FI (2011) Development and lithogenesis of the palustrine and calcrete deposits. J Asian Earth Sci 42:423–439. https://doi.org/10.1016/j.jseaes.2011.05.014
Anderson POD et al (2004) Provenance evolution and chemostratigraphy of a Palaeozoic submarine fan-complex: Tanqua Karoo Basin, South Africa. Mar Pet Geol 21:555–577. https://doi.org/10.1016/j.marpetgeo.2004.01.004
Aqrawi AAM, Goff JC, Horbury AD, Sadooni FN (2010) The Petroleum Geology of Iraq. Scientific Press Ltd., London
Armstrong-Altrin JS (2020) Detrital zircon U–Pb geochronology and geochemistry of the riachuelos and Palma Sola beach sediments, Veracruz State, Gulf of Mexico: a new insight on palaeoenvironment. J Palaeogeogr 9(4):28. https://doi.org/10.1186/s42501-020-00075-9
Armstrong-Altrin JS et al (2021) Microtexture and U–Pb geochronology of detrital zircon grains in the Chachalacas beach, Veracruz State, Gulf of Mexico. Geol J 56(5):2418–2438. https://doi.org/10.1002/gj.3984
Armstrong-Altrin JS et al (2021) Mineralogy and geochemistry of Tecolutla and Coatzacoalcos beach sediments, SW Gulf of Mexico. Appl Geochem. https://doi.org/10.1016/j.apgeochem.2021.105103
Armstrong-Altrin JS et al (2022) Geochemistry of marine sediments adjacent to the Los Tuxtlas Volcanic Complex, Gulf of Mexico: constraints on weathering and provenance. Appl Geochem 141:105321. https://doi.org/10.1016/j.apgeochem.2022.105321
Awadh SM, Al-Ankaz ZS (2016) Inorganic geochemistry and origin of bitumen intruded in Euphrates and Fatha formations in hit area, western Iraq. Iraqi J Sci 57(4A):2478–2489
Awadh SM, Al-Bahadily HA, Al-Ankaz ZS (2018) Interpreting the tectonics of the Abu Jir Fault, Karbala–Najaf Plateau using mineralogical and geophysical data. Bull Geol Min 14(1):47–63
Bhatia MR (1985) Rare earth element geochemistry of Australian paleozoic greywackes and mudrocks: provenance and tectonic control. Sediment Geol 45:97–113. https://doi.org/10.1016/0037-0738(85)90025-9
Bhatia MR, Crook KW (1986) Trace element characteristics of greywackes and tectonic setting discrimination of sedimentary basins. Mineral Petrol 92:181–193. https://doi.org/10.1007/BF00375292
Brown GF, Schmidt DL, Huffman AC (1984) Geology of the Arabian Peninsula shield area of western Saudi Arabia. U.S Geological Survey, Reston
Buday T (1980) The regional geology of Iraq. Stratigraphy and paleogeography. Dar Al-Kutib Publ. House, Mosul
Cui L, Zhao Z, Liu C et al (2017) Behavior of rare earth elements in granitic profiles, eastern tibetan Plateau, China. Acta Geochim 36:552–555. https://doi.org/10.1007/s11631-017-0234-7
Cullers RL (2002) Implications of elemental concentrations for provenance, redox conditions, and metamorphic studies of shales and limestones near Pueblo, CO. USA Chem Geol 191(4):305–327. https://doi.org/10.1016/S0009-2541(02)00133-X
Cullers RL, Podkovyrov VN (2000) Geochemistry of the Mesoproterozoic Lakhanda shales in southeastern Yakutia, Russia: implications for mineralogical and provenance control, and recycling. Precambrian Res 104(1–2):77–93. https://doi.org/10.1016/S0301-9268(00)00090-5
Cullers RL, Basu A, Suttner LJ (1988) Geochemical signature of provenance in sand-size material in soils and stream sediments near the Tobacco Root batholith, Montana, USA. Chem Geol 70(4):335–348. https://doi.org/10.1016/0009-2541(88)90123-4
Fralick PW, Kronberg BI (1997) Geochemical discrimination of clastic sedimentary rock source. Sediment Geol 113(1–2):111–124. https://doi.org/10.1016/S0037-0738(97)00049-3
Gao S, Wedepohl KH (1995) The negative Eu anomaly in Archean sedimentary rocks: implications for decomposition, age, and importance of their granitic sources. Planet Sci Lett 133(1–2):81–94. https://doi.org/10.1016/0012-821X(95)00077-P
Gromet LP, Silver LT (1983) Rare earth element distributions among minerals in a granodiorite and their petrogenetic implications. Geochim Cosmochim Acta 47(5):925–939. https://doi.org/10.1016/0016-7037(83)90158-8
Ingersoll RV, Suczek CA (1979) Petrology and provenance of Neogene sand from Nicobar and Bengal fans. DSDP site 211 and 218. J Sed Petrol 49(4):1217–1228. https://doi.org/10.1306/212F78F1-2B24-11D7-8648000102C1865D
Jahn BM, Condie KC (1995) Evolution of the Kaapvaal Craton as viewed from geochemical and Sm-Nd isotopic analysis of intracratonic pelites. Geochim Cosmochim Acta 59(11):2239–2258. https://doi.org/10.1016/0016-7037(95)00103-7
