Abstract
The water level fluctuation zone (WLFZ) of the Three Gorges Reservoir (TGR) acts as an important sink for inflowing suspended sediment loads over the inundation periods following regular dam operations. This study depicts the sedimentary geochemical dynamics along a sedimentary profile based on the determined chronology and explores its links to the specific hydrological regime created by dam flow regulation and riverine seasonal suspended sediment dynamics. A compact 345-cm-long sediment core was extracted near the base water level (145.3 m) from the WLFZ of the TGR and sectioned at 5-cm intervals. Extracted sediment subsamples were analyzed for grain size composition, organic matter (OM), total nitrogen (TN), and geochemical elements (Na, K, Ca, Mg, Pb, Zn, Ni, Co, Mn, Cr, Fe, and Cu). The sediment core chronology was determined using 137Cs elemental analysis. Sedimentary geochemistry and grain size properties of extracted sediment core exhibited greater variations during initial submergence years till the first complete impoundment of the TGR (2006–2010). Afterward (2011–2013), although upstream inflowing suspended sediments and reservoir water level were comparable, sediment deposition and concentrations of sedimentary geochemical constituents showed considerably fewer variations. Seasonal variations in sediment deposition and geochemical composition were also observed during the rainy (October–April) and dry (May–September) seasons, in addition to annual variations. Grain size, OM, and other sediment geochemical constituents all had significant correlations with each other and with sediment core depth. The concentrations of geochemical elements in various sediment stratigraphic layers exhibited staggering associations with each other and were dependent on each other in several ways. The arrangement of geochemical elements in various stratigraphic layers of the extracted core illustrated amalgamation with inputs from upstream seasonal suspended sediment dynamics and reservoir water levels. During shortened submergence periods and higher input sediment loads, geochemical elements demonstrated impulsive distributions. Alternatively, during longer submergence periods, elemental distributions were relatively uniform attributed to higher settling time to deposit according to grain size and geochemical affinities. Higher suspended sediment loads in association with seasonal floods also resulted in rough sediment deposition patterns, imparting variations in the distributions of geochemical elements. Interim mediations in geochemical element concentrations are associated with seasonal distal flash floods and local terrace bank collapses, which generate significant amounts of distal sediment loads that are quickly deposited and are not sorted hydrodynamically. Overall, although a specific mechanism was devised to circumvent the siltation process, a considerable amount of sediment is trapped at pre-dam sites. In addition, siltation caused nutrients and geochemical elements’ enrichment.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-022-25086-y/MediaObjects/11356_2022_25086_Fig9_HTML.png)
Similar content being viewed by others
Availability of data and materials
The authors confirm that the data supporting the findings of this study are available within the article.
References
Alagarsamy R, Zhang J (2005) Comparative studies on trace metal geochemistry in Indian and Chinese rivers. Curr Sci 89:299–309
Anderson FE (1972) Resuspension of estuarine sediments by small amplitude waves. J Sediment Res 42(3)
Annandale GW (2006) Reservoir sedimentation, Encyclopedia of Hydrological Sciences
Appleby P, Oldfieldz F (1983) The assessment of 210 Pb data from sites with varying sediment accumulation rates. Hydrobiologia 103(1):29–35
Bao Y, Gao P, He X (2015) The water-level fluctuation zone of Three Gorges Reservoir—a unique geomorphological unit. Earth-Sci Rev 150:14–24
