Abstract
In this paper, nano/microstructure lanthanum borates were synthesized by hydrothermal route. Furthermore, oleic acid-capped nano/microstructure lanthanum borates (OANLBs) were also prepared. The nano/microstructure of lanthanum borate is characterized by means of Fourier transform-infrared spectroscopy (FT-IR), field-emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). At the same time, the friction and wear properties of OANLBs as additives in poly-alpha-olefin (PAO) were measured for AISI 1045 steel and laser treated AISI 1045 steel. Results show that the PAO containing OANLBs possesses much better tribological properties for steel/steel and steel/laser treated AISI 1045 steel sliding pairs than pure PAO.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig1_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig4_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig5_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig6_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig7_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig8_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig9_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig10_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig11_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig12_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig13_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11249-010-9728-8/MediaObjects/11249_2010_9728_Fig14_HTML.gif)
Similar content being viewed by others
References
Chen, T., Deng, J.C., Wang, L.S., Feng, G.: Preparation and characterization of nano-zinc borate by a new method. Mater Process Technol 209, 4076–4079 (2009)
Tian, Y.M., Guo, Y.P., Jiang, M., Sheng, Y., Hari, B., Zhang, G.Y., et al.: Synthesis of hydrophobic zinc borate nanodiscs for lubrication. Mater Lett 60, 2511–2515 (2006)
Shi, X.X., **ao, Y., Yuan, L.J., Sun, J.T.: Hydrothermal synthesis and characterizations of 2D and 3D 4ZnO·B2O3·H2O nano/microstructures with different morphologies. Powder Technol 189, 462–465 (2009)
Zhou, J., Su, D.G., Luo, J.M., Zhong, M.F.: Synthesis of aluminum borate nanorods by a low-heating-temperature solid-state precursor method. Mater Res Bull 44, 224–226 (2009)
Bakunin, V.N., Suslov, A.Y., Kuzmina, G.N., Parenago, O.P.: Recent achievements in the synthesis and application of inorganic nanoparticles as lubricants components. Lubr Sci 17, 127–145 (2005)
Liu, N., Tian, Y.M., Yu, L.X., Li, Q.J., Meng, F.Y., Zheng, Y.H.: Synthesis and surface modification of uniform barium borate nanorods for lubrication. J Alloys Compd 466, L11–L14 (2008)
Chen, T., Deng, J.C., Wang, L.S., Fan, Y., Gang, F.: Synthesis of a new netlike nano zinc borate. Mater Lett 62, 2057–2059 (2008)
Qiao, Y.L., Liu, W.M., Xu, B.S., Ma, S.N., Xue, Q.J.: The tribochemical performance of nano/micrometer borate modified by an N-containing compound as an oil additive. Lubr Sci 15, 369–379 (2003)
Bonini, M., Bardi, U., Berti, D., Neto, C., Baglioni, P.: A new way to prepare nanostructured materials: flame spraying of microemulsions. J Phys Chem B 106, 6178–6183 (2002)
Liu, W.M., Zhang, Z.F., Xue, Q.J.: Friction and wear behaviors of aluminum-on-steel under the lubrication of grease containing a complex of lanthanum dialkyldithiocarbamate and phenanthroline. Wear 199, 153–156 (1990)
Standnes, H.: Analysis of oil recovery rates for spontaneous imbibition of aqueous surfactant solutions into preferential oil-wet carbonates by estimation of capillary diffusivity coefficients. Colloids Surf A 251, 93–101 (2004)
Olson, W.D., Muir, R.J., Eliades, T.I., Steib, T.: Improved sulfonate greases. EP 0613940A2 (1994)
Liu, W.M., Gao, C.Z., Zhang, Z.F., Xue, Q.J.: Tribological properties of aluminum-on-steel system under the lubrication of grease containing a complex of lanthanum N-salicylidene derivative of malonic dihydrazide. Wear 196, 234–237 (1996)
Zhang, Z.F., Liu, W.M., Xue, Q.J.: Study on lubricating mechanisms of La(OH)3 nanocluster modified by compound containing nitrogen in liquid paraffin. Wear 218, 139–144 (1998)
Zhang, Z.F., Liu, W.M., Xue, Q.J.: The tribological behaviors of succinimide-modified lanthanum hydroxide nanoparticles blended with zinc dialkyldithiophosphate as additives in liquid paraffin. Wear 248, 48–54 (2001)
Hu, Z.S., Dong, J.X., Chen, G.X., He, J.Z.: Preparation and tribological properties of nanoparticle lanthanum borate. Wear 243, 43–47 (2000)
Moulder, J.F., Stickle, W.F., Sobol, P.E., Bomben, K.D.: Handbook of X-ray Photoelectron Spectroscopy. Physical Electronics, Inc Press, Eden Prairie (1995)
Chen, S., Liu, W.M.: Oleic acid capped PbS nanoparticles: synthesis, characterization and tribological properties. Mater Chem Phys 98, 183–189 (2006)
Jia, Z.F., Wang, P., **a, Y.Q., Zhang, H.B., Pang, X.J., Li, B.: Tribological behaviors of diamond-like carbon coatings on plasma nitrided steel using three BN-containing lubricants. Appl Surf Sci 255, 6666–6674 (2009)
Jia, Z.F., **a, Y.Q., Li, J.L., Pang, X.J., Shao, X.: Friction and wear behavior of diamond-like carbon coating on plasma nitrided mild steel under boundary lubrication. Tribol Int 43, 474–482 (2010)
Zheng, Z., Shen, G.Q., Wan, Y., Cao, L.L., Xu, X.D., Yue, Q.X., Sun, T.J.: Synthesis, hydrolytic stability and tribological properties of novel borate esters containing nitrogen as lubricant additives. Wear 222, 135–144 (1998)
Acknowledgments
The authors would like to thank the financial support of this work by “Hundred Talents Program” of CAS, Natural Science Foundation of China (Grant No.50905177), and “973” program (2007CB607606).
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Jia, Z., **a, Y. Hydrothermal Synthesis, Characterization, and Tribological Behavior of Oleic Acid-Capped Lanthanum Borate with Different Morphologies. Tribol Lett 41, 425–434 (2011). https://doi.org/10.1007/s11249-010-9728-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11249-010-9728-8