Abstract
Purpose
The petroplinthic horizon is a layer of indurated material in which Fe is an important cement, and it pertains to the pedogenetic material called “laterite”. The aim of this paper is to document the evolution of a coastal pedosedimentary sequence that developed in NW Italy during the Quaternary and discuss the genesis of its petroplinthic horizon within the context of environmental changes that should not have been favourable to lateritisation processes.
Materials and methods
The palaeosol profile was described, and the soil horizons were grouped into pedostratigraphic levels. The horizons were characterised using laboratory routine analysis, X-ray diffraction and thin section micromorphology. In addition, a scanning electron microscope examination of the back-scattered images and an elemental analysis were performed on the petroplinthic horizon only.
Results and discussion
The micromorphological evidence and mineralogical analyses suggest a polygenetic origin for the profile that reflects the influence of separate processes acting on distinct parent material under different environmental conditions.
Conclusions
The petroplinthic horizon results from a pedogenetic process that occurs during seasonal fluctuations of the water table, whereas the plinthite has no pedogenetic link with the weathered bedrock. The plinthitisation/ferrugunisation derived from iron enrichment and accumulation from an external upslope source and/or by post-depositional precipitation of “secondary” iron phyllosilicates (e.g. hisingerite) is a result of the dissolution of pre-existing hematite in inherited detrital laterite fragments.
Similar content being viewed by others
References
Achyuthan H, Fedoroff N (2008) Ferricrete in Tamil Nadu, Chennai, South-Eastern India: From Landsape to Micromorphology, Genesi, and Paleoenvironmental Significance. In: Kapur S, Mermut A, Stoops G (eds) New Trends in Soil Micromorphology. Springer-Verlag, Berlin, pp 111–135
Bartolini C, Bidini D, Ferrari GA, Magaldi D (1984) Pedostratigrafia e Morfostratigrafia nello Studio delle Superfici Sommitali Situate fra Serchio e Ombrone Pistoiese. Geogr Fis Din Quat 7:3–9
Benyarku CA, Stoops G (2005) Guidelines for preparation of rock and soil thin section and polished sections. Quaderns DMACS 33, Paperkite Editorial, Departament de Medi Ambient I Ciències del Sòl, Universitat de Lleida
Biancotti A, Motta M (1998) Morfotettonica dell’Altopiano delle Manie e Zone Circostanti (Liguria Occidentale). Suppl Geogr Fis Din Quat I:45–68
Bigham JM, Heckendorn SE, Jaynes WF, Smeck NE (1991) Stability of iron oxides in two soils with contrasting colors. Soil Sci Soc Am J 55:1485–1492
Bond G, Broecker W, Johnsen S, McManus J, Labeyrie L, Jouzel J, Bonani G (1993) Correlations between climate records from North Atlantic sediments and Greenland ice. Nature 365:143–147
Botha GA, Fedoroff N (1995) Palaesols in Late Quaternary colluvium, northern KwaZulu-Natal, South Africa. J Afr Earth Sci 21(2):291–311
Brewer R (1976) Fabric and Mineral Analysis of Soils. Robert E.Krieger Publishing Company, Huntington
Bronger A, Sedov SN (2003) Vetusols and paleosols: natural versus man-induced environmental change in the Atlantic coastal region of Morocco. Quat Int 106–107:33–60
Busacca AJ, Singer MJ (1989) Pedogenesis of a chronosequence in the Sacramento Valley, California, USA. II. Elemental chemistry of silt fractions. Geoderma 44:43–75
Carobene L, Firpo M (1994) Una paleospiaggia tra Voltri e Palmaro (Genova): evidenze sedimentologiche e morfologiche. Quaternario 7(1):123–138
Carobene L, Firpo M (2002) Forme terrazzate relitte di genesi marina lungo la costa ligure tra Genova e Savona (Liguria occidentale). Quaternario 15(1):53–68
