Abstract
This research focused on degradation of carbaryl in water using TiO2-coated glass-fiber filter under sunlight irradiation. The coating substances were 0.3–2% w/v TiO2 mixed with 5 different binders, DURAMAX B1000, PEG molecular weight of 1000, 2000, 4000, and 6000, in a concentration of 0.3–2 wt% of TiO2. Optimum concentration of coating substance was investigated for the best degradation efficiency in terms of reaction kinetic rates. Sorption of carbaryl and zeta potential of coating substance were also studied.
The results revealed that carbaryl sorptions on the coated filters were 2% or less. The optimum concentration of coating substance was 1% w/v TiO2 and 1 wt% PEG6000 with the kinetic rate constant of 0.022–0.025 min−1. The point of zero charge of 1% w/v TiO2 + 1% wt% PEG6000 occurred at pH 7.5, while the pH of carbaryl solution was 7.3 ± 0.3. Thus, TiO2 was neutral, and repulsive force did not exist in this optimum coating. With the optimum TiO2 loading of 1–2 g/L, 100% carbaryl degradation was obtained in 150 min.
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Data supporting the findings are available from the corresponding author upon reasonable request.
References
Alalm MG, Tawfik A, Ookawara S (2015) Comparison of solar TiO2 photocatalysis and solar photo-Fenton for treatment of pesticides industry wastewater: operational conditions, kinetics, and costs. J Water Process Eng 8:55–63
Albano MP, Genova LA, Garrido LB, Plucknett K (2008) Processing of porous yttria-stabilized zirconia by tape-casting. Ceram Int 34:1983–1988
Bond C, Cross A, Buhl K, Stone D (2016) Carbaryl General Fact Sheet. National Pesticide Information Center, Oregon State University Extension Services. http://npic.orst.edu/factsheets/carbarylgen.html. Accessed 13 April 2022
Department of Agriculture (n.d.) Hazardous substances control. https://www.doa.go.th/ard/?page_id=386. (In Thai) Accessed 13 April 2022
Fadillah G, Saleh TA, Wahyuningsih S (2019) Enhanced electrochemical degradation of 4-nitrophenol molecules using novel Ti/TiO2-NiO electrodes. J Mol Liq 289:111108
Hantas J, Bartlett A, Oldfield P et al (2007) Application of an in-line imprinted polymer column in a potentiometric flow-injection chemical sensor to the determination of the carbamate pesticide carbaryl in complex biological matrices. Anal Bioanal Chem 387:351–357
Jiménez M, Maldonada MI, Rodríguez EM et al (2015) Supported TiO2 solar photocatalysis at semi-pilot scale: degradation of pesticides found in citrus processing industry wastewater, reactivity and influence of photogenerated species. J ChemTechnol Biotechnol 90:149–157
Karimian H, Babaluo AA (2006) Effect of polymeric binder and dispersant on the stability of colloidal alumina suspensions. Iran Polym J 15(11):879–889
Mondal NK, Chattoraj S, Sadhukhan B, Das B (2013) Evaluation of carbaryl sorption in alluvial soil. Songklanakarin J Sci Technol 35:727–738
Montinaro D, Sglavo VM, Bertoldi M et al (2006) Tape casting fabrication and co-sintering of solid oxide “half cells” with a cathode-electrolyte porous interface. Solid State Ion 177:2093–2097
Moraes FC, Mascaro LH, Machado SAS, Brett CMA (2009) Direct electrochemical determination of carbaryl using a multi-walled carbon nanotube/cobalt phthalocyanine modified electrode. Talanta 79:1406–1411
Nakata K, Fujishima A (2012) TiO2 photocatalysis: design and applications. J Photochem Photobiol c: Photochem Rev 13:169–189
Ngamsakpasert C, Suriyawong A, Supothina S, Chuaybamroong P (2020) Post-harvest treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios. J Nanoparticle Res 22 (7): Article 174
National Library of Medicine (n.d.) Carbaryl. https://pubchem.ncbi.nlm.nih.gov/compound/Carbaryl#section=Names-and-Identifiers. Accessed 13 April 2022
Ohtani B, Prieto-Mahaney OO, Li D, Abe R (2010) What is Degussa (Evonik) P25? Crystalline composition analysis, reconstruction from isolated pure particles and photocatalytic activity test. Photochem Photobiol a: Chem 216:179–182
Oliveira MF, Johnston CT, Premachandra GS et al (2005) Spectroscopic study of carbaryl sorption on smectite from aqueous suspension. Environ Sci Technol 39:9123–9129
Pramauro E, Prevot AB, Vincinti M, Brizzolesi G (1997) Photocatalytic degradation of carbaryl in aqueous solutions containing TiO2 suspension. Environ Sci Tech 31:3126–3131
Rahmani T, Bagheri H, Behbahani M et al (2018) Modified 3D graphene-Au as a novel sensing layer for direct and sensitive electrochemical determination of carbaryl pesticide in fruit, vegetable, and water samples. Food Anal Methods 11:3005–3014
