Abstract
A comparison of oxide films formed on the stainless steel surface during laser and furnace heating is presented. Obtained samples were examined by optical and scanning electron microscopy. In order to characterize the optical properties, reflection spectra within the wavelength range 190–900 nm were measured with a spectrophotometer equipped with the integrating sphere for incidence angles from 0° to 60°. The topology of obtained oxide films was characterized by scanning probe microscopy. Due to light interference in produced films, the coloration of treated area is observed. It was found that there is no change in the characteristic appearance of reflectance spectra at different light incidence angles, but a blue-shift occurs especially for the case of laser-induced films, which results in a visible change of surface color. This effect is associated with an interference character of originating color and features of surface relief under an oxide film.
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References
Arzuov, M.I., Barchukov, A.I., Bunkin, F.V., Kirichenko, N.A., Konov, V.I., Luk’yanchuk, B.S.: Influence of interference effects in oxide films on the kinetics of laser heating of metals. Sov. J. Quantum Electron. 9, 281–284 (1979)
Chourpa, I., Douziech-Eyrolles, L., Ngaboni-Okassa, L., Fouquenet, J.-F., Cohen-Jonathan, S., Soucé, M., Marchais, H., Dubois, P.: Molecular composition of iron oxide nanoparticles, precursors for magnetic drug targeting, as characterized by confocal Raman microspectroscopy. Analyst 130, 1395–1403 (2005)
Duprez, D., Cavani, F.: Handbook of Advanced Methods and Processes in Oxidation Catalysis: From Laboratory to Industry. World Scientific Publishing Co. Pte. Ltd., Singapore (2014)
Jervis, T.R., Williamson, D.L., Hirvonen, J.-P., Zocco, T.G.: Characterization of the surface oxide formed by excimer laser surface processing of AISI 304 stainless steel. Mater. Lett. 9, 379–383 (1990)
Kozakov, A.T., Yares’ko, S.I.: Using auger electron spectroscopy for studying the composition of the surface of multicomponent alloys under the effect of pulsed laser irradiation. Inorg. Mater. Appl. Res. 2, 254–260 (2011)
Łekecka, K.M., Antończak, A.J., Szubzda, B., Wójcik, M.R., Stekepak, B.D., Szymczyk, P., Trzciński, M., Ozimek, M., Abramski, K.M.: Effects of laser-induced oxidation on the corrosion resistance of AISI 304 stainless steel. J. Laser Appl. 28, 032009 (2016)
Li, Z.L., Zheng, H.Y., Teh, K.M., Liu, Y.C., Lim, G.C., Seng, H.L., Yakovlev, N.L.: Analysis of oxide formation induced by UV laser coloration of stainless steel. Appl. Surf. Sci. 256, 1582–1588 (2009)
Schneider, M., Langklotz, U., Michaelis, A.: Thickness determination of thin anodic titanium oxide films—a comparison between coulometry and reflectometry. Surf. Interface Anal. 43, 1471–1479 (2011)
Simka, W., Sadkowski, A., Warczak, M., Iwaniak, A., Dercz, G., Michalska, J., Maciej, A.: Characterization of passive films formed on titanium during anodic oxidation. Electrochim. Acta 56, 8962–8968 (2011)
Somervuori, M., Johansson, L.-S., Heinonen, M.H., Van Hoecke, D.H.D., Akdut, N., Hänninen, H.E.: Characterisation and corrosion of spot welds of austenitic stainless steels. Mater. Corros. 55, 421–436 (2004)
Tepluhin, G.N., Gropyanov, A.V.: Metallovedenie i termicheskaya obrabotka (Metallurgical Science and Heat Treatment). SPbGTU RP, St. Petersburg (2011)
Thibeau, R.J., Brown, C.W., Heidersbach, R.H.: Raman spectra of possible corrosion products of iron. Appl. Spectrosc. 32, 532–535 (1978)
Veiko, V., Odintsova, G., Ageev, E., Karlagina, Y., Loginov, A., Skuratova, A., Gorbunova, E.: Controlled oxide films formation by nanosecond laser pulses for color marking. Opt. Express 22, 24342–24347 (2014)
Veiko, V., Odintsova, G., Gorbunova, E., Ageev, E., Shimko, A., Karlagina, Y., Andreeva, Y.: Development of complete color palette based on spectrophotometric measurements of steel oxidation results for enhancement of color laser marking technology. Mater. Des. 89, 684–688 (2016)
Veiko, V.P., Slobodov, A.A., Odintsova, G.V.: Availability of methods of chemical thermodynamics and kinetics for the analysis of chemical transformations on metal surfaces under pulsed laser action. Laser Phys. 23, 66001 (2013)
Yun, H.-G., Kim, M., You, I.-K.: Tuned optical reflection characteristics of chemically-treated Ti substrates. ETRI J. 34, 954–957 (2012)
Acknowledgements
SEM and SPM characterization was made on the equipment of the Federal Joint Research Center “Material science and characterization in advanced technology” (Ioffe Institute, Saint-Petersburg, Russia). Raman and reflectance spectra were performed at the Center for Optical and Laser Research of Research Park of St. Petersburg State University. The reported study was partially supported by Grant for International scientific laboratory with state support of leading universities of the Russian Federation # 074-U01 and RSF Agreement No 14-12-00351.
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This article is part of the Topical Collection on Fundamentals of Laser Assisted Micro- and Nanotechnologies.
Guest edited by Eugene Avrutin, Vadim Veiko, Tigran Vartanyan and Andrey Belikov.
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Ageev, E.I., Andreeva, Y.M., Brunkov, P.N. et al. Influence of light incident angle on reflectance spectra of metals processed by color laser marking technology. Opt Quant Electron 49, 50 (2017). https://doi.org/10.1007/s11082-016-0876-4
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DOI: https://doi.org/10.1007/s11082-016-0876-4