Catt JA (1991) Soils as indicators of Quaternary climatic change in mid-latitude regions. Geoderma 51:167–187
Chiesa S, Cortesogno L, Forcella F, Galli M, Messiga B, Pasquare G, Pedemonte GM, Piccardo GB, Rossi PM (1975) Assetto strutturale ed interpretazione geodinamica del Gruppo di Voltri. Boll Soc Geol Ital 94:555–581
Costantini EAC (2007) Linee guida dei metodi di rilevamento e informatizzazione dei dati pedologici. CRA-ABP, Firenze
Costantini EAC, Priori S (2007) Pedogenesis of plinthite during early Pliocene in the Mediterranean environment. Case study of a buried paleosol at Podere Renieri, central Italy. Catena 71:425–443
Costantini EAC, Lessovaia S, Vodyanitskii Y (2006) Using the analysis of iron and iron oxides in paleosols (TEM, geochemistry and iron forms) for the assessment of present and past pedogenesis. Quat Inter 156–157:200–211
Costantini EAC, L'Abate G, Barbetti R, Fantappié M, Lorenzetti R, Magini S (2012) Soil map of Italy. DOI:ISBN: 978-88-97002-02-4
Cremaschi M, Ginesu S (1990) Morfogenesi e Pedogenesi Tardo Terziaria e Pleistocenica Antica nella Nurra Occidentale (Sardegna). Nota Preliminare, Geogr Fis Din Quat 13:81–82
Daniels RB, Perkins HF, Hajek BF, Gamble EE (1978) Morphology of discontinuous phase plinthite and criteria for its field identification in the southeastern United States. Soil Sci Soc Am J 42:944–949
Delvigne JE (1998) Atlas of Micromorphology of Mineral Alteration and Weathering. The Canadian Mineralogist, Special Publication 3
Dos Anjos LHC, Franzmeier DP, Schulze DG (1995) Formation of soils with plinthite on a toposequence in Maranh o State, Brazil. Geoderma 64:257–279
Douka K, Grimaldi S, Boschian G, del Lucchese A, Higham TFG (2012) A new chronostratigraphic framework for the Upper Palaeolithic of Riparo Mochi (Italy). J Hum Evol 62:286–299
Duchaufour P (1977) Précis de Pédologie. Masson, Paris
Dumas JBA (1831) Procédés de l'analysc organique. Ann Chim Phys 247:198–213
Eggleton RA, Tilley DB (1998) Hisingerite: a ferric kaolin mineral with curved morphology. Clay Clay Miner 46(4):400–413
Eswaran H, Sys C, Sousa EC (1975) Plasma infusions—a pedological process of significance in the humid tropics. Edafol Agrobiol 34:665–674
FAO, Food and Agricultural Organization of the United Nations (2006) World Reference Base for Soil Resources 2006, 2nd edition. Rome, Italy
Fedoroff N (1991) Possibilities of palaeopedology for palaeoenvironmental reconstructions. In: Special Proceedings Symposia of the XIII INQUA Congress, Review report, Bei**g, China, pp 117-120
Fedoroff N (1997) Clay illuviation in Red Mediterranean soils. Catena 28:171–189
Fedoroff N, Eswaran H (1985) Micromorphology of ultisols. In: Douglas LA, Thompson ML (eds) Soil Micromorphology and Soil Classification. SSSA Special Publication, Number 15, Madison
Fedoroff N, Courty MA, Guo Z (2010) Palaesoils and relict soils. In: Stoops G, Marcellino V, Florias M (eds) Interpretation of micromorphological features of soils and regoliths. Elsevier, Amsterdam, pp 623–662
Fedoroff N, Courty MA, Thompson ML (1990) Micromorphological evidence of paleoenvironmental change in Pleistocene and Holocene paleosols. In: Douglas LA (ed) Soil Micromorphology: a Basic and Applied Science. Elsevier, Amsterdam, p 653–665
Fernández-Caliani J, Cantano M (2010) Intensive kaolinization during a lateritic weathering event in southwest Spain mineralogical and geochemical inferences from a relict paleosol. Catena 80:23–33
MiPAF (Ministero delle Politiche Agricole e Forestali) (2000) Osservatorio nazionale pedologico e per la qualità del suolo, International Society of Soil Science, Società Italiana della Scienza del Suolo. Metodi di analisi chimica del suolo. F. Angeli (ed), Milano