Barbosa RI, Fearnside PM (1996) Carbon and nutrient flows in an Amazonian forest: fine litter production and composition at Apiaú, Roraima. Brazil Trop Ecol 37(1):115–125
Bjørlykke K (2015) Sedimentary geochemistry, petroleum geoscience. Springer, Berlin, Heidelberg, pp 87–111
Bouchez J, Gaillardet J, France‐Lanord C, Maurice L, Dutra‐Maia P (2011) Grain size control of river suspended sediment geochemistry: clues from Amazon River depth profiles. Geochem Geophys 12(3)
Chamley H (2013) Clay sedimentology. Springer, Berlin, Heidelberg, p 623
Chen X, Yan Y, Fu R, Dou X, Zhang E (2008) Sediment transport from the Yangtze River, China, into the sea over the Post-Three Gorge Dam Period: a discussion. Quat Int 186(1):55–64
Chen Z, Wang Z, Finlayson B, Chen J, Yin D (2010) Implications of flow control by the Three Gorges Dam on sediment and channel dynamics of the middle Yangtze (Changjiang) River. China Geology 38(11):1043–1046
Chetelat B, Liu C-Q, Zhao Z, Wang Q, Li S, Li J, Wang B (2008) Geochemistry of the dissolved load of the Changjiang Basin rivers: anthropogenic impacts and chemical weathering. Geochim Cosmochim Acta 72(17):4254–4277
Cojean R, Caï YJ (2011) Analysis and modeling of slope stability in the Three-Gorges Dam reservoir (China)—The case of Huangtupo landslide. J Mt Sci 8(2):166
Cotton F, Wilkinson G, Murillo C, Bochmann M (1999) Advanced inorganic chemistry. Wiley-Interscience, New York, p 1376
Cox S, Willig M, Scatena F (2002) Variation in nutrient characteristics of surface soils from the Luquillo Experimental Forest of Puerto Rico: a multivariate perspective. Plant Soil 247(2):189–198
Dupré B, Gaillardet J, Rousseau D, Allègre CJ (1996) Major and trace elements of river-borne material: the Congo Basin. Geochim Cosmochim Acta 60(8):1301–1321
Finney BP, Lyle MW, Heath GR (1988) Sedimentation at MANOP Site H (eastern equatorial Pacific) over the past 400,000 years: climatically induced redox variations and their effects on transition metal cycling. Paleoceanography 3(2):169–189
Francois R (1987) Some aspects of the geochemistry of sulphur and iodine in marine humic substances and transition metal enrichment in anoxic sediments, University of British Columbia, 462 pp
Fu B-J, Wu B-F, Lü Y-H, Xu Z-H, Cao J-H, Niu D, Yang G-S, Zhou Y-M (2010) Three Gorges Project: efforts and challenges for the environment. Prog Phys Geogr 34(6):741–754
Gagnon C, Arnac M, Brindle J-R (1992) Sorption interactions between trace metals (Cd and Ni) and phenolic substances on suspended clay minerals. Water Res 26(8):1067–1072
Gao Y, Zhu B, Zhou P, Tang J-L, Wang T, Miao C-Y (2009) Effects of vegetation cover on phosphorus loss from a hillslope cropland of purple soil under simulated rainfall: a case study in China. Nutr Cycl Agroecosystems 85(3):263–273
Gleick PH (2009) Three Gorges Dam Project, Yangtze River, China, The World's Water 2008–2009: the biennial report on freshwater resources. Island Press Washington DC, pp. 139–150
Graybeal AL, Heath GR (1984) Remobilization of transition metals in surficial pelagic sediments from the eastern Pacific. Geochim Cosmochim Acta 48(5):965–975
Hara T, Sonoda Y (1979) Comparison of the toxicity of heavy metals to cabbage growth. Plant Soil 51(1):127–133
Heier KS, Adams JA (1964) The geochemistry of the alkali metals. Phys Chem Earth 5:253–381
Ingri J, Widerlund A (1994) Uptake of alkali and alkaline-earth elements on suspended iron and manganese in the Kalix River, northern Sweden. Geochim Cosmochim Acta 58(24):5433–5442
James LA, Marcus WA (2006) The human role in changing fluvial systems: retrospect, inventory and prospect. Geomorphology 79(3–4):152–171
Javed M, Usmani N (2012) Toxic effects of heavy metals (Cu, Ni, Fe Co, Mn, Cr, Zn) to the haematology of Mastacembelus armatus thriving in Harduaganj Reservoir, Aligarh. India Glob J Med Res 12(8):59–64
