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Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives

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In this study, isophorone derivatives, which are single step aldol products, were designed and synthesized. Our overview of the synthesis of solar cell application and biological applications of series vinyl substituted isophorone compounds is reported. All synthesized compounds were characterized both through experimental techniques and calculations with density functional theory. Additionally, we investigated the photophysical properties of small organic compounds for organic bulk heterojunction photovoltaic cells. The solar cell efficiency results were compared and compound 4 was found to be more efficient than the other compounds. It was found that the optical quantum yield values were very close. Isophorone derivatives showed better antioxidant activities, which were DPPH, metal chelating, reducing activity, and antimicrobial activities against Salmonella typhimurium, Klebsiella pneumonia, Candida albicans, Staphylococcus aureus, Bacillus subtilis, and Escherichia coli. Compound 7 (which is substituted quinoline) and compound 5 (which is substituted cyno) had the highest antioxidant effect. The 4-brom phenyl, 4-cyno phenyl were used against gram negative bacteria and the 4-ter-butyl phenyl group was indicated for gram positive bacteria and yeast.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Amasya University, 05100, Amasya, Turkey

    Zehra Kozak & Melek Gul

  2. Photonic Technologies Laboratory, TÜBİTAK MAM Material Institute, 41470, Gebze, Kocaeli, Turkey

    Selin Pıravadılı Mucur

  3. S. Şerefeddin Health Services Vocational School, Amasya University, 05100, Amasya, Turkey

    Betül Canımkurbey

  4. Department of Physics, Faculty of Arts and Sciences, Amasya University, 05100, Amasya, Turkey

    Serpil Eryılmaz

  5. Department of Science Education, Faculty of Education, Amasya University, 05100, Amasya, Turkey

    Önder İdil

  6. Central Research Laboratory, Amasya University, 05100, Amasya, Turkey

    Betül Canımkurbey & Melek Gul

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  1. Zehra Kozak
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  2. Selin Pıravadılı Mucur
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  3. Betül Canımkurbey
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  4. Önder İdil
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  5. Serpil Eryılmaz
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Correspondence to Melek Gul.

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Kozak, Z., Pıravadılı Mucur, S., Canımkurbey, B. et al. Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives. Res Chem Intermed 45, 5625–5639 (2019). https://doi.org/10.1007/s11164-019-03924-y

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  • DOI: https://doi.org/10.1007/s11164-019-03924-y

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