Reddy PAK, Reddy PVL, Sharma VM et al (2010) Photocatalytic degradation of isoproturon pesticide on C, N and S doped TiO2. J Water Resource Prot 2:235–244
Rtimi S, Kiwi J (2017) Bactericide effects of transparent polyethylene photocatalytic films coated by oxides under visible light. Appl Catal b: Environ 213:62–73
Rtimi S, Pulgarin C, San**es R, Kiwi J (2013) Innovative semi-transparent nanocomposite films presenting photo-switchable behavior and leading to a reduction of the risk of infection under sunlight. RSC Adv 3:16345–16348
Rtimi S, Pulgarin C, San**es R, Kiwi J (2015) Kinetics and mechanism for transparent polyethylene-TiO2 films mediated self-cleaning leading to MB dye discoloration under sunlight irradiation. Appl Catal b: Environ 162:236–244
Rtimi S, Giannakis S, Bensimon M et al (2016) Supported TiO2 films deposited at different energies: implications of the surface compactness on the catalytic kinetics. Appl Catal b: Environ 191:42–52
Salih FE, Oularbi L, Halim E et al (2018) Conducting polymer/ionic liquid composite modified carbon paste electrode for the determination of carbaryl in real samples. Electroanalysis 30:1855–1864
Shankar MV, Anandan S, Venkatachalam N et al (2006) Fine route for an efficient removal of 2,4-dichlorophenoxyacetic acid (2,4-D) by zeolite-supported TiO2. Chemosphere 63:1014–1021
Sharma MVP, Sadanandam G, Ratnamala A et al (2009) An efficient and novel porous nanosilica supported TiO2 photocatalyst for pesticide degradation using solar light. J Hazard Mater 171:626–633
Sonawane RS, Dongare MK (2006) Sol-gel synthesis of Au/TiO2 thin films for photocatalytic degradation of phenol in sunlight. J Mol Catal a: Chem 243:68–76
Statista (n.d.) Agricultural consumption of pesticides worldwide in 2019, by type. https://www.statista.com/statistics/1263206/global-pesticide-use-by-type/. Accessed 13 April 2022
Sungkajuntranon K, Sribenjalux P, Supothina S, Chuaybamroong P (2014) Effect of binders on airborne microorganism inactivation using TiO2 photocatalytic fluorescent lamps. J Photochem Photobiol b: Biol 138:160–171
Tasić N, Branković Z, Marinković-Stanojević Z, Branković G (2012) Effect of binder molecular weight on morphology of TiO2 films prepared by tape casting and their photovoltaic performance. Sci Sinter 44:365–372
Thunyasirinon C, Sribenjalux P, Supothina S, Chuaybamroong P (2015) Enhancement of air filter with TiO2 photocatalysis for Mycobacterium tuberculosis removal. Aerosol Air Qual Res 15:600–610
U.S. EPA (2020) Carbaryl (056801) National and State Summary Use and Usage Summary. https://www3.epa.gov/pesticides/nas/carbaryl/appendix-1-4.pdf. Accessed 13 April 2022
US EPA (2021) Guidance for Reporting on the Environmental Fate and Transport of the Stressors of Concern in Problem Formulations. https://www.epa.gov/pesticide-science-and-assessing-pesticide-risks/guidance-reporting-environmental-fate-and-transport#I. Accessed 13 April 2022
USDA (US Department of Agriculture) (1995) https://www.ars.usda.gov/ARSUserFiles/00000000/DatabaseFiles/PesticidePropertiesDatabase/IndividualPesticideFiles/CARBARYL.TXT. Accessed 13 April 2022
Yu J, Zhao X, Zhao Q (2000) Effect of surface structure on photocatalytic activity of TiO2 thin films prepared by sol-gel method. Thin Solid Films 379:7–14
Zhu X, Yuan C, Chen H (2007) Photocatalytic degradation of pesticide pyridaben. 3. In surfactant/TiO2 aqueous dispersions. Environ Sci Technol 41:263–269
Funding
This research was financially supported by the Faculty of Science and Technology, Thammasat University (contract no. SciGR 7/2565). Juraiwan Jampawal was so grateful to Her Royal Highness Princess Maha Chakri Sirindhorn for a scholarship for the M.S. study.
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All authors contributed to the study. Conception, design, and manuscript preparation were performed by PC. Experimental studies were performed by JJ. TiO2 characterization was performed by SS. All authors read and approved the final manuscript.
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Jampawal, J., Supothina, S. & Chuaybamroong, P. Solar photocatalytic degradation of carbaryl in water using TiO2-coated filters with different binders and effect of the operating conditions. Environ Sci Pollut Res 29, 88027–88040 (2022). https://doi.org/10.1007/s11356-022-21907-2
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DOI: https://doi.org/10.1007/s11356-022-21907-2