Abstract
In this work, second pyrolysis oil-based drill cutting ash (OBDCA-sp) was modified using NaOH and cetyltrimethylammonium bromide (CTAB), respectively. The modified OBDCA-sp was used as the novel adsorbent for adsorption of tetracycline (TC) in aqueous solutions. The original and modified OBDCA-sp were characterized by SEM, XRD, FTIR, zeta potential analysis, contact angle, and BET. The maximum theoretical adsorption quantity (45 ℃) for TC was calculated as 1.7 mg/g using CTAB-OBDCA-sp as the adsorbent. The adsorption isotherm of TC on OBDCA-sp was fitted well with Freundlich model and the adsorption kinetic was illustrated by pseudo-second-order model. Neutral condition was favorable for the adsorption of TC. The result of regeneration experiment indicated the reusability of OBDCA-sp. The hydrogen bonding was the possible mechanism for TC adsorption. This paper developed the novel surface modification methods of OBDCA-sp and provided an approach for the resource utilization of OBDCA-sp as an environmental functional material.
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The authors would like to thank Shiyanjia Lab (www.shiyanjia.com) for the material characterization.
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The authors are grateful for the support provided by the Study on Comprehensive Control of Rocky Desertification and Ecological Service Function Improvement in Karst Peaks (no. 2016YFC0502402); Fuling Shale Gas Environmental Exploration Technology of National Science and Technology Special Project (grant no. 2016ZX05060); and the National Natural Science Foundation of China (no. 51709254), and Youth Innovation Promotion Association, Chinese Academy of Sciences (no. 2020335).
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Yang, H., Ding, Z., Zou, Y. et al. Enhanced adsorption of tetracycline using modified second pyrolysis oil-based drill cutting ash. Environ Sci Pollut Res 29, 81760–81776 (2022). https://doi.org/10.1007/s11356-022-21504-3
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DOI: https://doi.org/10.1007/s11356-022-21504-3