Javed M, Usmani N (2013) Assessment of heavy metal (Cu, Ni, Fe Co, Mn, Cr, Zn) pollution in effluent dominated rivulet water and their effect on glycogen metabolism and histology of Mastacembelus armatus. Springerplus 2(1):390
Jehlicka J (2009) Sedimentary geochemistry, geophysics and geochemistry. Eolss Publishers Co Ltd, Oxford, p 21
Jenner G, Longerich H, Jackson S, Fryer B (1990) ICP-MS—A powerful tool for high-precision trace-element analysis in Earth sciences: evidence from analysis of selected USGS reference samples. Chem Geol 83(1–2):133–148
Jensen WB (2003) The place of zinc, cadmium, and mercury in the periodic table. J Chem Educ 80(8):952
Kamala-Kannan S, PrabhuDassBatvari B, Lee KJ, Kannan N, Krishnamoorthy R, Shanthi K, Jayaprakash M (2008) Assessment of heavy metals (Cd, Cr and Pb) in water, sediment and seaweed (Ulva lactuca) in the Pulicat Lake, South East India. Chemosphere 71(7):1233–40
Kaplan I, Rittenberg S (1963) Basin sedimentation and diagenesis, The Sea, Volume 3: The Earth Beneath the Sea; History. John Wiley, New York, pp. 583–619
Kemp A (1971) Organic carbon and nitrogen in the surface sediments of Lakes Ontario. Erie and Huron J Sediment Res 41(2):537–548
Kim G, Yang H-S, Church TM (1999) Geochemistry of alkaline earth elements (Mg, Ca, Sr, Ba) in the surface sediments of the Yellow Sea. Chem Geol 153(1–4):1–10
Li Q, Yu M, Lu G, Cai T, Bai X, **a Z (2011) Impacts of the Gezhouba and Three Gorges reservoirs on the sediment regime in the Yangtze River. China J Hydrol 403(3–4):224–233
Li D, Yao P, Bianchi TS, Zhang T, Zhao B, Pan H, Wang J, Yu Z (2014a) Organic carbon cycling in sediments of the Changjiang Estuary and adjacent shelf: Implication for the influence of Three Gorges Dam. J Mar Syst 139:409–419
Li Z, Zhang Z, **ao Y, Guo J, Wu S, Liu J (2014b) Spatio-temporal variations of carbon dioxide and its gross emission regulated by artificial operation in a typical hydropower reservoir in China. Environ Monit Assess 186(5):3023–3039
Li Z, Lu L, Guo J, Yang J, Zhang J, He B, Xu L (2017) Responses of spatial-temporal dynamics of bacterioplankton community to large-scale reservoir operation: a case study in the Three Gorges Reservoir. China Sci Rep 7:42469
Liu P, Li L, Guo S, **ong L, Zhang W, Zhang J, Xu C-Y (2015) Optimal design of seasonal flood limited water levels and its application for the Three Gorges Reservoir. J Hydrol 527:1045–1053
Liu G, **ao H, Liu P, Zhang Q, Zhang J (2016) Using rare earth elements to monitor sediment sources from a miniature model of a small watershed in the Three Gorges area of China. CATENA 143:114–122
Looi LJ, Aris AZ, Yusoff FM, Isa NM, Haris H (2019) Application of enrichment factor, geoaccumulation index, and ecological risk index in assessing the elemental pollution status of surface sediments. Environ Geochem Health 41(1):27–42
Ludwig W, Probst JL, Kempe S (1996) Predicting the oceanic input of organic carbon by continental erosion. Global Biogeochem Cycles 10(1):23–41
Manahan SE (1993) Fundamentals of Environmental Chemistry. CRC Press, 864 pp
Martin J, Meybeck M (1979) Elemental mass-balance of material carried by major world rivers. Mar Chem 7(3):173–206
McLaughlin R (1955) Geochemical changes due to weathering under varying climatic conditions. Geochim Cosmochim Acta 8(3):109–130
Middelburg JJ (1989) A simple rate model for organic matter decomposition in marine sediments. Geochim Cosmochim Acta 53(7):1577–1581
Milliman JD, Farnsworth KL, Jones PD, Xu KH, Smith LC (2008) Climatic and anthropogenic factors affecting river discharge to the global ocean, 1951–2000. Glob Planet Change 62(3–4):187–194
Mudholkar A, Pattan J, Parthiban G (1993) Geochemistry of deep-sea sediment cores from the Central Indian Ocean Basin. Indian J Mar Sci 22(4):241–246
Nesbitt H, Young GM (1989) Formation and diagenesis of weathering profiles. J Geol 97(2):129–147
New T, **e Z (2008) Impacts of large dams on riparian vegetation: applying global experience to the case of China’s Three Gorges Dam. Biodivers Conserv 17(13):3149–3163