Gelati R, Gnaccolini M (1996) The stratigraphic record of the Oligocene-Early Miocene events at the south-western end of the Piedmont Tertiary Basin. Riv Ital Paleontol Stratigr 102(1):65–76
Gelati R, Gnaccolini M (2003) Genesis and evolution of the Langhe basin, with emphasis on the latest Oligocene-earliest Miocene and Serravallian. Atti Ticinensi Sci Terra 44:3–18
Gianmarino S, Tedeschi D (1983) Considerazioni geologico-stratigrafiche nel Pliocene di Albissola (Savona). Atti Soc Toscana Sci Nat Mem Ser A 90:211–216
Ingles OG, Willoughby DR (1967) An occurance of hisingerite with evidence of its genesis. Soil Sci 104(5):383–385
Kennett DJ, Kennett JP, West GJ, Erlandson JM, Johnson JR, Hendy IL, West A, Culleton BJ, JonesThomas TL, Stafford W Jr (2008) Wildfire and abrupt ecosystem disruption on California’s Northern Channel Islands at the Ållerød–Younger Dryas boundary (13.0–12.9 ka). Quat Sci Rev 27:2528–2543
Köppen W (1936) Das geographische system der climate. In: Köppen and Geiger (eds) Handbuch der Klimatologie, Vol I, Part C. Gebrüder Borntraeger, Berlin, p 44
Kovda I, Mermut AR (2010) Vertic features. In: Stoops G, Marcellino V, Florias M (eds) Interpretation of micromorphological features of soils and regoliths. Elsevier, Amsterdam, pp 109–127
Kubiena WL (1970) Micromorphological features of soil geography. Rutgers University Press, New Brunswick
Lambeck K, Yokoyama Y, Purcella T (2002) Into and out of the Last Glacial Maximum: sea-level change during oxygen isotope stages 3 and 2. Quat Sci Rev 21:343–360
Lisiecki LE, Raymo ME (2005) A Pliocene-Pleistocene stack of 57 globally distributed benthic d18O records. Paleoceanogr 20. doi:10.1029/2004PA001071
Magaldi D, Bidini D (1991) Microscopic and submicroscopic characterization of a well developed plinthite in a buried middle pleistocene soil in Northern Tuscany (Italy). Quad Scienza del Suolo III:31-44
McKeague JA (1983) Clay skins in argillic horizon. In: Bullock P, Murphy CP (eds) Soil Micromorphology. Soil Genesis vol. 2. A.B.. Academic Publishers, Berkhamsted, U.K., pp 367-388
Miedema R, Slager S (1972) Micromorphological quantification of clay illuviation. J Soil Sci 23:309–314
Migoń P, Lidmar-Bergström K (2002) Deep weathering through time in central and northwestern Europe: problems of dating and interpretation of geological record. Catena 49:25–40
Murphy CP (1983) Point counting pores and illuvial clay in thin sections. Geoderma 31:133–150
Murphy CP, Kemp RA (1984) The over-estimation of clay and the under-estimation of pores in soil thin sections. J Soil Sci 35:481–495
Nahon DB (1991) Introduction to the petrology of soils and chemical weathering. John Wiley & Sons, Inc., New York
Olsen S R, Cole CV, Watanabe FS, Dean LA (1954) Estimation of available phosphorus in soils by extraction with sodium bicarbonate. USDA circular 939, U.S. Gov. Print. Office, Washington, DC
Osher LJ, Buol SW (1998) Relationship of soil properties to parent material and landscape position in eastern Madre de Dios, Peru. Geoderma 83:143–166
Rellini I, Trombino L, Firpo M, Piccazzo M (2007) Geomorphological context of “plinthitic paleosols” in the mediterranean region: examples from the coast of western Liguria (Northern Italy). Rev Cuaternario Geomorfologia 21(1–2):27–40
Rellini I, Firpo M, Martino G, Riel-Salvatore J, Maggi R (2013) Climate and environmental changes recognized by micromorphology in Paleolithic deposits at Arene Candide (Liguria, Italy). Quat Inter 315:42–55
Robert M, Tessier D (1974) Methodes de preparation des argiles des sols pour des etudes mineralogiques. Ann Agron 25:859–880
Schwertmann U, Taylor RM (1989) Iron oxides. In: Dixon JB, Weed SB (eds) Minerals in Soil Environments, 2nd edn. Soil Sci Soc Am, Madison, pp 379–438