Jassim SZ, Goff J (2006) Geology of Iraq. Dolin, Prague and Moravian Museum, Brno
Khalil R (2023) Grain-size analysis of middle cretaceous sandstone Reservoirs, the Wasia Formation, Riyadh Province, Saudi Arabia. Sustainability 15(10):7983. https://doi.org/10.3390/su15107983
Madhavaraju J, Löser H et al (2016) Geochemistry of lower cretaceous limestones of the Alisitos formation, Baja California, México: implications for REE source and paleo-redox conditions. J S Am Earth Sci 66:149–165. https://doi.org/10.1016/j.jsames.2015.11.013
McLennan SM (1989) Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In: Lipin BR, Mckay GA (eds) Geochem mineralogy rare earth element, reviews in mineralogy, 169–200. Mineralogical Society of America, Boston, pp 169–200
McLennan SM, Taylor SR (1991) Sedimentary rocks and crustal evolution: tectonic setting and secular trends. J Geol 99(1):1–21
Mehrabi H, Zamanzadeh SM et al (2021) Geochemistry and provenance of the lower-middle pliocene cheleken formation. Iran Acta Geochim 40:787–805. https://doi.org/10.1007/s11631-021-00480-4
Migaszewski ZM, Gałuszka A (2015) The characteristics, occurrence, and geochemical behavior of rare earth elements in the environment: a review. Crit Rev Environ Sci Technol 45(5):429–471. https://doi.org/10.1080/10643389.2013.866622
Nesbitt HW, Markovics G, Price RC (1980) Chemical processes affecting alkalines and alkaline earths during continental weathering. Geochim Cosmochim Acta 44(11):1659–1666. https://doi.org/10.1016/0016-7037(80)90218-5
Ramos-Vázquez MA, Armstrong-Altrin JS (2021) Provenance of sediments from Barra Del Tordo and Tesoro beaches, Tamaulipas State, northwestern Gulf of Mexico. J Palaeogeogr 10(20):1–17. https://doi.org/10.1186/s42501-021-00101-4
Reimink JR, Davies JH, Ielpi A (2021) Global zircon analysis records a gradual rise of continental crust throughout the Neoarchean. Earth Planet Sci Lett 554:116654. https://doi.org/10.1016/j.epsl.2020.116654
Shinjo R, Amuro T et al (2020) Geochemical characteristics of mafic and felsic igneous rocks (1.9–1.75Ga) in the lesser Himalaya: Regional variation and its implications for tectonic setting. Isl Arc 29:e12369. https://doi.org/10.1111/iar.12369
Sinha S, Islam R et al (2007) Geochemistry of Neogene Siwalik mudstones along Punjab re-entrant, India: implications for source-area weathering, provenance and tectonic setting. Curr Sci 92(8):103–1113
Svendsen JB, Hartley NR (2002) Synthetic heavy mineral stratigraphy: applications and limitations. Mar Pet Geol 19(4):389–405. https://doi.org/10.1016/S0264-8172(02)00010-7
Tawfik HA, Salah MK, Maejima W, Armstrong-Altrin JS, Abdel-Hameed A-MT, Ghandour MME (2018) Petrography and geochemistry of the lower miocene moghra sandstones, Qattara Depression, North Western Desert, Egypt. Geol J 53:1938–1953. https://doi.org/10.1002/gj.3025
Taylor SR, McLennan SM (1981) The composition and evolution of the continental crust: rare earth element evidence from sedimentary rocks. Ser A Math Phys Sci 301:381–399. https://doi.org/10.1098/rsta.1981.0119
Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. An examination of the geochemical record preserved in sedimentary rocks. Blackwell Scientific Publication, Oxford University, Oxford
Verma SP, Armstrong-Altrin SJ (2013) New multi-dimensional diagrams for tectonic discrimination of siliciclastic sediments and their application to precambrian basins. Chem Geol 355:117–133. https://doi.org/10.1016/j.chemgeo.2013.07.014
Acknowledgements
The authors express their gratitude to the laboratory staff at ALS Chemex in Sevilla, Spain, for their valuable assistance with the analytical work. The research was conducted partly during the sabbatical period of the last author, John S. Armstrong-Altrin, at Bharathidasan University, which received approval from DGAPA (PASPA), UNAM.
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Awadh, S.M., Al-Ankaz, Z.S., Al-Owaidi, M.R.A. et al. Provenance and depositional setting of the Late Miocene- Pleistocene clastic sediments in the eastern Arabian Peninsula and western Iraq using rare earth elements geochemistry. Acta Geochim 43, 399–410 (2024). https://doi.org/10.1007/s11631-023-00658-y
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DOI: https://doi.org/10.1007/s11631-023-00658-y