Nilsson C, Reidy CA, Dynesius M, Revenga C (2005) Fragmentation and flow regulation of the world’s large river systems. Science 308(5720):405–408
Nissenbaum A, Swaine DJ (1976) Organic matter-metal interactions in recent sediments: the role of humic substances. Geochim Cosmochim Acta 40(7):809–816
Obunwo C, Abia A, Iboroma D (2014) Studies of sedimentation rates of nontransition alkaline-earth metal carbonates in aqueous medium. IOSR J Appl Chem 7(11):06–11
Petts GE, Gurnell AM (2005) Dams and geomorphology: research progress and future directions. Geomorphology 71(1–2):27–47
Prusty BAK, Chandra R, Azeez P (2009) Temporal variation and distribution of selected alkali and alkaline earth metals in the sediment of a monsoonal wetland in India. Fresenius Environ Bull 18(6):917–927
Pulley S, Foster I, Antunes P (2015) The uncertainties associated with sediment fingerprinting suspended and recently deposited fluvial sediment in the Nene river basin. Geomorphology 228:303–319
Rapaglia J, Zaggia L, Ricklefs K, Gelinas M, Bokuniewicz H (2011) Characteristics of ships’ depression waves and associated sediment resuspension in Venice Lagoon. Italy J Mar Syst 85(1–2):45–56
Sarma NS, Rao MU (1999) Alkali and alkaline earth metals in surface sediments off Bhimunipatnam-Amalapuram, central east coast of India (Bay of Bengal). Indian J Mar Sci 28(4):375–379
Schönbrodt-Stitt S, Behrens T, Schmidt K, Shi X, Scholten T (2013) Degradation of cultivated bench terraces in the Three Gorges Area: Field map** and data mining. Ecol Indic 34:478–493
Syvitski JP (2003) Supply and flux of sediment along hydrological pathways: research for the 21st century. Glob Planet Change 39(1–2):1–11
Syvitski JPM, Vorosmarty CJ, Kettner AJ, Green P (2005) Impact of humans on the flux of terrestrial sediment to the global coastal ocean. Science 308(5720):376–380
Tang Q, Bao YH, He XB, Zhou HD, Cao ZJ, Gao P, Zhong RH, Hu YH, Zhang XB (2014) Sedimentation and associated trace metal enrichment in the riparian zone of the Three Gorges Reservoir. China Sci Total Environ 479–480:258–266
Tang Q, Bao Y, He X, Fu B, Collins AL, Zhang X (2016) Flow regulation manipulates contemporary seasonal sedimentary dynamics in the reservoir fluctuation zone of the Three Gorges Reservoir. China Sci Total Environ 548–549:410–420
Tang Q, Collins AL, Wen A, He X, Bao Y, Yan D, Long Y, Zhang Y (2018) Particle size differentiation explains flow regulation controls on sediment sorting in the water-level fluctuation zone of the Three Gorges Reservoir. China Sci Total Environ 633:1114–1125
Thomas R (1969) A note on the relationship of grain size, clay content, quartz and organic carbon in some Lake Erie and Lake Ontario sediments. J Sediment Res 39(2):803–809
Trask PD, Patnode HW (1942) Source beds of petroleum. American Association of Petroleum Geologists, Tulsa
Vaithiyanathan P, Ramanathan A, Subramanian V (1993) Transport and distribution of heavy metals in Cauvery River. Water Air Soil Pollut 71(1–2):13–28
Velde B (2013) Origin and mineralogy of clays: clays and the environment. Springer Science & Business Media, Berlin, Heidelberg, 335 pp
Viers J, Dupré B, Gaillardet J (2009) Chemical composition of suspended sediments in World Rivers: New insights from a new database. Sci Total Environ 407(2):853–868
Vorosmarty CJ, Sahagian D (2000) Anthropogenic disturbance of the terrestrial water cycle. Bioscience 50(9):753–765
Vorosmarty CJ, Green P, Salisbury J, Lammers RB (2000) Global water resources: vulnerability from climate change and population growth. Science 289(5477):284–288
Vörösmarty CJ, Meybeck M, Fekete B, Sharma K, Green P, Syvitski JP (2003) Anthropogenic sediment retention: major global impact from registered river impoundments. Glob Planet Change 39(1–2):169–190
Walling DE (2006) Human impact on land–ocean sediment transfer by the world’s rivers. Geomorphology 79(3–4):192–216
