The influence of a dispersed powder filler obtained by thermal synthesis from a mixture of 65% titanium hydride, 30% ferrosilicon, and 5% technical carbon powders, on the main physicomechanical properties of a polymer composite based on ED-20 epoxy diane oligomer, is investigated. The content of the filler varied in the range from 5 to 40 mass%. The introduction of the filler into the polymer composition leads to a noticeable increase in the main mechanical characteristics of the composite. Its maximum values at the dispersed component content of 10%, ensure an increase in bending strength in 1.6 times, and an impact toughness in 1.7 times compared to the original matrix. A further increase in the dispersed filler content in the composite composition to 20–40% leads to a decrease in fracture stresses, the level of which, however, still exceeds the strength of the original matrix phase. Composites with 5% filler demonstrate maximum values of adhesive strength and minimum values of residual stresses. When the content of dispersed filler increases by more than 5–10%, the formation of the dispersed particles conglomerates the number and size of which increase with the increase in the powder concentration in the mixture is observed in the composite structure.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11003-024-00817-3/MediaObjects/11003_2024_817_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11003-024-00817-3/MediaObjects/11003_2024_817_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11003-024-00817-3/MediaObjects/11003_2024_817_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11003-024-00817-3/MediaObjects/11003_2024_817_Fig4_HTML.png)
Similar content being viewed by others
References
N. R. Paluvai, S. Mohanty, and S. K. Nayak, “Synthesis and modifications of epoxy resins and their composites: A review,” Polymer-Plastics Techn. and Eng., 53, Is. 16, 1723–1758 (2014). https://doi.org/10.1080/03602559.2014.919658
P. Mohan, “A critical review. The modification, properties, and applications of epoxy resins,” Polymer-Plastics Techn. and Eng., 52, Is. 2, 107–125 (2013). https://doi.org/10.1080/03602559.2012.727057
J.-P. Pascault, and R. J. J. Williams, Epoxy Polymers, New Materials and Innovations, Weinheim, Wiley-VCH (2010). https://doi.org/10.1002/9783527628704.ch1
M. L. Kerber, M. V. Vinogradov, G. S. Golovkin, Yu. A. Gotbatkina, and V. K. Kryzhanovskui, Polymer Composite Materials: Structure, Properties, Technology [in Russian], Proffesiya, St.-Peterburg (2009).
K. M. Sanjay, Composites Manufacturing, Materials, Products, & Process Engineering, Taylor & Francis, Washington (2002). https://doi.org/10.1201/9781420041989
A. K. Srivastava, and P. Mohan, “Synthesis reaction and properties of modified epoxy resins,” J. of Macromolecular Sci. – Rev. in Macromolecular Chem. and Phys., 37, Is. 4, 687–716 (1997). https://doi.org/10.1080/15321799708009653
S. L. Bazhenov, A. A. Berkin, A. A. Kulkov, and V. G. Oshmian, Polymer Composite Materials: Strength and Technology [in Russian], Intellekt, Moscow (2010).
C. M. Manjunatha, A. C. Taylor, A. J. Kinloch, and S. Sprenger, “The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite,” Composites Sci. and Techn., 70, Is. 1, 193–199 (2010). https://doi.org/10.1016/j.compscitech.2009.10.012
S.-Y. Fu, and B. Lauke, “Characterization of tensile behaviour of hybrid short glass fibre/calcite particle/ABS composites,” Composites Part A: Applied Sci. and Manufacturing, 29, Iss. 5–6, 575–583 (1998). https://doi.org/10.1016/S1359-835X(97)00117-6
G. O. Sirenko, L. Ya. Midak, and M. B. Kvych, “Search of optimal carbon fiber content in the polymer matrix of the antifriction composite,” Physics and Chemistry of Solid State [in Ukrainian], 7, Is. 1, 172–176 (2006).
I. Alexandrou, E. Kymakis, and G. A. J. Amaratunga, “Polymer-nanotube composites: Burying nanotubes improves their field emission properties,” Appl. Phys. Letters, 80, Is. 8, 1435–1437 (2002). https://doi.org/10.1063/1.1449537
K.-T. Lau, C. Gu, and D. Hui, “A critical review on nanotube and nanotube/nanoclay related polymer composite materials,” Composites Part B: Eng., 37, Is. 6, 425–436 (2006). https://doi.org/10.1016/j.compositesb.2006.02.020
X.-L. ** structure in epoxy coating,” Carbon, 157, 217–233 (2020). https://doi.org/10.1016/j.carbon.2019.10.034
A. V. Buketov, G. A. Bagliuk, O. M. Sizonenko, O. O. Sapronov, S. O. Smetankin, and A. S. Torpakov, “Effect of particulate Ti–Al–TiC reinforcements on the mechanical properties of epoxy polymer composites,” Powder Metallurgy and Metal Ceramics, 61, Iss. 9–10, 586–596 (2023). https://doi.org/10.1007/s11106-023-00347-8
G. A. Bagliuk, O. V. Suprun, and A. A. Mamonova, “Peculiarities of structure formation during the thermal synthesis of multicomponent compounds from powder mixtures based on the TiH2–Fe–Si–Mn–C(B4C) system,” Naukovi Notatky [in Ukrainian], Is. 58, 27–35 (2017).
O. V. Suprun, G. A. Bagliuk, and O. V. Shyrokov, “Features of the structure and phase formation of multicomponent compounds from powder mixtures based on the TiH2–Fe–Si–Mn system with different B4C content,” Naukovi Notatky [in Ukrainian], Is. 66, 344–350 (2019).
X. Li, L. Gao, X. Shao, C. Zhang, and C. Wang, “Mathematical modeling and evolutionary algorithm-based approach for integrated process planning and scheduling,” Computers & Operations Res., 37, Is. 4, 656–667 (2010). https://doi.org/10.1016/j.cor.2009.06.008
G. E. Rani, R. Murugeswari, S. Siengchin, N. Ra**i, and M. A. Kumar, “Quantitative assessment of particle dispersion in polymeric composites and its effect on mechanical properties,” J. of Mater. Res. and Techn., 19, 1836–1845 (2022). https://doi.org/10.1016/j.jmrt.2022.05.147
B. Turcsanyi, B. Pukanszky, and F. Tudos, “Composition dependence of tensile yield stress in filled polymers,” J. Mater. Sci. Lett., 7, 160–162 (1988). https://doi.org/10.1007/BF01730605
H.-L. Dai, C. Mei, and Y.-N. Rao, “A novel method for prediction of tensile strength of spherical particle-filled polymer composites with strong adhesion,” Polymer Eng. and Sci., 57, Is. 2, 137–142 (2017). https://doi.org/10.1002/pen.24393
A. Zavialov, T. Brusentseva, L. Vikulina, S. Bardakharov, T. Chymytov, and V. Syzrantsev, “Interaction of silica nanoparticles with polymers,” Nanoindustriya [in Ukrainian], 39, Is. 1, 32–36 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 59, No. 5, 89–96, September–October, 2023.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Baranovska, O.V., Bagliuk, G.A., Buketov, A.V. et al. The Influence of the Dispersed Filler of the Ni–Fe–Si–C System on the Physicomechanical Properties and Structure of Epoxy Composites. Mater Sci 59, 608–615 (2024). https://doi.org/10.1007/s11003-024-00817-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11003-024-00817-3