Abstract
The products and the kinetics of the reaction of dimethyldioxirane with adamantane in CCl4 were studied. It was found that the reaction simultaneously occurred via molecular and radical paths. The contribution of the radical process was 65% at 30.6°C. The activation parameters of the reaction of dimethyldioxirane with adamantane in the presence of an inhibitor were determined: logk = (7.33 ± 0.14)-(58.5 ± 0.8)/Θ, Θ = 2.3RT(kJ/mol) (10.3–69.3°C).
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Translated from Kinetika i Kataliz, Vol. 45, No. 6, 2004, pp. 859–862.
Original Russian Text Copyright © 2004 by Grabovskiy, Antipin, Kabal’nova.
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Grabovskiy, S.A., Antipin, A.V. & Kabal’nova, N.N. The role of free radicals in the reaction of dimethyldioxirane with adamantane. Kinet Catal 45, 809–812 (2004). https://doi.org/10.1007/s10975-005-0040-9
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DOI: https://doi.org/10.1007/s10975-005-0040-9