Walling DE, Fang D (2003) Recent trends in the suspended sediment loads of the world’s rivers. Glob Planet Change 39(1–2):111–126
Wei WH, **g Z (1990) Effect of particle size on transition metal concentrations in the Changjiang (Yangtze River) and the Huanghe (Yellow River). China Sci Total Environ 94(3):187–207
Welby C (1958) Occurrence of alkali metals in some Gulf of Mexico sediments. J Sediment Petrol 28(4):431–452
Wu J, Huang J, Han X, Gao X, He F, Jiang M, Jiang Z, Primack RB, Shen Z (2004) The three gorges dam: an ecological perspective. Front Ecol Environ 2(5):241–248
Yang S, Milliman J, Xu K, Deng B, Zhang X, Luo X (2014) Downstream sedimentary and geomorphic impacts of the Three Gorges Dam on the Yangtze River. Earth Sci Rev 138:469–486
Yang Z-S, Wang H-J, Saito Y, Milliman J, Xu K, Qiao S, Shi G (2006) Dam impacts on the Changjiang (Yangtze) River sediment discharge to the sea: the past 55 years and after the Three Gorges Dam. Water Resour Res 42(4)
Yap C, Edward F, Emila R, Ainey F, Ismail A, Tan S, Sharizat Y (2008) Determination of contamination and bioavailabilities of heavy metals (Cu, Cd, Zn, Pb and Ni) in the Serdang Urban Lake by using guppy fish Poecilia reticulata. Trends App Sci Res 3:69–75
Ye BS, Yang DQ, Kane DL (2003) Changes in Lena River streamflow hydrology: Human impacts versus natural variations. Water Resour Res 39(7):1200
Yuan X-Z, Zhang Y-W, Liu H, **ong S, Li B, Deng W (2013) The littoral zone in the Three Gorges Reservoir, China: challenges and opportunities. Environ Sci Pollut Res 20(10):7092–7102
Yun-Liang S, Wu Y, Mei-e R (1985) Hydrological characteristics of the Changjiang and its relation to sediment transport to the sea. Cont Shelf Res 4(1–2):5–15
Zhang Q, Lou Z (2011) The environmental changes and mitigation actions in the Three Gorges Reservoir region. China Environ Sci Policy 14(8):1132–1138
Zhang C, Wang L (2001) Multi-element geochemistry of sediments from the Pearl River system. China Appl Geochem 16(9–10):1251–1259
Zheng J, Yang D (2016) Hub-and-spoke network design for container ship** along the Yangtze River. J Transp Geogr 55:51–57
Zhong Z, Qi D (2008) The illustrated species catalog and biodiversity in the hydro-fluctuation belt of Three Gorges Reservoir (in Chinese) San **a ku qu xiao luo dai sheng wu duo yang xing yu tu pu, 10. Southwest China Normal University Press, Chongqing, p 359
Zhu Y, Lu X, Yang L, Wang L (2016) Accumulation and source of heavy metals in sediment of a reservoir near an industrial park of northwest China. Front Earth Sci 10(4):707–716
Funding
This work was supported by the National Natural Science Foundation of China (U2040207, 41977075), Science Fund for Distinguished Young Scholars of Chongqing (cstc2021jcyj-jqX0026), Fundamental Research Funds for the Central Universities (SWU020013), and the Sichuan Science and Technology Program (2020YJ0202, 2020YFQ0002).
Author information
Authors and Affiliations
Contributions
YB, QT, and XH designed and conceptualized the research, acquired the funding, and supervised the project. QT, DK, JL, JD, and GN analyzed the data. QT drafted the initial manuscript structure and DK wrote the original manuscript. QT, XH, and TB revised and approved the final manuscript. All authors read and approved the manuscript.
Corresponding author
Ethics declarations
Ethical approval
This article does not involve any experimentation based on humans or animals therefore no ethical approval is required.
Consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Christian Gagnon
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Khurram, D., Bao, Y., Tang, Q. et al. Sedimentary geochemistry mediated by a specific hydrological regime in the water level fluctuation zone of the Three Gorges Reservoir, China. Environ Sci Pollut Res 30, 40356–40374 (2023). https://doi.org/10.1007/s11356-022-25086-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-022-25086-y