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Efficient degradation and adsorption of roxarsone by FeOOH quantum decorated resorcinol–formaldehyde resins via Fenton-like process

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Abstract

Roxarsone (ROX), a feed additive widely used worldwide, was degraded into toxic products in the natural environment. Advanced oxidation processes (AOP) based on nonradicals used for the degradation of ROX had not been reported. Herein, resorcinol–formaldehyde resins (RFs) produced by a simple high-temperature hydrothermal method had efficient photocatalytic properties to produce H2O2. FeOOH quantum dots (QDs) act as the activator and electron shuttle to decompose H2O2 to produce 1O2. RFs decorated with FeOOH quantum dots (RFs-FeQDs) were successfully synthesized and completely remove ROX with a rate of 0.03649 min−1 under simulated sunlight. Otherwise, the 99.42% arsenic-containing portion that shed from Roxarsone was eventually converted to As(V) and in-situ adsorbed by FeOOH quantum dots. The experiment data showed that ·OH, O2·− and 1O2 participated in the degradation and 1O2 was the dominant reactive species. Moreover, the systems have excellent reusability and stability over a wide pH range. This study provided a new strategy for photocatalytic production of 1O2 to remove the ROX from water.

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Funding

This study was supported by National Natural Science Foundation of China (22006038, 22076046), and Fundamental Research Funds for the Central Universities (JKB01221619).

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Authors and Affiliations

  1. State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control On Chemical Process, National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery, School of Resources and Environmental Engineering, East China University of Science & Technology, Shanghai, 200237, People’s Republic of China

    Wentong Shen, Liang Zhou, Yongdi Liu & Juying Lei

  2. Key Laboratory for Advanced Materials, Shanghai Engineering Research Center for Multi-Media Environmental Catalysis and Resource Utilization, Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, People’s Republic of China

    **long Zhang

  3. Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, People’s Republic of China

    Liang Zhou, Yongdi Liu & Juying Lei

Authors
  1. Wentong Shen
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  2. Liang Zhou
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  3. Yongdi Liu
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  4. **long Zhang
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  5. Juying Lei
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Contributions

WS and LZ wrote the main manuscript text. YL and JL helped perform the analysis with constructive discussions. JZ contributed significantly to analysis and manuscript preparation. All authors reviewed the manuscript.

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Correspondence to Liang Zhou or Juying Lei.

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Shen, W., Zhou, L., Liu, Y. et al. Efficient degradation and adsorption of roxarsone by FeOOH quantum decorated resorcinol–formaldehyde resins via Fenton-like process. Res Chem Intermed 49, 2569–2582 (2023). https://doi.org/10.1007/s11164-023-05012-8

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  • DOI: https://doi.org/10.1007/s11164-023-05012-8

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