Simon M, Sanchez S, Garcia I (2000) Soil-landscape evolution on a Mediterranean high mountain. Catena 39:211–231
Soil Survey Staff (2010) Keys to Soil Taxonomy, 11th edn. US Department of Agriculture, Soil Survey Staff, Natural Resources Conservation Service, Washington
Sombroek WG (1971) Ancient levels of plinthisation in N.W. Nigeria. In: Yaalon DH (ed) Paleopedology. International Society of Soil Science and Israel University Press, Jerusalem, pp 329–336
Stoops G (1989) Relict properties in soils of humid tropical regions with special reference to Central Africa. In: Bronger A, Catt JA (eds) Paleopedology, vol 16, Nature and Application of Paleosols, Catena Supplement., pp 95–106
Stoops G (2001) Micropedology: Methods and Applications. International Training Centre for Post-Graduate Soil. Universiteit Gent, Scientists
Stoops G (2003) Guidelines for Analysis and Description of Soil and Regolith Thin Section. Soil Science Society of America Inc, Madison
Stoops G, Marcellino V (2010) Lateritic and Bauxitic Material. In: Stoops G, Marcellino V, Florias M (eds) Interpretation of micromorphological features of soils and regoliths. Elsevier, Amsterdam, pp 329–350
Stoops G, Marcellino V, Florias M (2010) Interpretation of micromorphological features of soils and regoliths. Elsevier, Amsterdam
Tardy Y (1993) Pétrologie des laterites et des sols tropicaux. Masson, Paris
Tardy Y, Boeglin JL, Novikoff A, Roquin C (1995) Petrological and geochemical classification of laterites. In: Churchman GJ, Fitzpatrick RW, Eggleton RA (eds) Clays controlling the environment. CSIRO, Melbourne, pp 481–486
Torrent J, Schwertmann U, Schulze DJ (1980) Iron oxide mineralogy of some soils of two river terrace sequences in Spain. Geoderma 23:191–208
Trombino L (1996) Lateriti nelle Regioni Mediterranee: Studio Micromorfologico del Paleosuolo dell’Altopiano delle Mànie (Finale Ligure). Atti Ticinensi di Scienze della Terra, Serie Speciale 4:65–76
Van Ranst E, Utami SR, Vanderdeelen J, Shamshuddin J (2004) Surface reactivity of Andisols on volcanic ash along the Sunda arc crossing Java Island, Indonesia. Geoderma 123:193–203
Van Vliet-Lanoë B (1998) Frost and soils: implications for paleosols, paleoclimates and stratigraphy. Catena 34:157–183
Vanossi M, Cortesogno L, Galbiati B, Messiga B, Piccardo G, Vannucci R (1984) Geologia delle Alpi Liguri: dati, problemi, ipotesi. Mem Soc Geol Ital 28:5–75
Wang Y (2003) Coastal laterite profiles at Po Chue Tam, Lantau Island, Hong Kong: the origin and implication. Geomorphology 52:335–346
Wood BW, Perkins HF (1976) A field method for verifying plinthite in Southern Coastal Plain soils. Soil Sci 122:240–241
Yaalon DH (1997) Soil in Mediterranean region: what makes them different? Catena 28:233–251
Zazo C, Goy JL, Dabrio CJ, Bardají T, Hillaire-Marcel C, Ghaleb B, González-Delgado JA, Sole V (2003) Pleistocene raised marine terraces of the Spanish Mediterranean and Atlantic coasts: records of coastal uplift, sea-level highstands and climate changes. Mar Geol 194(1-2):103–133
Acknowledgments
The authors are grateful to Georges Stoops for the very interesting discussions and his suggestions and valuable help during the micromorphological study at “Laboratorium voor Mineralogie, Petrologie en Micropedologie” of Ghent University. We also greatly appreciate the support of Lorenzo Rellini.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Markus Egli
Rights and permissions
About this article
Cite this article
Rellini, I., Trombino, L., Carbone, C. et al. Petroplinthite formation in a pedosedimentary sequence along a northern Mediterranean coast: from micromorphology to landscape evolution. J Soils Sediments 15, 1311–1328 (2015). https://doi.org/10.1007/s11368-014-0896-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11368-014-0896-2